Efficient and selective external activator-free cobalt catalyst for hydroboration of terminal alkynes enabled by BiPyPhos.

Li, Zheng; Zhao, Jiangui; Xue, Weichao; Tang, Juan; Li, Shun; Ge, Yicen; Xu, Jiaqi; Zheng, Xueli; Li, Ruixiang; Chen, Hua; Fu, Haiyan

Li, Zheng; Zhao, Jiangui; Xue, Weichao; Tang, Juan; Li, Shun; Ge, Yicen; Xu, Jiaqi; Zheng, Xueli; Li, Ruixiang; Chen, Hua; Fu, Haiyan.

Afiliação

Li Z; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Zhao J; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Xue W; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Tang J; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Li S; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Ge Y; College of Materials, Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China.
Xu J; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Zheng X; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Li R; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Chen H; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.
Fu H; Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. scufhy@scu.edu.cn.

Org Biomol Chem ; 22(22): 4455-4460, 2024 Jun 05.

Article em En | MEDLINE | ID: mdl-38764306

ABSTRACT

ABSTRACT

Herein, a robust catalyst system, composed of a bipyridine-based diphosphine ligand (BiPyPhos) and a cobalt precursor Co(acac)2, is successfully developed and applied in the hydroboration of terminal alkynes, exclusively affording various versatile ß-E-vinylboronates in high yields at room temperature.

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2024 Tipo de documento: Article

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google