Innovative Membrane Technologies for the Treatment of Wastewater Polluted with Heavy Metals: Perspective of the Potential of Electrodialysis, Membrane Distillation, and Forward Osmosis from a Bibliometric Analysis.

A bibliometric analysis, using the Scopus database as a source, was carried out in order to study the scientific documents published up to 2021 regarding the use of electrodialysis, membrane distillation, and forward osmosis for the removal of heavy metals from wastewater. A total of 362 documents that fulfilled the search criteria were found, and the results from the corresponding analysis revealed that the number of documents greatly increased after the year 2010, although the first document was published in 1956. The exponential evolution of the scientific production related to these innovative membrane technologies confirmed an increasing interest from the scientific community. The most prolific country was Denmark, which contributed 19.3% of the published documents, followed by the two main current scientific superpowers: China and the USA (with 17.4% and 7.5% contributions, respectively). Environmental Science was the most common subject (55.0% of contributions), followed by Chemical Engineering (37.3% of contributions) and Chemistry (36.5% of contribution). The prevalence of electrodialysis over the other two technologies was clear in terms of relative frequency of the keywords. An analysis of the main hot topics identified the main advantages and drawbacks of each technology, and revealed that examples of their successful implementation beyond the lab scale are still scarce. Therefore, complete techno-economic evaluation of the treatment of wastewater polluted with heavy metals via these innovative membrane technologies must be encouraged.

Techno-Economic Optimization of Multistage Membrane Processes with Innovative Hollow Fiber Modules for the Production of High-Purity CO2 and CH4 from Different Sources.

Within the current climate emergency framework and in order to avoid the most severe consequences of global warming, membrane separation processes have become critical for the implementation of carbon capture, storage, and utilization technologies. Mixtures of CO2 and CH4 are relevant energy resources, and the design of innovative membranes specifically designed to improve their separation is a hot topic. This work investigated the potential of modified polydimethylsiloxane and ionic liquid-chitosan composite membranes for separation of CO2 and CH4 mixtures from different sources, such as biogas upgrading, natural gas sweetening, or CO2 enhanced oil recovery. The techno-economic optimization of multistage processes at a real industrial scale was carried out, paying special attention to the identification of the optimal configuration of the hollow fiber modules and the selection of the best membrane scheme. The results demonstrated that a high initial content of CH4 in the feed stream (like in the case of natural gas sweetening) might imply a great challenge for the separation performance, where only membranes with exceptional selectivity might achieve the requirements in a two-stage process. The effective lifetime of the membranes is a key parameter for the successful implementation of innovative membranes in order to avoid severe economic penalties due to excessively frequent membrane replacement. The scale of the process had a great influence on the economic competitiveness of the process, but large-scale installations can operate under competitive conditions with total costs below 0.050 US$ per m3 STP of treated feed gas.

A Bibliometric Analysis of Research on Selenium in Drinking Water during the 1990-2021 Period: Treatment Options for Selenium Removal.

A bibliometric analysis based on the Scopus database was carried out to summarize the global research related to selenium in drinking water from 1990 to 2021 and identify the quantitative characteristics of the research in this period. The results from the analysis revealed that the number of accumulated publications followed a quadratic growth, which confirmed the relevance this research topic is gaining during the last years. High research efforts have been invested to define safe selenium content in drinking water, since the insufficient or excessive intake of selenium and the corresponding effects on human health are only separated by a narrow margin. Some important research features of the four main technologies most frequently used to remove selenium from drinking water (coagulation, flocculation and precipitation followed by filtration; adsorption and ion exchange; membrane-based processes and biological treatments) were compiled in this work. Although the search of technological options to remove selenium from drinking water is less intensive than the search of solutions to reduce and eliminate the presence of other pollutants, adsorption was the alternative that has received the most attention according to the research trends during the studied period, followed by membrane technologies, while biological methods require further research efforts to promote their implementation.

Self-Healing Asphalt: A Systematic Bibliometric Analysis for Identification of Hot Research Topics during the 2003-2018 Period.

The use of self-healing asphalt is a good option to extend the lifetime of roads and to improve the sustainability of pavement management systems. A bibliometric analysis based on the Scopus database was carried out to review the global research related to self-healing asphalt from 2003 to 2018 and to identify relevant quantitative characteristics from the research in this period. The results from this analysis revealed that the number of accumulated publications followed an exponential growth, which confirmed the relevance that this research topic has gained during the last years. The study revealed that China was the most productive country, followed by the Netherlands, where the most prolific institution is located: Delft University of Technology. Some important research features of the two main approaches most frequently used to develop asphalt mixtures with enhanced self-healing abilities (external heating and encapsulated rejuvenating agents) are compiled in this work.

Multi-Objective Optimization of Nutritional, Environmental and Economic Aspects of Diets Applied to the Spanish Context.

Current food consumption patterns must be revised in order to improve their sustainability. The nutritional, environmental, and economic consequences of these dietary patterns must be taken into consideration when diet guidelines are proposed. This study applied a systematic optimization methodology to define sustainable dietary patterns complying with nutritional, environmental, and economic issues. The methodology was based on a multi-objective optimization model that considered a distance-to-target approach. Although the three simultaneous objectives (maximal nutritional contribution, minimal greenhouse gas emissions, and minimal costs) could be divergent, the proposed model identified the optimal intake of each food product to achieve the maximal level of nutritional, environmental, and economic diets. This model was applied to six different eating patterns within the Spanish context: one based on current food consumption and five alternative diets. The results revealed that dietary patterns with improved nutritional profiles and reduced environmental impacts could be defined without additional costs just by increasing the consumption of vegetables, fruits, and legumes, while reducing the intake of meat and fish.

Comparison of Supported Ionic Liquid Membranes and Polymeric Ultrafiltration and Nanofiltration Membranes for Separation of Lignin and Monosaccharides.

Lignin is one of the three main components of lignocellulosic biomass and must be considered a raw material with attractive applications from an economic and ecological point of view. Therefore, biorefineries must have in mind the most adequate processing to obtain high-quality lignin and the separation tasks that play a key role to improve the purity of the lignin. Separation techniques based on membranes are a promising way to achieve these requirements. In this work, the separation performance of the SILM (Supported Ionic Liquid Membrane) formed with [BMIM][DBP] as IL (Ionic Liquid) and PTFE as membrane support was compared to a nanofiltration (NF) membrane (NP010 by Microdyn-Nadir) and two ultrafiltration (UF) membranes (UF5 and UF10 by Trisep). The SILM showed selective transport of Kraft lignin, lignosulphonate, xylose, and glucose in aqueous solutions. Although it was stable under different conditions and its performance was improved by the integration of agitation, it was not competitive when compared to NF and UF membranes, although the latter ones suffered fouling. The NF membrane was the best alternative for the separation of lignosulphonates from monosaccharides (separation factors around 75 while SILM attained only values lower than 3), while the UF5 membrane should be selected to separate Kraft lignin and monosaccharides (separation factors around 100 while SILM attained only values below 3).

Concentration of 1,3-dimethyl-2-imidazolidinone in Aqueous Solutions by Sweeping Gas Membrane Distillation: From Bench to Industrial Scale.

Sweeping gas membrane distillation (SGMD) is a useful option for dehydration of aqueous solvent solutions. This study investigated the technical viability and competitiveness of the use of SGMD to concentrate aqueous solutions of 1,3-dimethyl-2-imidazolidinone (DMI), a dipolar aprotic solvent. The concentration from 30% to 50% of aqueous DMI solutions was attained in a bench installation with Liqui-Cel SuperPhobic® hollow-fiber membranes. The selected membranes resulted in low vapor flux (below 0.15 kg/h·m2) but were also effective for minimization of DMI losses through the membranes, since these losses were maintained below 1% of the evaporated water flux. This fact implied that more than 99.2% of the DMI fed to the system was recovered in the produced concentrated solution. The influence of temperature and flowrate of the feed and sweep gas streams was analyzed to develop simple empirical models that represented the vapor permeation and DMI losses through the hollow-fiber membranes. The proposed models were successfully applied to the scaling-up of the process with a preliminary multi-objective optimization of the process based on the simultaneous minimization of the total membrane area, the heat requirement and the air consumption. Maximal feed temperature and air flowrate (and the corresponding high operation costs) were optimal conditions, but the excessive membrane area required implied an uncompetitive alternative for direct industrial application.

A Bibliometric Analysis of Research on Supported Ionic Liquid Membranes during the 1995-2015 Period: Study of the Main Applications and Trending Topics.

A bibliometric analysis based on Scopus database was performed to identify the global research trends related to Supported Ionic Liquid Membranes (SILMs) during the time period from 1995 to 2015. This work tries to improve the understanding of the most relevant research topics and applications. The results from the analysis reveal that only after 2005 the research efforts focused on SILMs became significant, since the references found before that year are scarce. The most important research works on the four main application groups for SILMs defined in this work (carbon dioxide separation, other gas phase separations, pervaporation and liquid phase separations) were summarized in this paper. Carbon dioxide separation appeared as the application that has received by far the most attention according to the research trends during the analysed period. Comments about other significant applications that are gaining attention, such as the employment of SILMs in analytical tasks or their consideration for the production of fuel cells, have been included.

Membrane bioprocesses for pharmaceutical micropollutant removal from waters.

The purpose of this review work is to give an overview of the research reported on bioprocesses for the treatment of domestic or industrial wastewaters (WW) containing pharmaceuticals. Conventional WW treatment technologies are not efficient enough to completely remove all pharmaceuticals from water. Indeed, these compounds are becoming an actual public health problem, because they are more and more present in underground and even in potable waters. Different types of bioprocesses are described in this work: from classical activated sludge systems, which allow the depletion of pharmaceuticals by bio-degradation and adsorption, to enzymatic reactions, which are more focused on the treatment of WW containing a relatively high content of pharmaceuticals and less organic carbon pollution than classical WW. Different aspects concerning the advantages of membrane bioreactors for pharmaceuticals removal are discussed, as well as the more recent studies on enzymatic membrane reactors to the depletion of these recalcitrant compounds.