Critical review on organophosphate esters in water environment: Occurrence, health hazards and removal technologies.

Organophosphate esters (OPEs), which are phosphoric acid ester derivatives, are anthropogenic substances that are widely used in commerce. Nevertheless, there is growing public concern about these ubiquitous contaminants, which are frequently detected in contaminated water sources. OPEs are mostly emitted by industrial operations, and the primary routes of human exposure to OPEs include food intake and dermal absorption. Because of their negative effects on both human health and the environment, it is clear that innovative methods are needed to facilitate their eradication. In this study, we present a comprehensive overview of the existing characteristics and origins of OPEs, their possible impacts on human health, and the merits, drawbacks, and future possibilities of contemporary sophisticated remediation methods. Current advanced remediation approaches for OPEs include adsorption, degradation (advanced oxidation, advanced reduction, and redox technology), membrane filtration, and municipal wastewater treatment plants, degradation and adsorption are the most promising removal technologies. Meanwhile, we proposed potential areas for future research (appropriate management approaches, exploring the combination treatment process, economic factors, and potential for secondary pollution). Collectively, this work gives a comprehensive understanding of OPEs, providing useful insights for future research on OPEs pollution.

Simultaneous degradation of p-arsanilic acid and inorganic arsenic removal using M-rGO/PS Fenton-like system under neutral conditions.

In this study, magnetic material based reduced graphene oxide (M-rGO) was prepared through co-precipitation and displayed high catalytic efficiency together with persulfate (PS) for simultaneous p-arsanilic acid (p-ASA) decomposition and arsenic removal. Linear sweep voltammetry and chronoamperometric measurements with M-rGO revealed that PS was effectively bound to M-rGO surface and probably formed charge transfer complex, in which M-rGO was pivotal in mediating facile electron transfer. The effects of pH, temperatures, anions, p-ASA concentration, PS, and M-rGO dosages on p-ASA decomposition were studied in the system. Excellent degradation of p-ASA was carried out at a wide range of pH values, which was unattainable by other Fenton-like processes. Under optimal conditions, M-rGO exhibited prominent removal of both p-ASA (98.8 %) and inorganic arsenic (89.8 %). M-rGO had reasonably excellent repeatability and stability, and 77.7 % p-ASA degraded in the third recovered catalyst. The advantages of environmental friendliness, short reaction time, and straightforward synthesis of M-rGO will facilitate the development of heterogeneous Fenton-like catalysts under neutral conditions.