Temperature overshoot responses to ambitious forestation in an Earth System Model.

Despite the increasing relevance of temperature overshoot and the rather ambitious country pledges on Afforestation/Reforestation globally, the mitigation potential and the Earth system responses to large-scale non-idealized Afforestation/Reforestation patterns under a high overshoot scenario remain elusive. Here, we develop an ambitious Afforestation/Reforestation scenario by harnessing 1259 Integrated Assessment Model scenarios, restoration potential maps, and biodiversity constraints, reaching 595 Mha by 2060 and 935 Mha by 2100. We then force the Max Planck Institute's Earth System Model with this scenario which yields a reduction of peak temperature by 0.08 oC, end-of-century temperature by 0.2 oC, and overshoot duration by 13 years. Afforestation/Reforestation in the range of country pledges globally could thus constitute a useful mitigation tool in overshoot scenarios in addition to fossil fuel emission reductions, but socio-ecological implications need to be scrutinized to avoid severe side effects.

Composite interfaces of g-C3N4 fragments loaded on a Cu substrate for CO2 reduction.

Designing an electrocatalyst with high efficiency and product selectivity is always crucial for an electrocatalytic CO2 reduction reaction (CO2RR). Inspired by the great progress of two-dimensional (2D) nanomaterials growing on Cu surfaces and their promising CO2RR catalytic efficiencies at their interfaces, the unique performance of Cu-based 2D materials as high-efficiency and low-cost CO2RR electrocatalysts has attracted extensive attention. Herein, based on density functional theory (DFT) calculations, we proposed a composite structure of graphitic carbon nitride (g-C3N4) fragments loaded on a Cu surface to explore the CO2RR catalytic property of the interface between g-C3N4 and the Cu surface. Three composite interfaces of C3N4/Cu(111), C3N4/Cu(110) and C3N4/Cu(100) have been studied by considering the reaction sites of vertex nitrogen atoms, edge nitrogen atoms and the nearby Cu atoms. It was found that the C3N4/Cu interfaces where nitrogen atoms contact the Cu substrate present competitive CO2RR activity. Among them, C3N4/Cu(111)-N3 exhibited a better activity for CH3OH production, with a low overpotential of 0.38 V. For HCOOH and CH4 production, C3N4/Cu(111)-Cu and C3N4/Cu(100)-N1 have overpotentials of 0.26 V and 0.44 V. The electronic analysis indicates the electron transfer from the Cu substrate to the g-C3N4 fragment and mainly accumulates on the nitrogen atoms of the interface. Such charge accumulation can activate the adsorbed CO bond of CO2 and lead to lower energetic barriers of CO2RR. DFT calculations indicate that the boundary nitrogen sites reduced the energy barrier of *CHO, which is crucial for CO2RR, compared with that of the pristine Cu surface. Our study explores a new Cu-based electrocatalyst and indicates that the C3N4/Cu interface can enhance the activities and selectivity of CO2RR and open a new strategy to design high-efficiency electrocatalysts for CO2RR.

How to reconcile land use conflicts in mega urban agglomeration? A scenario-based study in the Beijing-Tianjin-Hebei region, China.

With the development of global urbanization, land use conflicts have become one of the major issues hindering sustainable land use and human-environment coordination in urbanized areas. In this context, reconciliation of land use conflicts requires urgent attention. By taking the Beijing-Tianjin-Hebei (BTH) urban agglomeration as a case study area, the spatial comprehensive conflict index (SCCI) was constructed to identify and evaluate land use conflicts. Besides, the impacts of rapid urbanization and terrain restriction on land use conflicts were also explored using the coupling coordination degree (CCD) model and terrain index, respectively. Then, the Dyna-CLUE model was adopted to simulate land use conflicts under three adaptive scenarios in 2030. Results show that: (1) During 2000-2015, land use conflicts in the BTH region demonstrated an overall mitigating trend, and their spatial patterns remained relatively stable, characterized by significant cluster and belt agglomeration. (2) Land use conflicts were significantly intensified in areas experiencing rapid urban-rural transformation and terrain transition, and two typical conflict zones were identified, i.e. the urban-rural interface of the Beijing-Tianjin region and the terrain transition area located in the Taihang Mountains, Yan Mountains and Bashang Plateau. (3) In 2030, land use conflicts in the BTH region manifest overall mitigation under the ecological security (ES) scenario, while demonstrating an intensifying trend under the business as usual (BAU) scenario and cropland protection (CP) scenario. Based on simulation results, land use spatial optimization modes at county level for the BTH region were formulated. In face of increasingly prominent land use conflicts globally, this study will provide a scientific reference for policymaking in pursuit of sustainable land use management for the BTH region and urban agglomerations in other parts of the world.

Palladium-Catalyzed Regioselective Coupling Cyclohexenone into Indoles: Atom-Economic Synthesis of ß-Indolyl Cyclohexenones and Derivatization Applications.

Herein, we report a palladium-catalyzed dehydrogenative cross-coupling of indoles with cyclic enones to give ß-indolyl cyclic enones under mild and neutral reaction conditions. The key to the success is to explore a mild condition, which ensures the indole C-H activation and subsequent syn ß-hydride elimination through rapid enolization isomerization of Pd(II)-enolate while suppressing other undesired side reactions. Synthetic utility has also been demonstrated in the flexible transformation of the coupling products to meta-phenols and benzo[a]carbazoles.