Enhancing Performance and Stability of p-i-n Perovskite Solar Cells with Ag-Cu Codeposited Alloy Electrodes.

In the development of back electrodes for perovskite solar cells (PSCs), the major challenges are stability and cost. To address this, we present an innovative approach: Simultaneous evaporation of two independently controlled sources of metal materials was performed to achieve a uniform distribution of the alloy electrodes. In this study, Ag-Cu alloys (the molar ratio of Ag/Cu is 7/3) with a high-index crystal face (111) and a work function matching perovskite were prepared using a codeposition technique. These properties mitigate nonradiative carrier recombination at the interface and reduce the energy barrier for carrier migration. Consequently, compared to Ag based PSCs (22.77%), the implementation of Ag-Cu alloy (Ag/Cu is 7/3)-based PSCs resulted in a power conversion efficiency of 23.72%. In a 1500 h tracking test in ambient air, the Ag-Cu alloy (Ag/Cu is 7/3)-based PSCs maintained their initial efficiency of 86%. This can be attributed to almost no migration of elements from the Ag-Cu alloy electrode to the perovskite layer. Our work presents a vital strategy for improving the stability of PSCs and reducing the costs associated with the back electrode in PSCs.

Structural identification of carbohydrate isomers using ambient infrared-assisted dissociation.

Informative dissociation of carbohydrates using an infrared (IR) irradiation system is demonstrated under ambient conditions without the instrumentation of a mass spectrometer. Structural identification of carbohydrates and associated conjugates is essential for understanding their biological functions, but identification remains challenging. Herein, an easy and rugged method is reported for the structural identification of model carbohydrates, including Globo-H, three trisaccharide isomers (nigerotriose/laminaritriose/cellotriose), and two hexasaccharide isomers (laminarihexaose/isomaltohexaose). For Globo-H, the numbers of cross-ring cleavages increased by factors of 4.4 and 3.4 upon ambient IR exposure, compared to an untreated control and a collision-induced dissociation (CID) sample. Moreover, 25-82% enhancement in the numbers of glycosidic bond cleavages upon ambient IR exposure was also obtained compared to untreated and CID samples. Unique features of first-generation fragments produced by ambient IR facilitated the differentiation of three trisaccharide isomers. Semi-quantitative analysis was achieved (coefficient of determination (R2) of 0.982) in a mixture of two hexasaccharide isomers via unique features generated upon ambient IR. Photothermal and radical migration effects induced by ambient IR were postulated as responsible for promoting carbohydrate fragmentation. This easy and rugged method could be a universally applicable protocol and complementary to other techniques for detailed structural characterization of carbohydrates.

Event-Triggered Approximate Optimal Path-Following Control for Unmanned Surface Vehicles With State Constraints.

This article investigates the problem of path following for the underactuated unmanned surface vehicles (USVs) subject to state constraints. A useful control algorithm is proposed by combining the backstepping technique, adaptive dynamic programming (ADP), and the event-triggered mechanism. The presented approach consists of three modules: guidance law, dynamic controller, and event triggering. First, to deal with the "singularity" problem, the guidance-based path-following (GBPF) principle is introduced in the guidance law loop. In contrast to the traditional barrier Lyapunov function (BLF) method, this article converts the USV's constraint model to a class of nonlinear systems without state constraints by introducing a nonlinear mapping. The control signal generated by the dynamic controller module consists of a backstepping-based feedforward control signal and an ADP-based approximate optimal feedback control signal. Therefore, the presented scheme can guarantee the approximate optimal performance. To approximate the cost function and its partial derivative, a critic neural network (NN) is constructed. By considering the event-triggered condition, the dynamic controller is further improved. Compared with traditional time-triggered control methods, the proposed approach can greatly reduce communication and computational burdens. This article proves that the closed-loop system is stable, and the simulation results and experimental validation are given to illustrate the effectiveness of the proposed approach.

Sliding mode control for networked control systems: A brief survey.

In recent years, the control synthesis and analysis of networked control systems (NCSs) have attracted increasing attention from both industrial and scientific communities, and many contributions have been published. With the development of advanced control theories, it has become a trend to combine networks with control systems. As a specific nonlinear control method, due to its complete robustness on the sliding mode surface, sliding mode control (SMC) becomes an effective means to solve the uncertainties and nonlinear characteristics in NCSs. In this paper, a review of the recent advances and challenges of SMC in NCSs is given. Firstly, a brief introduction to NCSs is given and the essential technical constraints are also summarized. Then, the results of the SMC applied to NCSs with basic constraints, including packet dropouts, time delays and signal quantization are given in details. Finally, some concluding remarks are made and several potential future research topics are discussed.

Synthesis and Toxicity of Halogenated Bisphenol Monosubstituted-Ethers: Establishing a Library for Potential Environmental Transformation Products of Emerging Contaminant.

As an important branch of halogenated bisphenol compounds, the halogenated bisphenol monosubstituted-ether compounds have received a lot of attention in environmental health science because of their toxicity and variability. In this study, a synthetic method for bisphenol monosubstituted-ether byproduct libraries was developed. By using the versatile and efficient method, tetrachlorobisphenol A, tetrabromobisphenol A, and tetrabromobisphenol S monosubstituted alkyl-ether compounds were accessed in 39-82 % yield. Subsequently, the cytotoxicity of 27 compounds were screened using three different cell lines (HepG2, mouse primary astrocytes and Chang liver cells). Compound 2,6-dibromo-4-[3,5-dibromo-4-(2-hydroxyethoxy)benzene-1-sulfonyl]phenol was more toxic than other compounds in various cells, and the sensitivity of this compound to the normal hepatocytes and cancer cells was inconsistent. The compounds 2,6-dichloro-4-(2-{3,5-dichloro-4-[(prop-2-en-1-yl)oxy]phenyl}propan-2-yl)phenol and 2,6-dibromo-4-(2-{3,5-dibromo-4-[(prop-2-en-1-yl)oxy]phenyl}propan-2-yl)phenol were the most toxic to HepG2 cells, and most of the other compounds inhibited cell proliferation. Moreover, typical compounds were also reproductive and developmental toxic to zebrafish embryos at different concentrations. The synthetic byproduct libraries could be used as pure standard compounds and applied in research on environmental behavior and the transformation of halogenated flame retardants.

Controllable Synthesis of Graphdiyne Nanoribbons.

Graphdiyne nanoribbons with high chemical precision are of great significance for further understanding of the intrinsic properties of graphdiyne and the relationship between structure and properties. However, the reliable synthesis of graphdiyne nanoribbons with chemical precision remains a significant challenge. A facile method is now presented for fabrication of graphdiyne nanoribbons with uniform width through stepwise inter- and intramolecular Glaser-Hay coupling reaction of ethynyl groups. The synthetic ribbons were interwoven into nanotextiles by π-π stacking and were applied for protective coating of Li-electrode in Li-ion batteries, which efficiently suppressed the growth of the Li dendrites during cycling and prolonged the life span of Li-metal batteries.

X-Shaped Polycyclic Aromatic Hydrocarbons: Optical Properties and Tunable Assembly Ability.

Although a number of synthetic methodologies have been developed to prepare stable polycyclic aromatic hydrocarbons (PAHs), much less research has been devoted to functionalizing the peripheries of molecules to tune the self-assembly ability or introduce functional groups without altering their photophysical properties. Herein, we report twisted "X"-shaped molecules prepared through annulation of hexacene with benzoanthracene on the zigzag edge, and an investigation of their photophysical properties and self-assembly properties. The shape-complementary "X"-shaped molecules prefer to dimerize, while the π-extension would lead to one-dimensional π-stacking. Our findings give some insights into the design of stable PAHs without disturbing the electronic structures.

Direct Synthesis of Crystalline Graphdiyne Analogue Based on Supramolecular Interactions.

The synthesis of graphdiyne with an ordered internal structure is highly attractive for its various scientific and application investigations. We reported herein a rational method to fabricate a graphdiyne analogue with the help of supramolecular chemistry. The introduction of π-π/CH-π interactions controlled the conformations of the precursors and afforded multilayer graphdiyne analogue Ben-GDY through the wet chemical method. The in-plane periodicity of the multilayer Ben-GDY was corroborated by transmission electron microscopy and selected area electron diffraction, which showed a pattern well matched with ABC-style stacking.