Nickel-Catalyzed Isomerization of Homoallylic Alcohols.

Youmans, Dustin D; Tran, Hai N; Stanley, Levi M

Youmans, Dustin D; Tran, Hai N; Stanley, Levi M.

Afiliação

Youmans DD; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.
Tran HN; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.
Stanley LM; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.

Org Lett ; 25(19): 3559-3563, 2023 May 19.

Article em En | MEDLINE | ID: mdl-37154573

ABSTRACT

ABSTRACT

Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Estados Unidos

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