Ecological and human health risk assessment of potentially toxic elements in water and soils within a crude oil waste management facility, Southwestern Ghana.

Crude oil waste management is challenging due to the diverse constituents of the waste and its consequent impact on valued environmental receptors (water and soil). Characterization of the potentially toxic elements (PTEs) in soils and water within the surroundings of crude oil waste management facility is imperative, to aid evaluation of potential risks. The study assessed the potential environmental and human health risks posed by PTEs in soil and water from surroundings and adjoining settlement communities. A total of forty-four (44) samples were analyzed for PTEs (Cr, Pb, Zn, Co, Mn, Ni, Hg, Fe, As, Cu, Hg, and Cd) and physicochemical properties in both matrices. The total carcinogenic risk (TCR) for adults and children in the neighbouring community was 4.73 × 10-6 and 1.2 × 10-4, respectively, which was due to the high carcinogenic slope factor of arsenic. A strong correlation was observed between the PTEs and physicochemical properties, and their health risk was attributed to both geogenic and anthropogenic factors. The study indicated that the human health and ecological risk values obtained were within acceptable limits, with the waste management facility posing a higher risk in comparison to the nearby community. These risks may be attributed to the specific nature and intensity of the activities conducted at the facility. Hence, there is the need for continuous promotion of occupational and public awareness on the health and environmental impact of crude oil waste management.

Mercury methylation in cyanide influenced river sediments: A comparative study in Southwestern Ghana.

Studies on the influence of CN on Hg methylation rates in aquatic systems draining gold mining (artisanal and small-scale) communities in Africa are rare. The study assessed the influence of CN on Hg methylation in aquatic sediments of two major river systems draining artisanal and small-scale gold mining (ASGM) communities of the Prestea-Huni Valley district, Southwestern Ghana. The miners extract gold (Au) through exclusive amalgam [Hg-Au] formation or cyanidation of Au-rich Hg-contaminated tailings, or a combination of both techniques. Hg water solubility and probable mercuric compounds in sediments of Hg-contaminated CN-loaded (River Aprepre) and Hg-contaminated non-CN (River Ankobra) aquatic systems within the district were investigated. THg was determined by CV-AAS after HF/HNO3/HCl digestion. MeHg in sediments were extracted with H2SO4/KBr/CuSO4-CH2Cl2; followed by aqueous-phase propylation, preconcentration-on-Tenax, and GC-CV-AFS. River Aprepre showed 4.58-14.83 ngMeHg/g as Hg (1.4-3.7% THg as MeHg), with 241-415 ngTHg/g, and 0.05-0.21 mgCN/kg. For River Ankobra, MeHg ranged 0.24-1.21 ngMeHg/g (0.08-0.35% THg as MeHg) with 162-490 ngTHg/g dw and CN < 0.001 mg/kg. There was positive correlation (r2 = 0.5974; p < 0.01) between MeHg and CN in River Aprepre. The water-soluble fraction of Hg in sediment from both rivers was < 1% of THg. Hg in sediments from River Aprepre were generally more soluble than that from River Ankobra, indicating that Hg in sediments from River Aprepre were potentially more bioavailable for methylation. Accordingly, the presence of CN in Hg-dominated river sediments potentially influences and enhances the solubility and mobility of Hg, resulting in increased Hg methylation rates.

Speciation of As(III) and As(V) in water and sediment using reverse-phase ion-pair high-performance liquid chromatography-neutron activation analysis (HPLC-NAA).

Total As content and the As species distribution in water and sediments from the Kwabrafo stream, a major water body draining the Obuasi gold mining community in southwestern Ghana, have been investigated. Total As content was determined by instrumental neutron activation analysis (INAA). Ion-pair reverse phase high-performance liquid chromatography-neutron activation analysis (HPLC-NAA) was used for speciation of As species. Solid phase extraction with phosphate buffer was used to extract soluble As species from lyophilized sediment. The mass balance after phosphate extraction of soluble As species in sediment varied from 89 to 96 %. Compositionally appropriate reference material International Atomic Energy Agency (IAEA)-Lake Sediment (SL)-1 was used to check the validity of INAA method for total As determination. The measured values are in good agreement with the IAEA recommended value and also within the 95 % confidence interval. The accuracy of the measurement in terms of relative deviation from the IAEA recommended value was ±0.83 %. "In-house" prepared As(III) and As(V) standards were used to validate the HPLC-INAA method used for the As species determination. Total As concentration in the water samples ranged from 1.15 to 9.20 mg/L. As(III) species in water varied from 0.13 to 0.7 mg/L, while As(V) species varied from 0.79 to 3.85 mg/L. Total As content in sediment ranged from 2,134 to 3,596 mg/kg dry mass. The levels of As(III) and As(V) species in the sediment ranges from 138 to 506 mg/kg dry mass and 156 to 385 mg/kg dry mass, respectively.

Dietary supply of selenium for adolescents in three residential care orphanages in Southern Ghana.

Adolescents require optimum dietary supply of the essential trace mineral selenium (Se); however the absence of reliable and accurate data on the dietary supply of selenium for the adolescent population in Ghanaian residential care orphanages have made it difficult for public health nutritionists to assess the adequacy of the dietary supply. The dietary supply of selenium for adolescents (12-15 years) in three residential care orphanages, (Osu, Tutu-Akwapim and Teshie), in Southern Ghana have been evaluated by sampling their 24-h duplicate diets (including water) for 7-consecutive days using the duplicate diet sampling technique. The mass fraction of selenium in the blended lyophilized homogenates of duplicate diets was determined by radiochemical neutron activation analysis (RNAA). The validity of the RNAA method for selenium determination was checked by analyses of NIST SRM 1548a (Typical diet). The chemical yield of the radiochemical separation was determined by spectrophotometry. The average mass fractions of selenium in the blended lyophilized 24-hour duplicate diets for Osu, Tutu-Akwapim and Teshie were; 165±61 [117.2-285.2], 203±68 [110.5-304.9] and 250±92 [128.8-408.0]ng Seg(-1) lyophilized matter respectively. The average dietary supply of Se were, 57.6±17.3 [42.2-88.4], 82.0±30.7 [44.3-136.2] and 91.7±44.2 [46.0-153.4]µg Se day(-1) for Osu, Tutu-Akwapim and Teshie orphanages respectively. The data generated will help public health nutritionists in the provision of dietary advice and nutritional support for the studied orphanages, as well as other orphanages. The data will also help in the planning of institutional diets.