Fixing CO2 into ß-oxopropylcarbamates in neat condition by ionic gelation/Ag(i) supported on dendritic fibrous nanosilica.

In this research, a novel approach to produce a novel nanocatalyst, AgBr supported on an ionic gelation (IG)-based nanomaterial, was developed through the aqueous coprecipitation approach for the dendritic fibrous nanosilica (DFNS) production and the wet impregnation method for IG coating, taking into account TPP as the cross-linking agent. In addition, DFNS/IG@Ag(i) had heterogeneous features that contributed to the quick improvement of the catalyst by filtration separation. The catalytic activity of DFNS/IG@Ag(i) was examined to synthesize ß-oxopropylcarbamates through a multicomponent coupling of CO2, amines and propargyl alcohols in moderate conditions. The DFNS/IG@Ag(i) NPs were completely investigated by taking advantage of TG, TEM, FESEM and FT-IR spectroscopy analyses. The DFNS/IG@Ag(i) nanocatalyst indicated high stability in the reaction for five cycles without considerable loss of some properties like activity, which could be because of the high loading of IG on the catalyst surface.