Elucidating sources of VOCs in the Capital Region of New York State: Implications to secondary transformation and public health exposure.

Exposure to ambient volatile organic compounds (VOCs) in urban areas is of interest because of their potential adverse effects to public health. A study was carried out to elucidate ambient sources of VOCs in the Capital Region of New York State for the period 2015-2019. A combined dataset of VOCs and PM2.5 species was used in positive matrix factorization (PMF) model to better interpret the complex nature of different sources. Ten sources were revealed, where background source (3.8 µg/m3, 30%) was the largest contributor to VOCs, followed by petroleum-related emissions (2.9 µg/m3, 22%) and pyrolyzed oxygen (OP)-Elemental Carbon (EC2)-aldehydes-rich (2.7 µg/m3, 21%). Other notable VOC sources included methyl ethyl ketone (MEK)-rich, vehicular traffic, and biomass burning. Both OP-EC2-aldehydes-rich and petroleum-related emissions showed notable contribution to ozone (O3) and secondary organic aerosol (SOA) formation, respectively. Observed mean carcinogenic risk values of benzene and formaldehyde and 95th percentiles risk values of 1,3-butadiene and acetaldehyde were above the USEPA acceptable level of 1x10-6 but below a tolerable risk of 1x10-4. Estimated carcinogenic risk values of OP-EC2-aldehydes-rich, vehicular traffic, background and petroleum-related emissions were above the USEPA acceptable cancer risk and posed greater risk to public health (more than 80% of total carcinogenic risk) compared to other sources. Due to lack of some VOC species data (e.g., alkanes, alkenes, terpenes, alcohols), other urban VOC sources e.g., fugitive emissions, fuel evaporation, unburned fuel were not identified. More work is needed to better understand the contribution of VOC sources to O3 and SOA formation in Albany and surrounding region. Findings can support policy makers in developing appropriate air quality management initiatives for the Capital Region in New York State.

Ambient volatile organic compounds (VOCs) in two coastal cities in western Canada: Spatiotemporal variation, source apportionment, and health risk assessment.

Ambient volatile organic compounds (VOCs) in urban areas is of great interest due to their important roles in the atmospheric photochemistry as well as their potential adverse effects on public health. Limited information is available on the spatiotemporal variation, sources, and health risks of VOCs in the coastal cities of Canada, where the population density is much higher than inland areas. In this study, we investigated ambient VOCs levels, their potential sources and associated health risks in two coastal cities in Metro Vancouver during 2012-2016. Levels of the total measured VOCs were relatively higher in an industrial region in Port Moody (56.7 µg/m3) than an urban area of Burnaby south (38.0 µg/m3). A clear seasonality was observed for VOCs species with significantly higher levels in winter than in summer except for isoprene. Alkanes were the most dominant compounds at both sites accounting for up to 59.4% of the total measured VOCs, followed by halocarbons, aromatics, and alkenes. Industrial-related emissions (30.5%) and traffic-related emissions (35.8%) were the major sources contributing to ambient VOCs in Port Moody and Burnaby south, respectively, as calculated by the positive matrix factorization (PMF) model. A hybrid health risk assessment strategy using deterministic and stochastic approaches revealed that non-cancer risks of ambient VOCs exposure were all below the safe level of 1 at both cities, while the cumulative cancer risks of toxic VOCs exposure in Port Moody (9.2 × 10-5) and Burnaby south (7.6 × 10-5) were significantly higher than the provincial acceptable risk level (1.0 × 10-5). Surprisingly, the probabilities for cumulative cancer risks of VOCs exceeding the US EPA tolerable risk level (1.0 × 10-4) were 33.7% and 18.6% in Port Moody and Burnaby south, respectively. From a risk management perspective, greater emphasis on the reduction of emissions of carbon tetrachloride, benzene, and 1,3-butadiene is highly recommended in both cities of Metro Vancouver.

Airborne particles in the city center of Kuala Lumpur: Origin, potential driving factors, and deposition flux in human respiratory airways.

Equatorial warming conditions in urban areas can influence the particle number concentrations (PNCs), but studies assessing such factors are limited. The aim of this study was to evaluate the level of size-resolved PNCs, their potential deposition rate in the human respiratory system, and probable local and transboundary inputs of PNCs in Kuala Lumpur. Particle size distributions of a 0.34 to 9.02 µm optical-equivalent size range were monitored at a frequency of 60 s between December 2016 and January 2017 using an optical-based compact scanning mobility particle sizer (SMPS). Diurnal and correlation analysis showed that traffic emissions and meteorological confounding factors were potential driving factors for changes in the PNCs (Dp ≤1 µm) at the modeling site. Trajectory modeling showed that a PNC <100/cm3 was influenced mainly by Indo-China region air masses. On the other hand, a PNC >100/cm3 was influenced by air masses originating from the Indian Ocean and Indochina regions. Receptor models extracted five potential sources of PNCs: industrial emissions, transportation, aged traffic emissions, miscellaneous sources, and a source of secondary origin coupled with meteorological factors. A respiratory deposition model for male and female receptors predicted that the deposition flux of PM1 (particle mass ≤1 µm) into the alveolar (AL) region was higher (0.30 and 0.25 µg/h, respectively) than the upper airway (UA) (0.29 and 0.24 µg/h, respectively) and tracheobronchial (TB) regions (0.02 µg/h for each). However, the PM2.5 deposition flux was higher in the UA (2.02 and 1.68 µg/h, respectively) than in the TB (0.18 and 0.15 µg/h, respectively) and the AL regions (1.09 and 0.91 µg/h, respectively); a similar pattern was also observed for PM10.

Ambient volatile organic compounds (VOCs) in Calgary, Alberta: Sources and screening health risk assessment.

Exposure to ambient volatile organic compound (VOCs) in urban areas is of interest because of their potential chronic and acute adverse effects to public health. Limited information is available about VOC sources in urban areas in Canada. An investigation of ambient VOCs levels, their potential sources and associated risks to public health was undertaken for the urban core of Alberta's largest city (downtown Calgary) for the period 2010-2015. Twenty-four hour arithmetic and geometric mean concentrations of total VOCs were 42µg/m3 and 39µg/m3, respectively and ranged from 16 to 160µg/m3, with winter levels about two-fold higher than summer. Alkanes (58%) were the most dominant compounds followed by halogenated VOCs (22%) and aromatics (11%). Mean and maximum 24h ambient concentrations of selected VOCs of public health concern were below chronic and acute health risk screening criteria of the United States regulatory agencies and a cancer screening benchmark used in Alberta equivalent to 1 in 100,000 lifetime risk. The Positive matrix factorization (PMF) model revealed nine VOC sources at downtown Calgary, where oil/natural gas extraction/combustion (26%), fuel combustion (20%), traffic sources including gasoline exhaust, diesel exhaust, mixed fugitive emissions (10-15%), and industrial coatings/solvents (12%) were predominant. Other sources included dry cleaning (3.3%), biogenic (3.5%) and a background source (18%). Source-specific health risk values were also estimated. Estimated cancer risks for all sources were below the Alberta cancer screening benchmark, and estimated non-cancer risks for all sources were well below a safe level.

Ambient volatile organic compounds (VOCs) in communities of the Athabasca oil sands region: Sources and screening health risk assessment.

An investigation of ambient levels and sources of volatile organic compounds (VOCs) and associated public health risks was carried out at two northern Alberta oil sands communities (Fort McKay and Fort McMurray located < 25 km and >30 km from oil sands development, respectively) for the period January 2010-March 2015. Levels of total detected VOCs were comparatively similar at both communities (Fort McKay: geometric mean = 22.8 µg/m3, interquartile range, IQR = 13.8-41 µg/m3); (Fort McMurray: geometric mean = 23.3 µg/m3, IQR = 12.0-41 µg/m3). In general, methanol (24%-50%), alkanes (26%-32%) and acetaldehyde (23%-30%) were the predominant VOCs followed by acetone (20%-24%) and aromatics (∼9%). Mean and maximum ambient concentrations of selected hazardous VOCs were compared to health risk screening criteria used by United States regulatory agencies. The Positive matrix factorization (PMF) model was used to identify and apportion VOC sources at Fort McKay and Fort McMurray. Five sources were identified at Fort McKay, where four sources (oil sands fugitives, liquid/unburned fuel, ethylbenzene/xylene-rich and petroleum processing) were oil sands related emissions and contributed to 70% of total VOCs. At Fort McMurray six sources were identified, where local sources other than oil sands development were also observed. Contribution of aged air mass/regional transport including biomass burning emissions was ∼30% of total VOCs at both communities. Source-specific carcinogenic and non-carcinogenic risk values were also calculated and were below acceptable and safe levels of risk, except for aged air mass/regional transport (at both communities), and ethylbenzene/xylene-rich (only at Fort McMurray).

Ambient fine particulate matter (PM2.5) in Canadian oil sands communities: Levels, sources and potential human health risk.

An investigation of levels and potential sources affecting ambient fine particulate matter (PM2.5) and associated risk to public health was undertaken at two Canadian oil sands communities (Fort McKay and Fort McMurray) using a 4-year dataset (2010-2013). Geometric mean concentrations of PM2.5 at Fort McKay and Fort McMurray are not considered high and were 5.47µg/m3 (interquartile range, IQR=3.02-8.55µg/m3) and 4.96µg/m3 (IQR=3.20-7.04µg/m3), respectively. Carcinogenic risks of trace elements were below acceptable (1×10-6) and/or within tolerable risk (1×10-4), and non-carcinogenic risks were below a safe level of concern (hazard index=1). Positive matrix factorization (PMF) modeling revealed five sources, where fugitive dust appeared as the major contributor to PM2.5 mass (Fort McKay: 32%, Fort McMurray: 46%) followed by secondary sulfate (31%, 42%) and secondary nitrate/biomass burning (26%, 8%). Other minor sources included a mining/mobile and a Mn-rich/Mn-Co-Zn-rich source. Source-specific risk values were also estimated and were well below acceptable and safe level of risks. Further work would be needed to better understand the contribution of secondary organic aerosols to PM2.5 formation in these oil sands communities.

Concentrations, sources and human health risk of inhalation exposure to air toxics in Edmonton, Canada.

With concern about levels of air pollutants in recent years in the Capital Region of Alberta, an investigation of ambient concentrations, sources and potential human health risk of hazardous air pollutants (HAPs) or air toxics was undertaken in the City of Edmonton over a 5-year period (2009-2013). Mean concentrations of individual HAPs in ambient air including volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs) and trace metals ranged from 0.04 to 1.73 µg/m3, 0.01-0.54 ng/m3, and 0.05-3.58 ng/m3, respectively. Concentrations of benzene, naphthalene, benzo(a)pyrene (BaP), arsenic, manganese and nickel were far below respective annual Alberta Ambient Air Quality Objectives. Carcinogenic and non-carcinogenic risk of air toxics were also compared with risk levels recommended by regulatory agencies. Positive matrix factorization identified six air toxics sources with traffic as the dominant contributor to total HAPs (4.33 µg/m3, 42%), followed by background/secondary organic aerosol (SOA) (1.92 µg/m3, 25%), fossil fuel combustion (0.92 µg/m3, 11%). On high particulate air pollution event days, local traffic was identified as the major contributor to total HAPs compared to background/SOA and fossil fuel combustion. Carcinogenic risk values of traffic, background/SOA and metals industry emissions were above the USEPA acceptable level (1 × 10-6), but below a tolerable risk (1 × 10-4) and Alberta benchmark (1 × 10-5). These findings offer useful preliminary information about current ambient air toxics levels, dominant sources and their potential risk to public health; and this information can support policy makers in the development of appropriate control strategies if required.

Characteristics of air quality and sources affecting fine particulate matter (PM2.5) levels in the City of Red Deer, Canada.

With concern about levels and exceedances of Canadian and provincial standards and objectives for fine particulate matter (PM2.5) in recent years, an investigation of air quality characteristics and potential local and long-range sources influencing PM2.5 concentrations was undertaken in the City of Red Deer, Alberta. The study covered the period May 2009 to December 2015. Comparatively higher concentrations of PM2.5 were observed in winter (mean: 11.6 µg/m3, median: 10 µg/m3) than in summer (mean: 9.0 µg/m3, median: 7.0 µg/m3). Exceedances of the 1 h Alberta Ambient Air Quality objective (3-31 times per year > 80 µg/m3) and the 24 h Canada-Wide Standard (2-11 times per year > 30 µg/m3) were found at the Red Deer Riverside air monitoring station, particularly in 2010, 2011 and 2015. Positive matrix factorization (PMF) followed by multiple linear regression (MLR) analysis identified a mixed industry/agriculture factor as the dominant contributor to PM2.5 (39.3%), followed by an O3-rich (biogenic) factor (26.4%), traffic (19.3%), biomass burning (10.5%) and a mixed urban factor (4.4%). In addition to local traffic, the mixed industry/agriculture factor - inferred as mostly upstream oil and gas emission sources surrounding Red Deer - was identified as another potentially important source contributing to wintertime high PM2.5 pollution days. These findings offer useful preliminary information about current PM2.5 sources and their potential contributions in Red Deer; and this information can support policy makers in the development of particulate matter control strategies if required.

Fine particulate matter (PM2.5) in Edmonton, Canada: Source apportionment and potential risk for human health.

To design effective PM2.5 control strategies in urban centers, there is a need to better understand local and remote sources influencing PM2.5 levels and associated risk to public health. An investigation of PM2.5 levels, sources and potential human health risk associated with trace elements in the PM2.5 was undertaken in Edmonton over a 6-year period (September 2009-August 2015). The geometric mean PM2.5 concentration of was 7.11 µg/m3 (interquartile range, IQR = 4.83-10.08 µg/m3). Positive matrix factorization (PMF) receptor modeling identified secondary organic aerosol (SOA) as the major contributor (2.2 µg/m3, 27%), followed by secondary nitrate (1.3 µg/m3, 17%) and secondary sulfate (1.2 µg/m3, 15%). Other local sources included transportation (1.1 µg/m3, 14%) and industry-related emissions (0.26 µg/m3, 3.4%), biomass burning (1.0 µg/m3, 13%) and soil (0.54 µg/m3, 6.8%). Five factors (i.e., SOA, secondary nitrate, secondary sulfate, transportation and biomass burning) contributed more than 85% to PM2.5 for the 2009-2015 period. Geometric (arithmetic) mean and maximum ambient air concentrations for hazardous trace elements of public health concern in PM2.5 during the study period were below United States regulatory agency chronic and acute health risk screening criteria. Carcinogenic and non-carcinogenic risk of trace elements and source-specific risk values were well below acceptable and safe levels of risks recommended by regulatory agencies. More work is needed to understand the origin of potential SOA and wintertime wood burning sources in Edmonton and the surrounding region and to apply source-risk apportionment using all available hazardous air pollutants (HAPs) including organic compounds to better interpret the potential health risk posed by various sources in urban areas.

Evaluation of air quality indicators in Alberta, Canada - An international perspective.

There has been an increase in oil sands development in northern Alberta, Canada and an overall increase in economic activity in the province in recent years. An evaluation of the state of air quality was conducted in four Alberta locations - urban centers of Calgary and Edmonton, and smaller communities of Fort McKay and Fort McMurray in the Athabasca Oil Sands Region (AOSR). Concentration trends, diurnal hourly and monthly average concentration profiles, and exceedances of provincial, national and international air quality guidelines were assessed for several criteria air pollutants over the period 1998 to 2014. Two methods were used to evaluate trends. Parametric analysis of annual median 1h concentrations and non-parametric analysis of annual geometric mean 1h concentrations showed consistent decreasing trends for NO2 and SO2 (<1ppb per year), CO (<0.1ppm per year) at all stations, decreasing for THC (<0.1ppm per year) and increasing for O3 (≤0.52ppb per year) at most stations and unchanged for PM2.5 at all stations in Edmonton and Calgary over a 17-year period. Little consistency in trends was observed among the methods for the same air pollutants other than for THC (increasing in Fort McKay <0.1ppm per year and no trend in Fort McMurray), PM2.5 in Fort McKay and Fort McMurray (no trend) and CO (decreasing <0.1ppm per year in Fort McMurray) over the same period. Levels of air quality indicators at the four locations were compared with other Canadian and international urban areas to judge the current state of air quality. Median and annual average concentrations for Alberta locations tended to be the smallest in Fort McKay and Fort McMurray. Other than for PM2.5, Calgary and Edmonton tended to have median and annual average concentrations comparable to and/or below that of larger populated Canadian and U.S. cities, depending upon the air pollutant.

Eight-year (2007-2014) trends in ambient fine particulate matter (PM2.5) and its chemical components in the Capital Region of Alberta, Canada.

Currently there have been questions about ambient fine particulate matter (PM2.5) levels in the Capital Region of Alberta, Canada. An investigation of temporal trends in PM2.5 and its chemical components was undertaken in the City of Edmonton within the Capital Region over an 8-year period (2007-2014). A non-parametric trend detection method was adopted to characterize trends in ambient concentrations. No statistically significant change was observed for ambient PM2.5 concentrations during 2007-2014, while significant decreasing trends were found for organic carbon, elemental carbon, oxalate, barium, lead and cadmium. A statistically significant increasing trend was observed for sodium chloride indicating an increase of de-icing salt contribution for winter road maintenance in recent years. Concentrations of potassium ion and zinc exhibited strong and significant seasonal variability with higher concentrations in winter than in summer likely reflecting wood smoke origins more than other potential sources in Edmonton and the surrounding region. No statistically significant changes were observed for all other chemical components examined. Notwithstanding robust population growth that has occurred in Edmonton, these findings reveal that particulate air quality and corresponding trace elements in Edmonton's air has been unchanged or improved over the investigated period (2007-2014). Longer-term air quality monitoring at least over several decades is needed to establish whether trends reported here are actually occurring.

Twelve-year trends in ambient concentrations of volatile organic compounds in a community of the Alberta Oil Sands Region, Canada.

Environmental exposure to volatile organic compounds (VOCs) in ambient air is one of a number of concerns that the First Nation Community of Fort McKay, Alberta has related to development of Canada's oil sands. An in-depth investigation of trends in ambient air VOC levels in Fort McKay was undertaken to better understand the role and possible significance of emissions from Alberta's oil sands development. A non-parametric trend detection method was used to investigate trends in emissions and ambient VOC concentrations over a 12-year (2001-2012) period. Relationships between ambient VOC concentrations and production indicators of oil sands operations around Fort McKay were also examined. A weak upward trend (significant at 90% confidence level) was found for ambient concentrations of total VOCs based on sixteen detected species with an annual increase of 0.64µg/m(3) (7.2%) per year (7.7µg/m(3) increase per decade). Indicators of production (i.e., annual bitumen production and mined oil sands quantities) were correlated with ambient total VOC concentrations. Only one of 29 VOC species evaluated (1-butene) showed a statistically significant upward trend (p=0.05). Observed geometric (arithmetic) mean and maximum ambient concentrations of selected VOCs of public health concern for most recent three years of the study period (2010-2012) were below chronic and acute health risk screening criteria of the U.S. Agency for Toxic Substances and Disease Registry and U.S. Environmental Protection Agency. Thirty-two VOCs are recommended for tracking in future air quality investigations in the community to better understand whether changes are occurring over time in relation to oil sands development activities and to inform policy makers about whether or not these changes warrant additional attention.

Indoor and Outdoor Levels and Sources of Submicron Particles (PM1) at Homes in Edmonton, Canada.

Exposure to submicron particles (PM1) is of interest due to their possible chronic and acute health effects. Seven consecutive 24-h PM1 samples were collected during winter and summer 2010 in a total of 74 nonsmoking homes in Edmonton, Canada. Median winter concentrations of PM1 were 2.2 µg/m(3) (interquartile range, IQR = 0.8-6.1 µg/m(3)) and 3.3 µg/m(3) (IQR = 1.5-6.9 µg/m(3)) for indoors and outdoors, respectively. In the summer, indoor (median 4.4 µg/m(3), IQR = 2.4-8.6 µg/m(3)) and outdoor (median 4.3 µg/m(3), IQR = 2.6-7.4 µg/m(3)) levels were similar. Positive matrix factorization (PMF) was applied to identify and apportion indoor and outdoor sources of elements in PM1 mass. Nine sources contributing to both indoor and outdoor PM1 concentrations were identified including secondary sulfate, soil, biomass smoke and environmental tobacco smoke (ETS), traffic, settled and mixed dust, coal combustion, road salt/road dust, and urban mixture. Three additional indoor sources were identified i.e., carpet dust, copper-rich, and silver-rich. Secondary sulfate, soil, biomass smoke and ETS contributed more than 70% (indoors: 0.29 µg/m(3), outdoors: 0.39 µg/m(3)) of measured elemental mass in PM1. These findings can aid understanding of relationships between submicron particles and health outcomes for indoor/outdoor sources.

Particle-phase concentrations of polycyclic aromatic hydrocarbons in ambient air of rural residential areas in southern Germany.

An important source of polycyclic aromatic hydrocarbons (PAHs) in residential areas, particularly in the winter season, is the burning process when wood is used for domestic heating. The target of this study was to investigate the particle-phase PAH composition of ambient samples in order to assess the influence of wood combustion on air quality in residential areas. PM(10) samples (particulate matter <10 mum) were collected during two winter seasons at two rural residential areas near Stuttgart in Germany. Samples were extracted using toluene in an ultrasonic bath and subsequently analysed by gas chromatography-mass spectrometry. Twenty-one PAH compounds were detected and quantified. The PAH fingerprints of different wood combustion emissions were found in significant amounts in ambient samples and high correlations between total PAHs and other wood smoke tracers were found, indicating the dominant influence of wood combustion on air quality in residential areas. Carcinogenic PAHs were detected in high concentrations and contributed 49% of the total PAHs in the ambient air. To assess the health risk, we investigated the exposure profile of individual PAHs. The findings suggest that attention should be focused on using the best combustion technology available to reduce emissions from wood-fired heating during the winter in residential areas.