Self-assembled discotics as molecular semiconductors.

ABSTRACT

With the advent of a new era of smart-technology, the demand for more economic optoelectronic materials that do not compromise with efficiency is gradually on the rise. Organic semiconductors provide greener alternatives to the conventional inorganic ones, but encounter the challenge of balancing charge carrier mobility with processability in devices. Discotic liquid crystals (DLCs), a class of self-assembling soft organic materials, possess the perfect degree of order and dynamics to address this challenge. Providing unidimensional charge carrier pathways through their nanoscale columnar architecture, DLCs can behave as efficient charge transport systems across a wide range of optoelectronic devices. Moreover, DLCs are solution-processable, thus reducing the fabrication cost. In this article, we have discussed the approaches towards developing DLCs as semiconductors, focusing on their molecular design concepts, supramolecular structures and electronic properties in the context of their charge carrier mobilities.