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1.
Opt Express ; 29(10): 14425-14437, 2021 May 10.
Artigo em Inglês | MEDLINE | ID: mdl-33985166

RESUMO

Diamonds containing the negatively charged nitrogen-vacancy centre are a promising system for room-temperature magnetometry. The combination of nano- and micro-diamond particles with optical fibres provides an option for deploying nitrogen-vacancy magnetometers in harsh and challenging environments. Here we numerically explore the coupling efficiency from nitrogen-vacancy centres within a diamond doped at the core/clad interface across a range of commercially available fibre types so as to inform the design process for a diamond in fibre magnetometers. We determine coupling efficiencies from nitrogen-vacancy centres to the guided modes of a step-index fibre and predict the optically detected magnetic resonance (ODMR) generated by a ensemble of four nitrogen-vacancy centres in this hybrid fibre system. Our results show that the coupling efficiency is enhanced with a high refractive index difference between the fibre core and cladding and depends on the radial position of the nitrogen-vacancy centres in the fibre core. Our ODMR simulations show that due to the preferential coupling of the nitrogen-vacancy emission to the fibre guided modes, certain magnetometry features such as ODMR contrast can be enhanced and lead to improved sensitivity in such diamond-fibre systems, relative to conventional diamond only ensemble geometries.

2.
ACS Appl Mater Interfaces ; 12(43): 48408-48419, 2020 Oct 28.
Artigo em Inglês | MEDLINE | ID: mdl-33047948

RESUMO

Next generation wound care technology capable of diagnosing wound parameters, promoting healthy cell growth, and reducing pathogenic infections noninvasively would provide patients with an improved standard of care and accelerated wound repair. Temperature is one of the indicating biomarkers specific to chronic wounds. This work reports a hybrid, multifunctional optical material platform-nanodiamond (ND)-silk membranes as biopolymer dressings capable of temperature sensing and promoting wound healing. The hybrid structure was fabricated through electrospinning, and 3D submicron fibrous membranes with high porosity were formed. Silk fibers are capable of compensating for the lack of an extracellular matrix at the wound site, supporting the wound-healing process. Negatively charged nitrogen vacancy (NV-) color centers in NDs exhibit optically detected magnetic resonance (ODMR) and act as nanoscale thermometers. This can be exploited to sense temperature variations associated with the presence of infection or inflammation in a wound, without physically removing the dressing. Our results show that the presence of NDs in the hybrid ND-silk membranes improves the thermal stability of silk fibers. NV- color centers in NDs embedded in silk fibers exhibit well-retained fluorescence and ODMR. Using the NV- centers as fluorescent nanoscale thermometers, we achieved temperature sensing in 25-50 °C, including the biologically relevant temperature window, for cell-grown ND-silk membranes. An enhancement (∼1.5× on average) in the temperature sensitivity of the NV- centers was observed for the hybrid materials. The hybrid membranes were further tested in vivo in a murine wound-healing model and demonstrated biocompatibility and equivalent wound closure rates as the control wounds. Additionally, the hybrid ND-silk membranes exhibited selective antifouling and biocidal propensity toward Gram-negative Pseudomonas aeruginosa and Escherichia coli, while no effect was observed on Gram-positive Staphylococcus aureus.


Assuntos
Materiais Biocompatíveis/farmacologia , Técnicas Biossensoriais , Fibroínas/farmacologia , Nanodiamantes/química , Seda/química , Cicatrização/efeitos dos fármacos , Animais , Materiais Biocompatíveis/química , Fibroínas/química , Camundongos , Camundongos Endogâmicos C57BL , Tamanho da Partícula , Propriedades de Superfície
3.
Sci Rep ; 6: 31289, 2016 08 18.
Artigo em Inglês | MEDLINE | ID: mdl-27535577

RESUMO

Ceramic YAG/Yb:YAG/YAG planar waveguide lasers were realized on continuous-wave and mode-locked operations. The straight waveguide, fabricated by non-aqueous tape casting and solid state reactive sintering, enabled highly efficient diode-pumped waveguide continuous-wave laser with the slope efficiency of 66% and average output power of more than 3 W. The influence of the waveguide structure on the wavelength tunability was also experimentally investiccgated with a dispersive prism. Passively mode-locked operation of the ceramic waveguide laser was achieved by using a semiconductor saturable absorber mirror (SESAM), output 2.95 ps pulses with maximum power of 385 mW at the central wavelength of 1030 nm.

4.
Opt Express ; 24(10): 10939-45, 2016 May 16.
Artigo em Inglês | MEDLINE | ID: mdl-27409915

RESUMO

We report on a high-power third-order dispersion managed amplification system that delivers 33-fs pulses of 93.5 W at a repetition rate of 55 MHz. A pair of grisms are used as the pre-chirper for optimizing the third order dispersion (TOD) to group velocity dispersion (GVD) ratio. Detail experiments show that the use of a grsim pre-chirper significantly enhances the quality of the compressed pulses. We demonstrate that the third order dispersion of both the amplifier and the compressor can be compensated for by the grisms. Furthermore, the nonlinear phase shift introduced by spectral asymmetry during amplification can be restrained. This type of scheme, applied in our experiment, can be used for further development of a high power laser with ultrashort pulse and wide spectrum.

5.
Opt Lett ; 37(15): 3021-3, 2012 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-22859072

RESUMO

We experimentally explored the influence of passive harmonic mode locking on the temporal and spectral features of a ytterbium-doped fiber laser. Similar dependences of free-running linewidth of the laser carrier-envelope offset frequency (f0) on the intracavity net dispersion were observed for the fundamental-, second-, and third-order mode-locking states. Due to the reduction of nonlinear effects and supermode phase locking that balanced the third-order dispersion in the fiber cavity, the third-order harmonic mode-locking exhibited the narrowest free-running f0 linewidth of ~120 kHz in the near-zero net dispersion regime.

6.
Opt Lett ; 37(9): 1511-3, 2012 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-22555721

RESUMO

We report on a simple scheme to precisely control carrier-envelope phase of a nonlinear-polarization-rotation mode-locked self-started Yb-fiber laser system with an average output power of ∼7 W and a pulse width of 130 fs. The offset frequency was locked to the repetition rate of ∼64.5 MHz with a relative linewidth of ∼1.4 MHz by using a self-referenced feed-forward scheme based on an acousto-optic frequency shifter. The phase noise and timing jitter were calculated to be 370 mrad and 120 as, respectively.

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