ABSTRACT
We fabricated nanosized KMgF3 single crystals via a dry pulsed laser ablation process using femtosecond laser pulses. The sizes, shapes, and crystallographic properties of the crystals were evaluated by transmission electron microscopy (TEM). Almost all of the particles were spherical with diameters of less than 100 nm, and they were not highly agglomerated. Selected-area electron diffraction and high-resolution TEM analyses showed that the particles were single crystals. Particle diameter was controlled within a wide range by adjusting the Ar ambient gas pressure. Under low gas pressures (1 and 10 Pa), relatively small particles (primarily 10 nm or less) were observed with a high number density. With increasing pressure, the mean diameter increased and the number density drastically decreased. Vacuum-ultraviolet cathodoluminescence was observed at 140-230 nm with blue shift and broadening of spectrum.
ABSTRACT
A vacuum ultraviolet (VUV) field emission lamp was developed by using a neodymium ion doped lutetium fluoride (Nd(3+) : LuF3) thin film as solid-state phosphor and carbon nanofiber field electron emitters. The thin film was synthesized by pulsed laser deposition and incorporated into the lamp. The cathodoluminescence spectra of the lamp showed multiple emission peaks at 180, 225, and 255 nm. These emission spectra were in good agreement with the spectra reported for the Nd(3+) : LuF3 crystal. Moreover, application of an acceleration voltage effectively increased the emission intensity. These results contribute to the performance enhancement of the lamp operating in the VUV region.
Subject(s)
Electrons , Lutetium/chemistry , Neodymium/chemistry , Humans , Luminescent Measurements , Ultraviolet RaysABSTRACT
Experimental results are presented on the neutron scintillating properties of a custom-designed Pr3+ (praseodymium)-doped lithium (Li) glass. Luminescence was observed at 278 nm wavelength, originating from the 5d-4f transition. Time-resolved measurements yielded about 20 ns decay times for ultraviolet and x-ray excitation while much faster decay times of about 6 ns were observed for alpha particle and neutron excitation. Actual time-of-flight data in laser fusion experiments at the GEKKO XII facility of the Institute of Laser Engineering, Osaka University reveal that it can clearly discriminate fusion neutrons from the much stronger x-rays signals. This material can promise improved accuracy in future scattered neutron diagnostics.