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1.
Proc Natl Acad Sci U S A ; 118(20)2021 May 18.
Artigo em Inglês | MEDLINE | ID: mdl-33972449

RESUMO

Future terrestrial and interplanetary travel will require high-speed flight and reentry in planetary atmospheres by way of robust, controllable means. This, in large part, hinges on having reliable propulsion systems for hypersonic and supersonic flight. Given the availability of fuels as propellants, we likely will rely on some form of chemical or nuclear propulsion, which means using various forms of exothermic reactions and therefore combustion waves. Such waves may be deflagrations, which are subsonic reaction waves, or detonations, which are ultrahigh-speed supersonic reaction waves. Detonations are an extremely efficient, highly energetic mode of reaction generally associated with intense blast explosions and supernovas. Detonation-based propulsion systems are now of considerable interest because of their potential use for greater propulsion power compared to deflagration-based systems. An understanding of the ignition, propagation, and stability of detonation waves is critical to harnessing their propulsive potential and depends on our ability to study them in a laboratory setting. Here we present a unique experimental configuration, a hypersonic high-enthalpy reaction facility that produces a detonation that is fixed in space, which is crucial for controlling and harnessing the reaction power. A standing oblique detonation wave, stabilized on a ramp, is created in a hypersonic flow of hydrogen and air. Flow diagnostics, such as high-speed shadowgraph and chemiluminescence imaging, show detonation initiation and stabilization and are corroborated through comparison to simulations. This breakthrough in experimental analysis allows for a possible pathway to develop and integrate ultra-high-speed detonation technology enabling hypersonic propulsion and advanced power systems.

2.
Angew Chem Int Ed Engl ; 58(5): 1355-1360, 2019 Jan 28.
Artigo em Inglês | MEDLINE | ID: mdl-30412349

RESUMO

Unambiguously confirmed by low-temperature in situ NMR experiments, X-ray diffraction and vibrational spectroscopy, phosphonium-carbenium superelectrophiles are shown to be generated in strong acidic conditions. Representing crucial intermediates, their exploitation allows for the synthesis of unprecedented fluorinated (cyclic) phosphine oxides.

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