Sorption of chromium from aqueous solutions using Fucus vesiculosus algae biosorbent.

The presence of heavy metals in wastewater is an environmental concern and the current treatment procedures are very expensive so it is necessary to find effective and inexpensive biosorbents. In this study, Fucus vesiculosus was used as a biosorbent for the biosorption of Cr(III) ions from the aqueous solutions. Biosorption parameters, such as pH, adsorbent dose, contact time, and initial concentrations of Cr(III) had the most impact on the sorption process. The required pH value for sorption was 5, the biosorbent dose was 4.0 g/L, the contact time was seen to occur after 90 min, and the Cr(III) removal decreased from 98.9 to 92%. The maximum biosorption capacity of chromium was 14.12 mg/g. FTIR analysis of Fucus vesiculosus biomass before the sorption process contains carboxyl, amino, hydroxyl, alkyne, and carbonyl groups, and according to the analysis after the sorption process, it was found that Cr(III) metal ions were incorporated within the sorbent during the interaction with (=C-H) active functional groups. The biosorption data were found to be perfectly suited by Langmuir equilibrium isotherm model. According to the results of this study, Fucus vesiculosus is an effective biosorbent for the removal of Cr(III) from aqueous solutions.

Evaluation of Chlorella vulgaris biosorption capacity for phosphate and nitrate removal from wastewater.

High wastewater production rates during the past few decades are mostly attributable to anthropogenic activities. The main components leading to the nutrient enrichment of natural water bodies are such as nitrogen, phosphorus, and other minerals. The main focus of this research was to assess the ability of using Chlorella vulgaris algae, a potent and environmentally benign material, to eliminate phosphate and nitrate ions from wastewater. FTIR results showed that the biologically active molecules that facilitate the binding of phosphate and nitrate ions unto the C. vulgaris are C=C and N-H amid. The ideal equilibrium time for adsorption was 24 h with an optimum pH of 7 and the mass ratio of algae and different anions concentration was 80%. Freundlich isotherm model was the best-fitted isotherm. Moreover, the results of the experiment fit more closely with the pseudo-second-order kinetic model than other models. Elovich kinetic model data for both ions showed that the adsorption rate was much higher than the desorption rate. The growing popularity of biosorbents in treating wastewater has led to an improvement in their affordability and availability, and C. vulgaris may now represent an environmentally friendly choice from an environmental, and economic standpoint.

Reclamation of wastewater in wetlands using reed plants and biochar.

To cope with water crisis, wastewater reuse has been introduced as a potential source for irrigation. On the other hand, irrigation with wastewater may negatively affect the surroundings. In this study, reed plant (Phragmits australis) and its biochar were tested as low-cost treatments to enhance the efficiency of wastewater reclamation in wetlands within only 72 h. The investigated water was of low irrigation quality and exhibited high contents of BOD5 and fecal coliform. Moreover, this water contained high levels of soluble cations and anions; besides, being marginally contaminated with Cu, Mn and Cd. After 2 days in the sedimentation unit, wastewater was subjected to three reclamation treatments in parallel (each lasted for 24 h): (1) a "sand & gravel bed", (2) "reed plants grown on a sand & gravel bed" and (3) "biochar + a sand & gravel bed". The results showed that all treatments decreased BOD5, fecal coliform, total cations and anions, with superiority for the second and third treatments. The levels of the potentially toxic elements also decreased to values within the permissible levels. Although the aforementioned wastewater treatment processes upgraded the quality of this water, it remained in the poor grade. Biochar or reed plants grown on sand and gravel beds significantly improved wastewater quality to the medium quality grade, with superiority for biochar treatment. In conclusion, investigated treatments are guaranteed in wetlands for wastewater reclamation; yet, further protocols should be followed to achieve safe handling of this water and attain the sustainable goals.