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1.
PLoS One ; 19(7): e0307109, 2024.
Article in English | MEDLINE | ID: mdl-39024367

ABSTRACT

The prevention and control of natural gas hydrates is an important link in ensuring winter production. Traditional thermodynamic inhibitors, like methanol, are commonly utilized due to their low unit costs and pricing, but they come with considerable safety issues when used on-site due to their high toxicity, flammability, and explosive potential. A cost-effective and eco-friendly hydrate inhibitor was created by combining light polyol amine with other ingredients to solve this problem. At a concentration of 30%, the product has a flash point greater than 80°C and a solidification point of -45°C. With success rates of 99% and 100%, respectively, it was used for winter casing pre-injection anti-freezing operations and balancing tank defoamer anti-freezing operations. Experiments have demonstrated the effectiveness of this inhibitor in preventing the formation of natural gas hydrates. In wintertime on-site anti-freezing activities, the projected cost can be substituted for methanol, as it is essentially equivalent to methanol.


Subject(s)
Natural Gas , Water/chemistry , Seasons , Thermodynamics
2.
Environ Sci Pollut Res Int ; 31(33): 45970-46001, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38981964

ABSTRACT

Natural gas hydrate (NGH) is a significant alternative energy resource in achieving carbon neutrality. The developmental trend and competitive landscape of NGH exploitation and production are crucial for policymakers in government, managers of enterprises, and researchers. This study introduces a novel framework for conducting an in-depth analysis of NGH, integrating patentometrics, technology evolution, and correlation relationships to monitor developmental trends and competitive landscape through patent analysis. The results indicate that China, the USA, and Japan have distinct technology advantages. Current technological developments in the NGH field focus primarily on extraction technologies, equipment, and processing systems. The co-opetition analysis among countries reveals that the most extensive international cooperation network is primarily in Europe and the USA, with national partnerships in Asia concentrated in China and Japan. Institutional cooperation remains limited, primarily within universities in China, while both the USA and Japan foster collaboration between enterprises. The competitive landscapes of key NGH-related technologies among countries and institutions are also examined. This study contributes not only to monitoring the developmental trend and competitive landscape in NGH but also to providing policy recommendations for government and enterprises regarding strategic management and collaborative innovation.


Subject(s)
Natural Gas , China , Japan , United States , Patents as Topic
3.
Annu Rev Chem Biomol Eng ; 15(1): 63-80, 2024 Jul.
Article in English | MEDLINE | ID: mdl-39047722

ABSTRACT

Hydrogen is similar to natural gas in terms of its physical and chemical properties but does not release carbon dioxide when burnt. This makes hydrogen an energy carrier of great importance in climate policy, especially as an enabler of increasing integration of volatile renewable energy, progressive electrification, and effective emission reductions in the hard-to-decarbonize sectors. Leaving aside the problems of transporting hydrogen as a liquid, technological challenges along the entire supply chain can be considered as solved in principle, as shown in the experimental findings of the Hydrogen Innovation Program of the German Technical and Scientific Association for Gas and Water. By scaling up production and end-use capacities and, most importantly, producing hydrogen in regions with abundant renewable energy, hydrogen and its applications can displace natural gas at affordable prices in the medium term. However, this substitution will take place at different rates in different regions and with different levels of added value, all of which must be understood for hydrogen uptake to be successful.


Subject(s)
Hydrogen , Natural Gas , Hydrogen/chemistry , Natural Gas/analysis , Renewable Energy , Carbon Dioxide/chemistry
4.
Sci Total Environ ; 945: 174080, 2024 Oct 01.
Article in English | MEDLINE | ID: mdl-38906281

ABSTRACT

Reverse osmosis (RO) plays a pivotal role in shale gas wastewater resource utilization. However, managing the reverse osmosis concentrate (ROC) characterized by high salinity and increased concentrations of organic matter is challenging. In this study, we aimed to elucidate the enhancement effects and mechanisms of pre-ozonation on organic matter removal efficacy in ROC using a biological activated carbon (BAC) system. Our findings revealed that during the stable operation phase, the ozonation (O3 and O3/granular activated carbon)-BAC system removes 43.6-72.2 % of dissolved organic carbon, achieving a 4-7 fold increase in efficiency compared with that in the BAC system alone. Through dynamic analysis of influent and effluent water quality, biofilm performance, and microbial community structure, succession, and function prediction, we elucidated the following primary enhancement mechanisms: 1) pre-ozonation significantly enhances the biodegradability of ROC by 4.5-6 times and diminishes the organic load on the BAC system; 2) pre-ozonation facilitates the selective enrichment of microbes capable of degrading organic compounds in the BAC system, thereby enhancing the biodegradation capacity and stability of the microbial community; and 3) pre-ozonation accelerates the regeneration rate of the granular activated carbon adsorption sites. Collectively, our findings provide valuable insights into treating ROC through pre-oxidation combined with biotreatment.


Subject(s)
Charcoal , Osmosis , Ozone , Waste Disposal, Fluid , Wastewater , Waste Disposal, Fluid/methods , Wastewater/chemistry , Charcoal/chemistry , Biodegradation, Environmental , Water Pollutants, Chemical/analysis , Natural Gas
5.
Environ Sci Technol ; 58(27): 12018-12027, 2024 Jul 09.
Article in English | MEDLINE | ID: mdl-38875010

ABSTRACT

The timely detection of underground natural gas (NG) leaks in pipeline transmission systems presents a promising opportunity for reducing the potential greenhouse gas (GHG) emission. However, existing techniques face notable limitations for prompt detection. This study explores the utility of Vegetation Indicators (VIs) to reflect vegetation health deterioration, thereby representing leak-induced stress. Despite the acknowledged potential of VIs, their sensitivity and separability remain understudied. In this study, we employed ground vegetation as biosensors for detecting methane emissions from underground pipelines. Hyperspectral imaging from vegetation was collected weekly at both plant and leaf scales over two months to facilitate stress detection using VIs and Deep Neural Networks (DNNs). Our findings revealed that plant pigment-related VIs, modified chlorophyll absorption reflectance index (MCARI), exhibit commendable sensitivity but limited separability in discerning stressed grasses. A NG-specialized VI, the optimized soil-adjusted vegetation index (OSAVI), demonstrates higher sensitivity and separability in early detection of methane leaks. Notably, the OSAVI proved capable of discriminating vegetation stress 21 days after methane exposure initiation. DNNs identified the methane leaks following a 3-week methane treatment with an accuracy of 98.2%. DNN results indicated an increase in visible (VIS) and a decrease in near-infrared (NIR) in spectra due to methane exposure.


Subject(s)
Natural Gas , Neural Networks, Computer , Environmental Monitoring/methods , Hyperspectral Imaging , Methane/analysis
6.
J Environ Manage ; 364: 121459, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38870798

ABSTRACT

The current trend in the European biogas industry is to shift away from electricity production towards the production of biomethane for the need to replace natural gas. The upgrading of biogas to biomethane is normally performed by separating the biogas in a stream containing natural gas grid quality methane and a stream containing mostly CO2. The CO2 stream is normally released into the atmosphere; however, part of the methane may still remain in it, and, if not oxidized, even a small fraction of methane released may jeopardise all the GHG emissions savings from producing the biomethane, being methane a powerful climate forcer. Scope of this work is to assess the opportunity cost of installing an Off Gas Combustion (OGC) device in biomethane upgrading plants. The currently available technologies for biogas upgrading to biomethane and the most common technology of OGC (the Regenerative Thermal Oxidisers, RTO) are described according to their performances and cost. Then the cost per tonne of CO2eq avoided associated to the adoption of RTO systems in relation to the upgrading performance is calculated to identify a potential threshold for an effective and efficient application of the RTO systems. It is found that, in case of upgrading technologies which can capture almost all biomethane in the upgrading off-gas (i.e. 99.9%), currently the adoption of an RTO to oxidise the methane left in the off-gas would add costs and need additional fuel to be operated, but would generate limited GHG emission savings, therefore the cost per tonne of CO2eq emissions avoided would result not competitive with other GHG emissions mitigation investments. While the installation of RTOs on upgrading systems with a methane slip of 0.3%, or higher, normally results cost competitive in reducing GHG emissions. The installation of an RTO on systems with a methane slip of 0.2% results in a cost per tonne of CO2eq emissions avoided of 50-100 euro, which is comparable to the current cost of CO2 emissions allowances in the EU ETS carbon market, representing therefore a reasonable choice for a threshold on methane slip regulation for biogas upgrading systems.


Subject(s)
Biofuels , Carbon Dioxide , Greenhouse Gases , Methane , Greenhouse Gases/analysis , Carbon Dioxide/analysis , Greenhouse Effect , Natural Gas
7.
Environ Sci Pollut Res Int ; 31(29): 42160-42173, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38861060

ABSTRACT

The world faces several problems related to natural gas resource rents and energy production from renewable sources. One of the main problems is the influence of energy imports, manufacturing exports, and alternative energy sources on natural gas and electricity production from renewable sources. Energy imports, manufacturing exports, and alternative energy sources can impact natural gas and electricity production. This paper examines natural gas resource rents and electricity production from renewable sources nexus from 1971 to 2021, using energy imports, manufacturer's exports, and alternative energy sources in China. Electricity production from renewable sources and manufacturing exports are negatively associated with natural gas resource rents. Energy imports and alternative energy sources positively relate to natural gas resource rents in China. These results suggest that the energy sector in China is highly interconnected and that policies that seek to promote renewable energy sources and other alternatives can positively affect natural gas resource rents. China needs to develop an energy policy considering the policy implications of energy imports and natural gas resource rents. Such a policy should focus on increasing domestic production, reducing energy imports, and ensuring adequate revenue from natural gas resource rents. Additionally, regulations could be implemented that support the development of alternative energy sources, such as requiring utilities to purchase a certain percentage of their power from renewable sources.


Subject(s)
Electricity , Natural Gas , Renewable Energy , China , Nuclear Energy
8.
Environ Sci Pollut Res Int ; 31(26): 38367-38384, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38805134

ABSTRACT

This study adopts a new approach to reassess the factors influencing urban energy intensity in China. Initially, the factors impacting energy intensity are classified into controllable and uncontrollable categories. Subsequently, employing a single-factor multi-stage method combined with the Adaboost method, 289 Chinese cities are categorized based on uncontrollable factors to eliminate the influence of inherent differences on energy intensity. Finally, panel data regression analyses are conducted using data from 289 Chinese cities between 2005 and 2016, individually for each city type, to evaluate the extent to which controllable factors contribute to energy intensity. The findings indicate that (1) heightened energy prices, an increased share of electricity consumption, and a greater proportion of centralized heating significantly influence the reduction of energy intensity across all city types; (2) to optimize energy consumption, each city type should adopt specific strategies. For instance, cities located in resource-rich heating regions with low economic outputs can reduce their energy intensity by increasing electricity consumption, while cities with high economic outputs can decrease their energy intensity by increasing natural gas consumption. The findings of this study carry substantial implications for the Chinese government in shaping targeted energy policies tailored to different city types.


Subject(s)
Cities , China , Electricity , Energy-Generating Resources , Natural Gas
9.
Sci Rep ; 14(1): 11996, 2024 05 25.
Article in English | MEDLINE | ID: mdl-38796638

ABSTRACT

Different from the Qaidam basin with about 320 billion m3 microbial gas, only limited microbial gases were found from the Junggar basin with similarly abundant type III kerogen. To determine whether microbial gases have not yet identified, natural gas samples from the Carboniferous to Cretaceous in the Junggar basin have been analyzed for chemical and stable isotope compositions. The results reveal some of the gases from the Mahu sag, Zhongguai, Luliang and Wu-Xia areas in the basin may have mixed with microbial gas leading to straight ethane to butane trends with a "dogleg" light methane in the Chung's plot. Primary microbial gas from degradation of immature sedimentary organic matter is found to occur in the Mahu sag and secondary microbial gas from biodegradation of oils and propane occurred in the Zhongguai, Luliang and Beisantai areas where the associated oils were biodegraded to produce calcites with δ13C values from + 22.10‰ to + 22.16‰ or propane was biodegraded leading to its 13C enrichment. Microbial CH4 in the Mahu sag is most likely to have migrated up from the Lower Wuerhe Formation coal-bearing strata by the end of the Triassic, and secondary microbial gas in Zhongguai and Beisantan uplifts may have generated after the reservoirs were uplifted during the period of the Middle and Late Jurassic. This study suggests widespread distribution of microbial gas and shows the potential to find large microbial gas accumulation in the basin.


Subject(s)
Methane , Natural Gas , Methane/analysis , Methane/metabolism , Natural Gas/analysis , Gases/metabolism , Gases/analysis , China , Geologic Sediments/microbiology , Geologic Sediments/chemistry , Geologic Sediments/analysis , Carbon Isotopes/analysis
10.
Chemosphere ; 359: 142259, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38723692

ABSTRACT

6-Methylquinoline (6-MQ) is identified as a high-concentration organic compound pervasive in shale gas wastewater (SGW) and poses a significant risk of environmental pollution. In response, this study aimed to address these challenges by introducing an innovative electrochemical membrane constructed with multi-walled carbon nanotubes (CNTs) for the removal of 6-MQ. The investigation systematically explored the impact of voltage, initial pollutant concentration, and salinity on the performance of the electrochemical CNTs filter. It was found a positive correlation between removal efficiency and increasing voltage and salinity levels. Conversely, as the initial concentration of pollutants increased, the efficiency showed a diminishing trend. The electrochemical CNTs filter exhibited remarkable efficacy in both adsorption removal and electrochemical oxidation of 6-MQ. Notably, the CNTs membrane exhibited robust adsorption capabilities, evidenced by the sustained adsorption of 6-MQ for over 33 h. Furthermore, applying an electrochemical oxidation voltage of 3 V consistently maintained a removal rate exceeding 34.0% due to both direct and indirect oxidation, underscoring the sustained efficacy of the electrochemical membranes. Besides, real wastewater experiments, while displaying a reduction in removal efficiency compared to synthetic wastewater experiments, emphasized the substantial potential of the electrochemical CNTs filter for practical applications. This study underscores the significant promise of electrochemical membranes in addressing low molecular weight contaminants in SGW, contributing valuable insights for advancing SGW treatment strategies.


Subject(s)
Nanotubes, Carbon , Quinolines , Wastewater , Water Pollutants, Chemical , Nanotubes, Carbon/chemistry , Wastewater/chemistry , Adsorption , Water Pollutants, Chemical/chemistry , Water Pollutants, Chemical/analysis , Quinolines/chemistry , Electrochemical Techniques/methods , Natural Gas , Filtration/methods , Oxidation-Reduction , Waste Disposal, Fluid/methods
11.
J Environ Manage ; 360: 121091, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38761617

ABSTRACT

In an exploration of environmental concerns, this groundbreaking research delves into the relationship between GDP per capita, coal rents, forest rents, mineral rents, oil rents, natural gas rents, fossil fuels, renewables, environmental tax and environment-related technologies on CO2 emissions in 30 highly emitting countries from 1995 to 2021 using instrumental-variables regression Two-Stage least squares (IV-2SLS) regression and two-step system generalized method of moments (GMM) estimates. Our results indicate a significant positive relationship between economic growth and CO2 emissions across all quantiles, showcasing an EKC with diminishing marginal effects. Coal rents exhibit a statistically significant negative relationship with emissions, particularly in higher quantiles, and mineral rents show a negative association with CO2 emissions in lower and middle quantiles, reinforcing the idea of resource management in emissions reduction. Fossil fuels exert a considerable adverse impact on emissions, with a rising effect in progressive quantiles. Conversely, renewable energy significantly curtails CO2 emissions, with higher impacts in lower quantiles. Environmental tax also mitigates CO2 emissions. Environment-related technologies play a pivotal role in emission reduction, particularly in lower and middle quantiles, emphasizing the need for innovative solutions. These findings provide valuable insights for policymakers, highlighting the importance of tailoring interventions to different emission levels and leveraging diverse strategies for sustainable development.


Subject(s)
Carbon Dioxide , Economic Development , Carbon Dioxide/analysis , Fossil Fuels , Conservation of Natural Resources , Natural Gas
12.
Nature ; 629(8011): 295-306, 2024 May.
Article in English | MEDLINE | ID: mdl-38720037

ABSTRACT

Fossil fuels-coal, oil and gas-supply most of the world's energy and also form the basis of many products essential for everyday life. Their use is the largest contributor to the carbon dioxide emissions that drive global climate change, prompting joint efforts to find renewable alternatives that might enable a carbon-neutral society by as early as 2050. There are clear paths for renewable electricity to replace fossil-fuel-based energy, but the transport fuels and chemicals produced in oil refineries will still be needed. We can attempt to close the carbon cycle associated with their use by electrifying refinery processes and by changing the raw materials that go into a refinery from fossils fuels to carbon dioxide for making hydrocarbon fuels and to agricultural and municipal waste for making chemicals and polymers. We argue that, with sufficient long-term commitment and support, the science and technology for such a completely fossil-free refinery, delivering the products required after 2050 (less fuels, more chemicals), could be developed. This future refinery will require substantially larger areas and greater mineral resources than is the case at present and critically depends on the capacity to generate large amounts of renewable energy for hydrogen production and carbon dioxide capture.


Subject(s)
Carbon Dioxide , Fossil Fuels , Oil and Gas Industry , Renewable Energy , Carbon Cycle , Carbon Dioxide/adverse effects , Carbon Dioxide/isolation & purification , Coal/adverse effects , Coal/supply & distribution , Fossil Fuels/adverse effects , Fossil Fuels/supply & distribution , Hydrogen/chemistry , Natural Gas/adverse effects , Natural Gas/supply & distribution , Petroleum/adverse effects , Petroleum/supply & distribution , Renewable Energy/statistics & numerical data , Oil and Gas Industry/methods , Oil and Gas Industry/trends
13.
Environ Sci Pollut Res Int ; 31(22): 32649-32663, 2024 May.
Article in English | MEDLINE | ID: mdl-38662290

ABSTRACT

The diffusion effect of the digital economy (DEN) has become increasingly prominent, but few scholars have investigated the energy transition effect of China's DEN. To this end, this study takes 207 cities in China as the research object to explore the potential role of DEN development in boosting energy resource transition (ERT). The endogeneity and asymmetry between variables are also analyzed. We find that (i) China's urban DEN and ERT show a synchronized fluctuating upward trend from 2006 to 2019; (ii) both DEN and ERT show significant positive nexus; put differently, the rapid evolution of DEN can significantly help enhance the strength of ERT; and (iii) substantial heterogeneity exists at different quantiles. In 10th and 90th quantiles, the impacts of DEN on ERT are insignificant, and both DEN and ERT exhibit significant positive linkage in 25th, 50th, and 75th quantiles. To this end, we put forward corresponding policy recommendations to boost ERT from the perspective of DEN.


Subject(s)
Cities , Natural Gas , China
14.
PLoS One ; 19(4): e0298672, 2024.
Article in English | MEDLINE | ID: mdl-38669299

ABSTRACT

Aqueous phase trapping (APT), which is one of the most prominent damages, seriously restricts the natural gas production in tight gas sandstone with low permeability. Pore size and microscopic pore structures are the most important factors to determine the water blocking damage. In this paper, 9 core samples from tight gas sandstone with various physical properties were employed, and the pore size distribution (PSD) of the core samples were investigated by high pressure mercury intrusion tests (HPMI). Results showed that the porosity of core samples ranges from 5.68% to 13.7%, and the permeability ranges from 0.00456 to 7.86 mD, which is a typical tight reservoir with strong heterogeneity. According to the HPMI capillary curve, the cores can be divided into two types: Type I and Type II, and the pore sizes of type I are larger than that of type II. Fractal distributions were obtained using HPMI data to further determine the pore structure characteristics of tight reservoirs. The pore structures of tight sandstones display the multifractal fractal feature: D1 corresponding to macro-pores, and D2 corresponding to fractal dimension of micro-pores. Furthermore, APT damage was determined by the permeability recovery ratios (Kr) after gas flooding tests. The correlation of Kr and PSD and fractal dimensions were jointly analyzed in tight gas sandstone. Although positive correlations between pore size parameters and the permeability recovery ratios were observed with relatively weak correlations, for those core samples with very close permeability, pore size parameters (both permeability and PSD) is inadequate in clarifying this damage. The fractal dimension can well describe the complexity and heterogeneity of flow channels in pores, which can become the determining factor to distinguish the flow capacity of tight sandstone. The D2 for samples of type I and type II exhibited a good negative relation with Kr with a correlation coefficient of 0.9878 and 0.7723, respectively. The significance of this finding is that for tight gas sandstone, fractal dimensions, especially the small pore fractal dimension (D2), can be used to predict the possible APT damage very well.


Subject(s)
Permeability , Porosity , Natural Gas , Water/chemistry , Fractals
15.
Chemosphere ; 355: 141834, 2024 May.
Article in English | MEDLINE | ID: mdl-38565376

ABSTRACT

Membrane fouling caused by the organics-coated particles was the main obstacle for the highly efficient shale gas produced water (SGPW) treatment and recycling. In this study, a novel hybrid electrocoagulation (EC) and E-peroxone process coupled with UF (ECP-UF) process was proposed to examine the efficacy and elucidate the mechanism for UF fouling mitigation in assisting SGPW reuse. Compared to the TMP (transmembrane pressure) increase of -15 kPa in the EC-UF process, TMP in ECP-UF system marginally increased to -1.4 kPa for 3 filtration cycles under the current density of 15 mA/cm2. Both the total fouling index and hydraulically irreversible fouling index of the ECP-UF process were significantly lower than those of EC-UF process. According to the extended Derjaguin-Landau-Verwey-Overbeek theory, the potential barriers was the highest for ECP-UF processes due to the substantial increase of the acid-base interaction energy in ECP-UF process, which was well consistent with the TMP and SEM results. Turbidity and TOC of ECP-UF process were 63.6% and 45.8% lower than those of EC-UF process, respectively. According to the MW distribution, the variations of compounds and their relative contents were probably due to the oxidation and decomposing products of the macromolecular organics. The number of aromatic compound decreased, while the number of open-chain compounds (i.e., alkenes, alkanes and alcohols) increased in the permeate of ECP-UF process. Notably, the substantial decrease in the relative abundance of di-phthalate compounds was attributed to the high reactivity of these compounds with ·OH. Mechanism study indicated that ECP could realize the simultaneous coagulation, H2O2 generation and activation by O3, facilitating the enhancement of ·OH and Alb production and therefore beneficial for the improved water quality and UF fouling mitigation. Therefore, the ECP-UF process emerges as a high-efficient and space-saving approach, yielding a synergistic effect in mitigating UF fouling for SGPW recycling.


Subject(s)
Ultrafiltration , Water Purification , Natural Gas , Hydrogen Peroxide , Membranes, Artificial , Water Purification/methods , Electrocoagulation
16.
Chemosphere ; 356: 141962, 2024 May.
Article in English | MEDLINE | ID: mdl-38614399

ABSTRACT

The impact of shale gas extraction on surrounding environmental media remains unclear. In this study, the current state of contamination by polycyclic aromatic hydrocarbons (PAHs), which are high-frequency contaminants of shale gas, was investigated in the soil surrounding emerging shale gas development sites. The source analysis of PAHs was conducted in the soils of shale gas extraction sites using positive matrix factorization (PMF). The health risk assessment (HRA) was calculated for ingestion, dermal contact, and inhalation exposures, and the priority sources of PAHs in the soil were jointly identified by PMF and HRA to refine the contribution level of different individual PAHs to the carcinogenic risk. The results showed that both Sichuan and Chongqing mining site soils were contaminated to different degrees. Shale gas extraction has an impact on the surrounding soil, and the highest contributing source of PAHs in the mining site soil of Sichuan was anthropogenic activity, accounting for 31.6%, whereas that in the mining site soil of Chongqing was biomass combustion and mixed automobile combustion, accounting for 35.9%. At the two mining sites in Sichuan and Chongqing, none of the three exposure pathways (ingestion, dermal contact, and inhalation) posed a carcinogenic risk to children, whereas the dermal exposure pathway posed a carcinogenic risk to adults. Health risk assessments based on specific source assignments indicate that when managing soil pollution, the control of fossil fuel combustion and vehicular emissions should be prioritized.


Subject(s)
Environmental Monitoring , Polycyclic Aromatic Hydrocarbons , Soil Pollutants , Soil , Polycyclic Aromatic Hydrocarbons/analysis , Soil Pollutants/analysis , Risk Assessment , Humans , Environmental Monitoring/methods , Soil/chemistry , China , Mining , Natural Gas/analysis
17.
Environ Sci Technol ; 58(15): 6575-6585, 2024 Apr 16.
Article in English | MEDLINE | ID: mdl-38564483

ABSTRACT

Wide-area aerial methods provide comprehensive screening of methane emissions from oil and gas (O & G) facilities in production basins. Emission detections ("plumes") from these studies are also frequently scaled to the basin level, but little is known regarding the uncertainties during scaling. This study analyzed an aircraft field study in the Denver-Julesburg basin to quantify how often plumes identified maintenance events, using a geospatial inventory of 12,629 O & G facilities. Study partners (7 midstream and production operators) provided the timing and location of 5910 maintenance events during the 6 week study period. Results indicated three substantial uncertainties with potential bias that were unaddressed in prior studies. First, plumes often detect maintenance events, which are large, short-duration, and poorly estimated by aircraft methods: 9.2 to 46% (38 to 52%) of plumes on production were likely known maintenance events. Second, plumes on midstream facilities were both infrequent and unpredictable, calling into question whether these estimates were representative of midstream emissions. Finally, 4 plumes attributed to O & G (19% of emissions detected by aircraft) were not aligned with any O & G location, indicating that the emissions had drifted downwind of some source. It is unclear how accurately aircraft methods estimate this type of plume; in this study, it had material impact on emission estimates. While aircraft surveys remain a powerful tool for identifying methane emissions on O & G facilities, this study indicates that additional data inputs, e.g., detailed GIS data, a more nuanced analysis of emission persistence and frequency, and improved sampling strategies are required to accurately scale plume estimates to basin emissions.


Subject(s)
Air Pollutants , Air Pollutants/analysis , Aircraft , Methane/analysis , Natural Gas/analysis
18.
Environ Sci Technol ; 58(19): 8149-8160, 2024 May 14.
Article in English | MEDLINE | ID: mdl-38652896

ABSTRACT

Environmental impacts associated with shale gas exploitation have been historically underestimated due to neglecting to account for the production or the release of end-of-pipe organic pollutants. Here, we assessed the environmental impacts of shale gas production in China and the United States using life cycle assessment. Through data mining, we compiled literature information on organic pollutants in flowback and produced water (FPW), followed by assessments using USEtox to evaluate end-of-pipe risks. Results were incorporated to reveal the life cycle risks associated with shale gas exploitation in both countries. China exhibited higher environmental impacts than the US during the production phase. Substantially different types of organic compounds were observed in the FPW between two countries. Human carcinogenic and ecological toxicity attributed to organics in FPW was 3 orders of magnitude higher than that during the production phase in the US. Conversely, in China, end-of-pipe organics accounted for approximately 52%, 1%, and 47% of the overall human carcinogenic, noncarcinogenic, and ecological impacts, respectively. This may be partially limited by the quantitative data available. While uncertainties exist associated with data availability, our study highlights the significance of integrating impacts from shale gas production to end-of-pipe pollution for comprehensive environmental risk assessments.


Subject(s)
Natural Gas , China , Risk Assessment , United States , Humans , Environmental Monitoring
19.
Environ Sci Pollut Res Int ; 31(19): 27566-27608, 2024 Apr.
Article in English | MEDLINE | ID: mdl-38592635

ABSTRACT

The gas flaring network is an inseparable constituent commonly present in most of the oil and gas refineries and petrochemical facilities conferring reliable operational parameters. The improper disposal of burn-off gases improperly results in environmental problems and loss of economic resources. In this regard, waste to energy transforming nexus, in accord with the "carbon neutrality" term, has potentially emerged as a reasonable pathway to preserve our planet. In a transdisciplinary manner, the present review article deeply outlines the different up-to-date strategies developed to recover the emitted gases (flaring minimization) into different value-added products. To analyze the recovery potential of flare gases, different technologies, and decision-making factors have been critically reviewed to find the best recovery methods. We recommend more straightforward recovery methods despite lower profits. In this regard, electricity generation seems to be an appropriate option for application in small amounts of flaring. However, several flare gas utilization processes such as syngas manufacturing, reinjection of gas into petroleum reservoirs, and production of natural gas liquid (NGL) are also recommended as options because of their economic significance, technological viability (both onshore and offshore), and environmental benefits. Moreover, the adopted computational multi-scale data assimilation for predictive modeling of flare gas recovery scenarios has been systematically reviewed, summarized, and inspected.


Subject(s)
Gases , Natural Gas , Oil and Gas Industry , Petroleum , Models, Theoretical
20.
Environ Sci Pollut Res Int ; 31(21): 31632-31645, 2024 May.
Article in English | MEDLINE | ID: mdl-38648001

ABSTRACT

Integrating hydrogen with CNG is crucial for carbon neutrality and environmental goals, as it enhances flame temperature, reduces emissions, and combats global warming. This study employs the CHEMKIN tool to examine combustion characteristics, including adiabatic flame temperature, mole fraction, normalization, and production rate, in H2-CNG mixtures under various atmospheric and operating conditions. Blending 50% hydrogen with CNG results in significant changes, including a temperature increase from 2322 to 2344 K when the hydrogen content is at 50%. The introduction of hydrogen causes a notable 30-35% reduction in CH4 mole fraction and a simultaneous 26.6% increase in C-normalized CH4 production. Free radicals play a role in affecting CO2 production, with the normalization of CO species increasing from 0.068 to 0.087. Through NSGA-II multi-objective optimization methods, the study identifies a 50% H2-50% CNG blend as the optimal choice for thermal and environmental performance. The study explores the energy and environmental impacts of incorporating hydrogen into CNG-air combustion, with a specific focus on the effects of 50% H2 blending with CNG. Hydrogen blending benefits from elevated adiabatic flame temperature and increased free radical formation, ultimately leading to emission reduction. These findings firmly establish H2-CNG mixtures as promising environmentally friendly alternatives with superior combustion characteristics. Their potential paves the way for significant progress towards achieving carbon neutrality and combating climate change through cleaner, more efficient fuel options.


Subject(s)
Hydrogen , Natural Gas , Hydrogen/chemistry , Carbon Dioxide/chemistry , Methane , Hydrogenation , Global Warming
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