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Phys Chem Chem Phys ; 16(43): 23908-14, 2014 Nov 21.
Article in English | MEDLINE | ID: mdl-25277596

ABSTRACT

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.


Subject(s)
Krypton/chemistry , Organometallic Compounds/chemistry , Xenon/chemistry , Adsorption , Noble Gases/chemistry , Organometallic Compounds/chemical synthesis , Temperature , X-Ray Diffraction
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