Catalysts for gaseous organic sulfur removal.

Organic sulfur gases (COS, CS2 and CH3SH) are widely present in reducing industrial off-gases, and these substances pose difficulties for the recovery of carbon monoxide and other gases. The reaction pathways and reaction mechanisms of organic sulfur on different catalyst surfaces have yet to be fully summarized. The literature shows that many factors, such as catalyst synthesis method, loaded metal composition, number of surface hydroxyl groups, number of acid-base sites and methods of surface modification, have important effects on the catalytic performance of metal catalysts. Therefore, this paper presents a comprehensive review of the research on the application of catalysts such as zeolites, metal oxides, carbon-based materials, and hydrotalcite-like derivatives in the field of organic sulfur removal. Future research prospects are summarized, more in situ characterization experiments and theoretical calculations are needed for the catalytic decomposition of methanethiol to analyze the coke generation pathways at the microscopic level, while the simultaneous removal of multiple organic sulfur gases needs to be focused on. Based on previous catalyst research, we propose possible innovations in catalyst design, desulfurization technology and organic sulfur resource utilization technology.

Observation of hybrid higher-order skin-topological effect in non-Hermitian topolectrical circuits.

Robust boundary states epitomize how deep physics can give rise to concrete experimental signatures with technological promise. Of late, much attention has focused on two distinct mechanisms for boundary robustness-topological protection, as well as the non-Hermitian skin effect. In this work, we report the experimental realizations of hybrid higher-order skin-topological effect, in which the skin effect selectively acts only on the topological boundary modes, not the bulk modes. Our experiments, which are performed on specially designed non-reciprocal 2D and 3D topolectrical circuit lattices, showcases how non-reciprocal pumping and topological localization dynamically interplays to form various states like 2D skin-topological, 3D skin-topological-topological hybrid states, as well as 2D and 3D higher-order non-Hermitian skin states. Realized through our highly versatile and scalable circuit platform, theses states have no Hermitian nor lower-dimensional analog, and pave the way for applications in topological switching and sensing through the simultaneous non-trivial interplay of skin and topological boundary localizations.

Study on the role of copper converter slag in simultaneously removing SO2 and NOx using KMnO4/copper converter slag slurry.

To achieve "waste controlled by waste", a novel wet process using KMnO4/copper converter slag slurry for simultaneously removing SO2 and NOx from acid-making tail gas was proposed. Through the solid-liquid separation for copper slag slurry, the liquid-phase part has a critical influence on removing NOx and SO2. Also, the leached metal ions played a crucial role in the absorption of SO2 and NOx. Subsequently, the effects of single/multi-metal ions on NOx removal was investigated. The results showed that the leached metal from copper converter slag (Al3+, Cu2+, and Mg2+) and KMnO4 had a synergistic effect on NOx removal, thereby improving the NOx removal efficiency. Whereas Fe2+ had an inhibitory effect on the NOx removal owing to the reaction between Fe2+ and KMnO4, thereby consuming the KMnO4. Besides, SO2 was converted to SO42- completely partly due to the liquid catalytic oxidation by metal ions. The XRD and XPS results indicated that the Fe (II) species (Fe2SiO4, Fe3O4) in copper slag can react with H+ ions with the generation of Fe2+, and further consumed the KMnO4, thereby resulting in a decrease in the NOx removal. The characterization of the slags and solutions before and after reaction led us to propose the possible mechanisms. The role of copper slag is as follows: (1) the alkaline substances in copper slag can absorb SO2 and NO2 by KMnO4 oxidation. (2) copper slag may function as a catalyst to accelerate SO2 conversion and improve NOx removal by synergistic effect between leached metal ions and KMnO4.

Experimental Observation of Higher-Order Topological Anderson Insulators.

Recently, a new family of symmetry-protected higher-order topological insulators has been proposed and was shown to host lower-dimensional boundary states. However, with the existence of the strong disorder in the bulk, the crystal symmetry is broken, and the associated corner states are disappeared. It is well known that the emergence of robust edge states and quantized transport can be induced by adding sufficient disorders into a topologically trivial insulator, that is the so-called topological Anderson insulator. The question is whether disorders can also cause the higher-order topological phase. This is not known so far, because interactions between disorders and the higher-order topological phases are completely different from those with the first-order topological system. Here, we demonstrate theoretically that the disorder-induced higher-order topological corner state and quantized fraction corner charge can appear in a modified Haldane model. In experiments, we construct the classical analog of such higher-order topological Anderson insulators using electric circuits and observe the disorder-induced corner state through the voltage measurement. Our work defies the conventional view that the disorder is detrimental to the higher-order topological phase, and offers a feasible platform to investigate the interaction between disorders and higher-order topological phases.