A Color-tunable Nitride Phosphor for Near-Ultraviolet Excitation of White Light-emitting Diodes.
Chem Asian J
; 17(19): e202200639, 2022 Oct 04.
Article
em En
| MEDLINE
| ID: mdl-35932212
ABSTRACT
Due to the diversity of structure and composition and the unique coordination environment, nitride materials enable the doped activator ions to possess compelling luminescence characteristics, such as rich emission colors, favorable stability and tunable emission spectra. Here, novel SrLuSi4 N7Ce3+ ,Tb3+ nitride phosphors were successfully synthesized by a modified carbothermal reduction and nitridation method at atmospheric pressure. SrLuSi4 N7 (SLSN) belongs to hexagonal symmetry, with space group P63 mc, and its crystal structure is composed of the basic building block with corner-sharing [SiN4 ] tetrahedron. Under 365â
nm excitation, SLSNCe3+ exhibits a broad emission band peaking at 450â
nm with a full width at half-maximum (FWHM) of 92â
nm and the most forceful intensity obtained at the Ce3+ concentration amount of 0.04. On the basis of the efficient energy transfer, SLSNCe3+ ,Tb3+ exhibits color-tunable emission from blue (450â
nm) to green (545â
nm). Our results indicate that SLSN nitride phosphor is a promising candidate for near-ultraviolet (n-UV) based white LEDs.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Asian J
Ano de publicação:
2022
Tipo de documento:
Article