Mononuclear indium(III) photosensitizers for photo-dehalogenation and olefin reduction.
Chem Commun (Camb)
; 60(12): 1595-1598, 2024 Feb 06.
Article
em En
| MEDLINE
| ID: mdl-38226668
ABSTRACT
Photoactive main-group complexes have been relatively underexplored in photocatalytic applications. Herein, we report a family of indium(III) complexes (In-1-In-4) containing pyridylpyrrolide ligands with different amounts of methyl groups, which all exhibit intense visible-light absorption as well as blue-green emission with nanosecond emission lifetimes and emission quantum yields of 6.7-12.5%. Electrochemical studies and quantum chemical calculations indicate that their (photo-)redox processes involve only ligand-centered events, which efficiently mediate photocatalytic dehalogenation and olefin reduction.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
/
Chem. commun. (Lond., 1996, Online)
/
Chemical communications (London. 1996. Online)
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article