ABSTRACT
The combination of nuclear and electron magnetic resonance techniques, in pulse and continuous wave regimes, is used to unravel the nature and features of the light-induced magnetic state arising at the surface of chemically prepared zinc oxide nanoparticles (NPs) occurring under 120 K when subjected to a sub-bandgap (405 nm) laser excitation. It is shown that the four-line structure observed around g â¼ 2.00 in the as-grown samples (beside the usual core-defect signal at g â¼ 1.96) arises from surface-located methyl radicals (â¢CH3), originating from the acetate capped ZnO molecules. By functionalizing the as-grown zinc oxide NPs with deuterated sodium acetate, the â¢CH3 electron paramagnetic resonance (EPR) signal is replaced by trideuteromethyl (â¢CD3). For â¢CH3, â¢CD3, and core-defect signals, an electron spin echo is detected below â¼100 K, allowing for the spin-lattice and spin-spin relaxation-time measurements for each of them. Advanced pulse-EPR techniques reveal the proton or deuteron spin-echo modulation for both radicals and give access to small unresolved superhyperfine couplings between adjacent â¢CH3. In addition, electron double resonance techniques show that some correlations exist between the different EPR transitions of â¢CH3. These correlations are discussed as possibly arising from cross-relaxation phenomena between different rotational states of radicals.
ABSTRACT
An ultrasharp photoluminescence line intimately related to antiferromagnetic order has been found in NiPS_{3}, a correlated van der Waals material, opening prospects for magneto-optical coupling schemes and spintronic applications. Here we unambiguously clarify the singlet origin of this excitation, confirming its roots in the spin structure. Based on a comprehensive investigation of the electronic structure using angle-resolved photoemission and q-dependent electron energy loss spectroscopy as experimental tools we develop, in a first step, an adequate theoretical understanding using density functional theory (DFT). In a second step the DFT is used as input for a dedicated multiplet theory by which we achieve excellent agreement with available multiplet spectroscopy. Our Letter connects the understanding of the electronic structure and of optical processes in NiPS_{3} and related materials as a prerequisite for further progress of the field.
ABSTRACT
The effects of white-light irradiation on â¼15 nm diameter ZnO nanoparticles are investigated by means of electron paramagnetic resonance, near liquid-nitrogen and liquid-helium temperatures. Under dark conditions, usual core- and surface-defects are detected, respectively, at g = 1.960 and g = 2.003. Under white-light illumination, the core-defect signal intensity is strongly increased, which is to be correlated to the light-induced conductivity's augmentation. Beside, a four-lines structure appears, with the same gravity center as that of the surface defects. Simulations and intensity power-dependence measurements show that this four-line-structure is very likely to arise from a localized high spin S = 2, induced by light irradiation, and subjected to a weak axial anisotropy. At 85 K, this high-spin state can last several hours after the light-irradiation removal, probably due to highly spin-forbidden recombination process. The possible excited resonant complexes at the origin of this signal are discussed. Other light-induced S = 1/2-like centers are detected as well, which depend on the nanoparticles growth conditions.
ABSTRACT
Zinc oxide (ZnO) nanorods grown by the low-temperature (90 °C) aqueous chemical method with different cobalt concentration within the synthesis solution (from 0% to 15%), are studied by electron paramagnetic resonance (EPR), just above the liquid helium temperature. The anisotropic spectra of substitutional Co2+ reveal a high crystalline quality and orientation of the NRs, as well as the probable presence of a secondary disordered phase of ZnO:Co. The analysis of the EPR spectra indicates that the disappearance of the paramagnetic native core-defect (CD) at [Formula: see text] is correlated with the apparition of the Co2+ ions lines, suggesting a gradual neutralization of the former by the latter. We show that only a little amount of cobalt in the synthesis solution (about 0.2%) is necessary to suppress almost all these paramagnetic CDs. This gives insight in the experimentally observed improvement of the crystal quality of diluted ZnO:Co nanorods, as well as into the control of paramagnetic defects in ZnO nanostructures.
ABSTRACT
Pure and cobalt-doped zinc oxide aligned nanorods have been grown by the low-temperature (90 °C) aqueous chemical method on amorphous ZnO seed layer, deposited on a sapphire substrate. High crystallinity of these objects is demonstrated by the electron paramagnetic resonance investigation at liquid helium temperature. The successful incorporation of Co2+ ions in substitution of Zn2+ ones in the ZnO matrix has also been confirmed. A drastic reduction of intrinsic ZnO nanorods core defects is observed in the Co-doped samples, which enhances the structural quality of the NRs. The quantification of substitutional Co2+ ions in the ZnO matrix is achieved by comparison with a reference sample. The findings in this study indicate the potential of using the low-temperature aqueous chemical approach for synthesizing material for spintronics applications.
ABSTRACT
A judicious analysis of previously published experimental data leads one to conclude that the ground state of iron(II) phthalocyanine is an orbitally degenerate spin triplet a(1g)(2) e(g)(↑↓↑) b(2g)(↑) ((3)Eg). The ligand field parameters, in relation to Racah's C, are approximately as follows: B20∕C = 0.84, B40∕C = 0.0074. The uniqueness of this result is demonstrated by means of a special diagram in the B20∕C - B40∕C plane (under additional conditions that B44∕B40 = 35∕3 and B∕C = 0.227). The system is in a strong-ligand-field regime, which enables the use of single-determinant techniques corrected for correlations within the 3d shell of Fe.