Long-atmospheric-path measurements of near-visible absorption lines of O(2) isotopes and H(2)O with a prototype AlGaAs laser transceiver system.

Near-visible absorption lines of ambient H(2)O vapor and normal and heavy isotopes of O(2) have been measured over atmospheric paths of up to 0.46 km by using two wavelength-modulated, line-locked AlGaAs laser sources with a retroreflector-telescope system. The absolute signal levels agree with theoretical calculations for the O(2) isotopes to within 2%, which is similar to the accuracy with which the column densities were known. Measurements of (16)O(2) linewidths and line strengths were made, and they agree with literature values to within experimental error. The detection sensitivity for (16)O(18)O was found to be 0.1 part in 10(6) atm. km, correspondingto an absorbance sensitivity of 1 × 10(-5). It is concluded that atmospheric trace-gas sensing will be feasible with this apparatus over distances of several kilometers and at levels under 1 part in 10(6).

Laser Raman sensor for measurement of trace-hydrogen gas.

A new optical hydrogen sensor based on spontaneous Raman scattering of laser light has been designed and constructed for rugged field use. It provides good sensitivity (better than 100 parts in 10(6)), rapid response (several seconds), and the inherent Raman characteristics of linearity and background gas independence of the signal. Efficient light collection and discrimination by using fast optics and a bandpass interference filter compensate for the inefficiency of the Raman-scattering process. A multipass optical cavity with a Herriott-type configuration provides intense illumination from an air-cooled cw gas laser. The observed performance is in good agreement with the theoretical signal and noise level predictions.