Chemical fixation of CO2/CS2 to access iodoallenyl oxazolidinones and allenyl thiazolidine-thiones.
Chem Commun (Camb)
; 60(66): 8756-8759, 2024 Aug 13.
Article
em En
| MEDLINE
| ID: mdl-39073322
ABSTRACT
Constructing heterocyclic compounds by chemical fixation of CO2/CS2 as a C1 building block is a promising approach. An efficient and environmentally friendly synthetic approach has been developed using CO2/CS2 to prepare complicated allenyl heterocycles with high yields and diastereoselectivities in a metal-free manner under mild conditions. NIS promoted CO2 fixation and the cyclization reaction by exclusive 1,4-syn-addition of 1,3-enynes rather than 1,2-addition or 3,4-addition, while CS2 participated in unique 1,4-syn-hydrothiolation of 1,3-enynes to afford allenyl heterocycles with different reaction patterns.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article