Carbon/copper oxide electrode materials with high atomic utilization constructed by in-situ induced growth strategy of nano metal-organic frameworks.

Carbon/metal composites derived from metal-organic frameworks (MOFs) have attracted widespread attention due to their excellent electronic conductivity, adjustable porosity, and outstanding stability. However, traditional synthesis methods are limited by the dense stereo geometry and large crystal grain size of MOFs, resulting in many metals active sites are buried in the carbon matrix. While the common strategy involves incorporating additional dispersed media into material, this leads to a decrease in practical metal content. In this study, nanosized copper-metal-organic frameworks (Cu-MOFs) are in-situ grown on surface of carbon spheres by pre-anchoring copper ions, and the hybrid composite of porous carbon/copper oxide with high copper atom utilization rate is prepared through activation and pyrolysis methods. This strategy effectively addresses the issue of insufficient exposure of metal sites, and the obtained composite material exhibits high effective copper atom utilization rate, large specific surface area (2052.3 m2·g-1), diverse pore structure, outstanding specific capacity (1076.5F·g-1 at 0.5 A·g-1), and excellent cycle stability. Furthermore, this highly atom-economical universal method has positive significance in application fields of catalysis, energy storage, and adsorption.

Dual-Site Biomacromolecule Doped Poly(3, 4-Ethylenedioxythiophene) for Bosting Both Anticoagulant and Electrochemical Performances.

Poly(3, 4-ethylenedioxythiophene) (PEDOT) as a new generation of intelligent conductive polymers, is attracting much attention in the field of tissue engineering. However, its water dispersibility, conductivity, and biocompatibility are incompatible, which limit its further development. In this work, biocompatible electrode material of PEDOT doped with sodium sulfonated alginate (SS) which contains two functional groups of sulfonic acid and carboxylic acid per repeat unit of the macromolecule. The as dual-site doping strategy simultaneously boosts anticoagulant and electrochemical performances, for example, good hydrophilicity (water contact angle of 59.40°), well dispersibility (dispersion solution unstratified in 30 days), high conductivity (4.45 S m-1), and enhanced anticoagulant property (extended activated partial thrombin time value of 59.0 s), forming an adjustable PEDOT: biomacromolecule interface; this fills the technical gap of implantable bioelectronics in terms of coagulation and thrombosis risk. At the same time, the assembled all-in-one supercapacitor with anticoagulant properties is prepared by PEDOT: sodium sulfonated alginate as electrode material and sodium alginate hydrogel as electrolyte layer. The dual-site doping strategy provides a new opinion for the design and optimization of functional conductive polymers and its applications in implantable energy storage fields.