Interface designing of efficient Z-scheme Ti-ZnFe2O4/In2O3 photoanode toward boosting photoelectrochemical water oxidation.

Ti-ZnFe2O4 photoanode has attracted extensive attention in photoelectrochemical (PEC) water oxidation due to its narrow band gap and good photostability. However, its low efficiency limits its development. Herein, we designed and constructed direct Z-scheme Ti-ZnFe2O4/In2O3 (Ti-ZFO/In2O3) photoanode. Under the interface electric field, photogenerated holes with stronger oxidation capacity on In2O3 are retained to participate in the water oxidation reaction, and the photocurrent density of Ti-ZFO/In2O3 is much higher than that of pure Ti-ZFO, reaching 2.2 mA/cm2 at 1.23 V vs. RHE. Kelvin Probe, steady-state photovoltage spectroscopy (SPV), transient photovoltage spectroscopy (TPV) and in-situ double beam strategy were used to demonstrate the Z-scheme charge transfer mechanism of Ti-ZFO/In2O3 photoanode. Our work provides an effective scheme and technical means for further understanding the mechanism of interfacial charge transfer.

BiOCl Heterojunction photocatalyst: Construction, photocatalytic performance, and applications.

BiOCl semiconductors have attracted extensive amounts of attention and have substantial potential in alleviating energy shortages, improving sterilization performance, and solving environmental issues. To improve the optical quantum efficiency of layered BiOCl, the lifetimes of photogenerated electron-hole pairs, and BiOCl reduction capacity. During the past decade, researchers have designed many effective methods to weaken the effects of these limitations, and heterojunction construction is regarded as one of the most promising strategies. In this paper, BiOCl heterojunction photocatalysts designed and synthesized by various research groups in recent years were reviewed, and their photocatalytic properties were tested. Among them, direct Z-scheme and S-scheme photocatalysts have high redox potentials and intense redox capabilities. Hence, they exhibit excellent photocatalytic activity. Furthermore, the applications of BiOCl heterojunctions for pollutant degradation, CO2 reduction, water splitting, N2 fixation, organic synthesis, and tumor ablation are also reviewed. Finally, we summarize research on the BiOCl heterojunctions and put forth new insights on overcoming their present limitations.

Interfacial internal electric field and oxygen vacancies synergistically enhance photocatalytic performance of bismuth oxychloride.

Solar-to-chemical energy conversion is valuable and sustainable strategy for energy and environmental crisis through photocatalysis. The amorphous SnOx modified BiOCl (Sn-BiOCl) full-spectrum-responsive catalysts were designed and synthesized through solvothermal method. The introduced Sn regulates the growth of BiOCl to form ultrathin nanosheets with surface oxygen vacancies. And the surface modification of SnOx induces interfacial internal electric field via charge redistribution on the interface of BiOCl and SnOx to accelerate the photogenerated charge separation. The modification of SnOx decreased work function of Sn-BiOCl and thus elevated its conduction band and valence band simultaneously, leading enhanced photocatalytic reducibility with the improved generation rate of ·O2-. The surface SnOx and oxygen vacancies of Sn-BiOCl broadened light absorption range and enhanced photocatalytic performance synergistically, resulting in 14-fold increased photodegradation rate of phenol compared with pure BiOCl under full spectrum. This method is also able to expand to other metal ions (such as Fe3+, In3+ and Sb3+). This work provides a valuable concept in structure regulating for enhanced photocatalytic performance in the removal of organic pollutants by interfacial internal electric field and surface oxygen vacancies.