Multimaterial Additively Manufactured Metamaterials Functionalized with Customizable Thermal Expansion in Multiple Directions.

Metamaterials functionalized with customizable multidirectional coefficient of thermal expansion (CTE) are urgently needed for advanced shape control or dimensional stability under temperature variations. The currently reported metamaterials still lack the development of diverse base material systems and exploration of the multimaterial fabrication process. Especially, the reported range of customizable CTEs for metamaterials in multiple directions is limited within [-68.1, 56.4] ppm/°C. Here, this work explicitly proposes a strategy for closely linking base materials, additive manufacturing (AM) process, architecture, and CTE tunability, in order to provide a general guideline for the design or customization of such metamaterials. In detail, first, we systematically identify the key process parameters and related performance for additive manufacturing of polymers and propose various multimaterial systems such as polypropylene-polycarbonate (PP-PC). Then, six types of metamaterials have been fabricated with high quality by the established multimaterial additive manufacturing. By measuring the effective CTEs in multiple directions, the CTE tunability of metamaterials, including large positive values (+523.36 ppm/°C) and large negative values (-230.61 ppm/°C), far beyond the literature-reported CTE range, has been experimentally verified. Further, we have developed a bidirectional requirement-solution strategy here that acts as a bridge between design and fabrication. This work opens advanced avenues for metamaterials with multidirectionally customizable and extensive CTE tunability for a variety of engineering applications such as actuators, thermal stress relief, and improved structural stability.

Bifunctional Metamaterials Incorporating Unusual Geminations of Poisson's Ratio and Coefficient of Thermal Expansion.

Natural materials overwhelmingly shrink laterally under stretching and expand upon heating. Through incorporating Poisson's ratio and coefficient of thermal expansion (PR and CTE) in unusual geminations, such as positive PR and negative CTE, negative PR and positive CTE, and even zero PR and zero CTE, bifunctional metamaterials would generate attractive shape control capacity. However, reported bifunctional metamaterials are only theoretically constructed by simple skeletal ribs, and the magnitudes of the bifunctions are still in quite narrow ranges. Here, we propose a methodology for generating novel bifunctional metamaterials consisting of engineering polymers. From concept to refinement, the topology and shape optimization are integrated for programmatically designing bifunctional metamaterials in various germinations of the PR and CTE. The underlying deformation mechanisms of the obtained bifunctions are distinctly revealed. All of the designs with complex architectures and material layouts are fabricated using the multimaterial additive manufacturing, and their effective properties are experimentally characterized. Good agreements of the design, simulation, and experiments are achieved. Especially, the accessible range of the bifunction, namely, PR and CTE, is remarkably enlarged nearly 4 times. These developed approaches open an avenue to explore the bifunctional metamaterials, which are the basis of myriad mechanical- and temperature-sensitive devices, e.g., morphing structures and high-precision components of the sensors/actuators in aerospace and electronical domains.