Activated persulfate for efficient bisphenol A degradation via nitrogen-doped Fe/Mn bimetallic biochar.

ABSTRACT

To achieve the purpose of treating waste by waste, in this study, a nitrogen-doped Fe/Mn bimetallic biochar material (FeMn@N-BC) was prepared from chicken manure for persulfate activation to degrade Bisphenol A (BPA). The FeMn@N-BC was characterized by scanning electron microscopy (SEM), X-ray diffract meter (XRD), fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectrometer (XPS) and found that N doping can form larger specific surface area. Catalytic degradation experiments showed that Fe/Mn bimetal doping not only accelerated the electron cycling rate on the catalyst surface, but also makes the biochar magnetic and easy to separate, thus reducing environmental pollution. Comparative experiments was concluded that the highest degradation efficiency of BPA was achieved when the mass ratios of urea and chicken manure, Fe/Mn were 31 and 21, respectively, and the pyrolysis temperature was 800 °C, which can almost degrade all the BPA in 60 min. FeMn@N-BC/PS system with high catalytic efficiency and low consumables is promising for reuse of waste resources and the remediation of wastewater.