Your browser doesn't support javascript.
loading
High-pressure synthesis of A-site ordered perovskite PbMn3(CrMn3)O12 with long-range antiferromagnetic ordering and a spin glass transition.
Xue, Man; Yan, Xiaohui; Xu, Deyang; Zheng, Bin; Guo, Wenbin; Kuang, Xiaojun; Lei, Xiuyun; Yin, Congling.
Afiliação
  • Xue M; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Yan X; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Xu D; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Zheng B; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Guo W; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Kuang X; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
  • Lei X; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P. R. China.
  • Yin C; MOE Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources, College of Materials Scienc
Dalton Trans ; 53(23): 9819-9826, 2024 Jun 10.
Article em En | MEDLINE | ID: mdl-38787742
ABSTRACT
An AA'3B4O12-type perovskite oxide PbMn3(CrMn3)O12 was synthesized by high-pressure solid-state reactions at 8 GPa and 1373 K. Synchrotron X-ray diffraction shows a cubic crystal structure with the space group Im3̄. The charge states are verified by X-ray photoelectron spectroscopy to be PbMn3+3(Cr3+Mn3+2Mn4+)O12, where the Pb2+ and Mn3+ are 1 3 ordered respectively at A and A' sites, while the Cr3+, Mn3+ and Mn4+ are disorderly distributed at the B site. PbMn3(CrMn3)O12 features a long-range antiferromagnetic order of A'-site Mn3+ spins at about 66 K and a subsequent spin glass transition around 36 K due to the randomly distributed Cr3+, Mn3+, and Mn4+ cations at the B site. This unique stepwise order of A' and B-site spins indicates weak A'-B site spin interactions, which are dominated by the difference in the B-site Mn3+/Ni2+ and Mn4+ number in the quadruple perovskites AMn3B4O12.
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article