1.
Appl Radiat Isot
; 170: 109582, 2021 Apr.
Artigo
em Inglês
| MEDLINE
| ID: mdl-33561749
RESUMO
In-beam Mössbauer spectra of 57Mn implanted into LiAlH4 were measured at different temperatures between 17 and 300 K. The Mössbauer spectrum measured at 17 K showed two sets of doublets, which were assigned to 57Fe atoms at substitutional sites at Al3+ and Li+ sites. The Debye temperatures θM for the 57Fe atoms at Al3+-substituted and Li+-substituted sites were estimated to be 194 K and 117 K, respectively. The assignments were confirmed by density functional theory calculations.