Anammox, biochar column and subsurface constructed wetland as an integrated system for treating municipal solid waste derived landfill leachate from an open dumpsite.

This study aims to treat nitrogen-rich landfill leachate from Karadiyana open dumpsite, Sri Lanka, through an integrated treatment train consists of an anammox process, Municipal Solid Waste derived biochar column followed by a biochar embedded subsurface constructed wetland. Characterization of leachate was done and the leachate pollution index (LPI) was estimated. Meanwhile, leachate was treated through a treatment system comprising an anammox reactor having 140 mm diameter and 250 mm height, a biochar reactor having the same dimensions with 1.3 kg of MSW biochar, and a laboratory-scale constructed wetland of 1 × 0.3 × 0.45 m. The influent and effluent quality was assessed for the samples taken in 24 h intervals. The analysis indicated that the leachate was high in COD (4000-14,000 mg/L), ammonia (760-900 mg/L), nitrate (60-126 mg/L), and phosphorus (33-66 mg/L). Ammonia and nitrite were removed 94 and 99% by anammox unit, respectively. Nitrate, phosphate, COD and conductivity were significantly removed by the constructed wetland system in 78, 70, 65 and 61%, respectively, whereas biochar barricades extended support for removal of the contaminants and color. The combined treatment system demonstrated treatment efficiencies as 100% of ammonia, 98.7% of nitrite, 98.2% of nitrate, 80.9% of phosphate, 79.7% of COD, and 69.9% of conductivity. Thus, it can be concluded that the anammox, combined with biochar embedded treatment train is promising to treat landfill leachate, having a high pollutant index.

Influence of bioenergy waste biochar on proton- and ligand-promoted release of Pb and Cu in a shooting range soil.

Presence of organic and inorganic acids influences the release rates of trace metals (TMs) bound in contaminated soil systems. This study aimed to investigate the influence of bioenergy waste biochar, derived from Gliricidia sepium (GBC), on the proton and ligand-induced bioavailability of Pb and Cu in a shooting range soil (17,066mg Pb and 1134mg Cu per kg soil) in the presence of inorganic (sulfuric, nitric, and hydrochloric) and organic acids (acetic, citric, and oxalic). Release rates of Pb and Cu in the shooting range soil were determined under different acid concentrations (0.05, 0.1, 0.5, 1, 5, and 10mM) and in the presence/absence of GBC (10% by weight of soil). The dissolution rates of Pb and Cu increased with increasing acid concentrations. Lead was preferentially released (2.79×10-13 to 8.86×10-13molm-2s-1) than Cu (1.07×10-13 to 1.02×10-13molm-2s-1) which could be due to the excessive Pb concentrations in soil. However, the addition of GBC to soil reduced Pb and Cu dissolution rates to a greater extent of 10.0 to 99.5% and 15.6 to 99.5%, respectively, under various acid concentrations. The increased pH in the medium and different adsorption mechanisms, including electrostatic attractions, surface diffusion, ion exchange, precipitation, and complexation could immobilize Pb and Cu released by the proton and ligands in GBC amended soil. Overall, GBC could be utilized as an effective soil amendment to immobilize Pb and Cu in shooting range soil even under the influence of soil acidity.

Biochar-based constructed wetlands to treat reverse osmosis rejected concentrates in chronic kidney disease endemic areas in Sri Lanka.

The objectives were to investigate the potential remedial measures for reverse osmosis (RO) rejected water through constructed wetlands (CWs) with low-cost materials in the media established in chronic kidney disease of unknown etiology (CKDu) prevalent area in Sri Lanka. A pilot-scale surface and subsurface water CWs were established at the Medawachchiya community-based RO water supply unit. Locally available soil, calicut tile and biochar were used in proportions of 81, 16.5 and 2.5% (w/w), respectively, as filter materials in the subsurface. Vetiver grass and Scirpus grossus were selected for subsurface wetland while water lettuce and water hyacinth were chosen for free water surface CWs. Results showed that the CKDu sensitive parameters; total dissolved solids, hardness, total alkalinity and fluoride were reduced considerably (20-85%) and most met desirable levels of stipulated ambient standards. Biochar seemed to play a major role in removing fluoride from the system which may be due to the existing and adsorbed K+, Ca+2, Mg+2, etc. on the biochar surface via chemisorption. The least reduction was observed for alkalinity. This study indicated potential purification of aforesaid ions in water which are considerably present in RO rejection. Therefore, the invented bio-geo constructed wetland can be considered as a sustainable, economical and effective option for reducing high concentrations of CKDu sensitive parameters in RO rejected water before discharging into the inland waters.