Sustainable development of an effective anti-corrosion film over the St12-steel surface against seawater attacks using Ce(III) ions/tri-sodium phosphate anions.

One application of organic compounds is to utilize them as corrosion inhibitors in acidic environments to diminish steel corrosion. These inhibitors do not show very good inhibition properties in saline (NaCl) environments. There have been many studies on boosting these inhibitors' performance in such environments (especially Cl- containing media). One of the ways that have been proposed is the use of organic and inorganic inhibitors, simultaneously. The synergistic effect of these inhibitors has shown promising results in reducing steel corrosion. In this study, cerium(III) nitrate and tri-sodium phosphate (TSP) was used as organic and inorganic inhibitors to control the corrosion of steel in a 3.5 wt.% NaCl environment. The corrosion measurements were conducted in the 3.5 wt.% NaCl environment by EIS and polarization methods. Surface studies were done by SEM, Raman, GIXRD, and EDS methods. Corrosion studies (EIS and polarization) have revealed that when 500 ppm of Ce(NO3)3 and 500 ppm of TSP are added to the 3.5 wt.% NaCl medium, the highest synergism index (1.27) and inhibition efficiency (73.7%) are achieved. Also, by adding 500Ce-500TPS to the solution, icorr and Rct of steel decreased by about 80% and increased approximately 4-fold, respectively. This improvement in the steel performance against corrosion in the presence of an equal ratio of Ce(NO3)3 and TSP is the outcome of the formation of a hydrophobic dense film (consisting of Ce(OH)3, Ce/Fe-phosphate complexes) on the metal surface. This claim has been proven by SEM/EDS, contact angel, FT-IR, and XRD analysis.

Epoxy coating anti-corrosion properties enhancement via the steel surface treatment by nanostructured samarium oxide-poly-dopamine film.

Nowadays, the rare earth element-based conversion coatings (REE-based CCs) are a potential eco-friendly alternative for hazardous and carcinogenic Cr-based CCs. These coatings have morphological defects that impair their performance; therefore, they need to be surface modified. In this study, for the first time, the steel surface was coated with an eco-friendly Sm-based CC and then post-modified by poly-dopamine based biopolymer. The air-exposed based self-polymerization and oxidant-induced polymerization are two protocols which have been utilized for poly-dopamine synthesis. The SEM/EDS analysis and Raman spectroscopy have been employed for the treated steel surface characterization. In addition, the electrochemical impedance spectroscopy (EIS) analysis and salt-spray test (SST) were carried out to investigate the epoxy (EP) coating corrosion protection performance. The Rt values of the EP applied on the Sm-PDA modified steel, subjected to a 3.5 wt. % NaCl solution, are respectively 2550 GΩ.cm2 and 100 kΩ. cm2 before and after the creation of scratch. These values are about 94000-fold and 21-fold more than the Rt of the defected/un-defected EP coatings applied on the unmodified steel. In addition, the EP applied on the Sm-PDA modified steel showed lower corrosion and less disbonding in SST and higher resistance against CD than the EP applied on the unmodified steel.

Development of a nanostructured film based on samarium (III)/polydopamine on the steel surface with superior anti-corrosion and water-repellency properties.

HYPOTHESIS: The application of various hydrophobic/superhydrophobic coatings on the surface of metals has become the hot topic of the recent studies. The corrosion protection effectiveness and environmental issues are two important factors that should be taken into consideration when developing advanced surface coatings. Recently, the rare-earth elements (i.e., samarium) and biopolymers (i.e., polydopamine) have attracted much attention in the metals' corrosion control field. EXPERIMENTS: The Sm(NO3)3 containing solution was sprayed to the steel (St-12) sheets. Then, the Sm-modified plates were post-modified by polydopamine biopolymers that were synthesized by the self-polymerization (using tris (hydroxymethyl) aminomethane as a buffer), and oxidant-induced (using CuSO4 as an oxidant) approaches. The structural analysis was carried out by different techniques such as contact angle (CA) test. Moreover, the electrochemical impedance spectroscopy (EIS) and polarization tests were performed to investigate the anti-corrosion performance of various samples. FINDINGS: The CA test results revealed that by applying the nanostructured Sm-based film, the surface of the metal becomes near superhydrophobic (CA > 140°). EIS results evidenced the significant impact of the post-treatment of the Sm-treated samples by polydopamine (PDA) nanoparticles (NPs) on its corrosion protection ability enhancement. Also, the polarization test results confirmed that all treatments could retard the corrosion of steel via a mixed-type inhibition mechanism.