Uniform Colloidal Polymer Rods by Stabilizer-Assisted Liquid-Crystallization-Driven Self-Assembly.

The synthesis of anisotropic colloidal building blocks is essential for their self-assembly into hierarchical materials. Here, a highly efficient stabilizer-assisted liquid-crystallization-driven self-assembly (SA-LCDSA) strategy was developed to achieve monodisperse colloidal polymer rods. This strategy does not require the use of block copolymers, but only homopolymers or random copolymers. The resulting rods have tunable size and aspect ratios, as well as well-defined columnar liquid crystal structures. The integrated triphenylene units enable the rods to exhibit unusual photo-induced fluorescence enhancement and accompanying irradiation memory effect, which, as demonstrated, are attractive for information encryption/decryption of paper documents. In particular, unwanted document decryption during delivery can be examined by fluorescence kinetics. This SA-LCDSA-based approach can be extended to synthesize other functional particles with desired π-molecular units.