The effect of maleic anhydride grafted polypropylene addition on the degradation in the mechanical properties of the PP/wood composites.

This work focuses on studying the influence of coupling agents on the degradation in the mechanical properties of Polypropylene (PP)/wood composites. Maleic anhydride polypropylene (MAPP) was used as a coupling agent between the wood flour and PP matrix. As the coupling agent plays an important role in the stability of the WPC, a 10 wt% wood flour was mixed with PP granules along with a UV stabilizer and varying percentages (1, 3, 5 wt%) of MAPP in a twin-screw extruder to obtain PWC granules. The composite granules were injection molded to produce tensile samples for the mechanical characterization of the composites. To test the environmental degradation of the PWCs, the tensile samples were exposed to the environmental conditions for 0, 336 h (14 days), and 672 h (28 days) prior to testing. After the specified exposure time, the samples were mechanically characterized using tensile testing. The degradation characteristics of the WPCs were quantified in terms of the failure strains of the composite with exposure time. The experiments were designed, and various analyses, including ANOVA, regression equation, and prediction tests, were carried out to investigate the impact of parameters on the failure strain of the PWCs. Moreover, the study aimed to examine the effect of parameters such as MAPP and time, on the failure strain of the composites. From the experimental results, it is concluded that the composites containing 1 wt% of MAPP showed superior retention in the degradation of composites when compared with 3 and 5 wt% MAPP content.

A Novel Application of the Hydrophobic Polyurethane Foam: Expansive Soil Stabilization.

The reversible shrink-swell behavior of expansive soil imposes a serious challenge that threatens the overlying structures' safety and durability. Traditional chemical additives such as lime and cement still exhibit satisfying performance over their counterparts in terms of swelling potential reduction. Nevertheless, significant concerns are associated with these chemicals, in addition to their environmental impact. This paper proposes a novel application of the closed-cell one-component hydrophobic polyurethane foam (HPUF) to stabilize the swelling soil. An extensive experimental study was performed to assess the efficiency of HPUF in mitigating both the swelling and shrinkage response of high montmorillonite content expansive soil. Expansive soil was injected/mixed with different weight ratios of the proposed stabilizer, and the optimum mixing design and injection percentage of the foam resin were identified to be ranged from 10% to 15%. The shrink-swell behaviors of both injected and noninjected samples were compared. Results of this comparison confirmed that HPUF could competently reduce both the swelling potential and the shrinkage cracking of the reactive expansive soil, even after several wet-shrink cycles.