RESUMO
The escalating loads of municipal solid waste (MSW) end up in open dumps and landfills, producing continuous flows of landfill leachate. The risk of incorporating highly toxic landfill leachate into environment is important to be evaluated and measured in order to facilitate decision making for landfill leachate management and treatment. Leachate pollution index (LPI) provides quantitative measures of the potential environmental pollution by landfill leachate and information about the environmental quality adjacent to a particular landfill. According to LPI values, most developing countries show high pollution potentials from leachate, mainly due to high organic waste composition and low level of waste management techniques. A special focus on leachate characterization studies with LPI and its integration to treatment, which has not been focused in previous reviews on landfill leachate, is given here. Further, the current review provides a summary related to leachate generation, composition, characterization, risk assessment and treatment together with challenges and perspectives in the sector with its focus to developing nations. Potential commercial and industrial applications of landfill leachate is discussed in the study to provide insights into its sustainable management which is original for the study.
Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Poluentes Químicos da Água , Resíduos Sólidos/análise , Instalações de Eliminação de Resíduos , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidadeRESUMO
The discovery of anammox process has provided eco-friendly and low-cost means of treating ammonia rich wastewater with remarkable efficiency. Furthermore, recent studies have shown that the possibility of operating the anammox process under low temperatures and high organic matter contents broadening the application of the anammox process. However, short doubling time and extensive levels of sensitivity towards nutrients and environmental alterations such as salinity and temperature are the limitations in practical applications of the anammox process. This review article provides the recent yet comprehensive viewpoint on anammox bacteria and the key perspectives in applying them as an efficient strategy for wastewater treatment.
RESUMO
In this paper, we investigate the release of heavy metals from sludge produced from an electrical industry using both organic and inorganic acids. Single and sequential extractions were conducted to assess heavy metals in different phases of the sludge. Metal release from sludge was investigated in the presence of three inorganic acids (nitric, sulfuric, and phosphoric) and three organic acids (acetic, malic, and citric) at concentrations ranging from 0.1 to 2.0â¯molâ¯L-1. Sequential extraction indicated the presence of Cu primarily in the carbonate fraction, Pb in the residual fraction, and Ni in the FeMn oxide fraction. The cumulative release rates of heavy metals (i.e., Pb, Cu, and Ni) by 1.0â¯molâ¯L-1 of acid increased with the use of the following acids in the order of: malic < sulfuric < acetic < phosphoric < citric < nitric. Acetic acid exhibited the highest release of Cu, at a rate of 72.62â¯×â¯10-11â¯molâ¯m-2â¯s-1 at pHâ¯1, and malic acid drove the release of Pb at a maximum rate of 3.90â¯×â¯10-11â¯molâ¯m-2â¯s-1. Meanwhile, nitric acid provided the maximum rate of Ni release (0.23â¯×â¯10-11â¯molâ¯m-2â¯s-1) at pHâ¯1. The high rate of metal release by organic acids is explained through ligand-promoted mechanisms that enhance the release of metal ions from the sludge. The results from our study emphasize that an understanding of the metal release mechanism is key to selecting the optimal acid for the maximum recovery of heavy metals.