Efficient eradication of antibiotic and dye by C-dots@zeolite nanocomposites: Performance evaluation, and degraded products analysis.

Metronidazole (MET), a recalcitrant antibiotic from the nitro-imidazole family and commercially used Rhodamine B (RhB) dye, contributes a huge to water pollution, which needs to eliminate, preferably by photocatalytic degradation technique. The Cdots@zeolite (CDZ) nanocomposites with different weight ratios (1:1, 1:3, 1:5, 5:1, 1:7) were synthesized hydrothermally to degrade MET and RhB molecules. The CDZ composites were characterized by XRD, BET, EDS, and XPS technique which verifies the crystalline nature, incorporation of C-dots into zeolite frameworks with high surface area (∼187 m2/g). The morphology, d-spacing and lattice planes were analyzed by SEM images, HR-TEM and SAED analysis. The maximum degradation (∼79%) was achieved at an optimum catalyst dose of 0.2 g/L and pH 4 for MET and that of RhB was ∼90% at a catalyst dose of 0.4 g/L. The PZC (point of zero charge) value for CDZ composite was about pH 3.4, which justifies the maximum removal of MET at pH 4. The obtained rate constants 'k' were found to be 0.0081, 0.0041, and 0.0101 min-1 in sun, UV, and visible light sources, respectively. The real industrial wastewater sample has been treated to give ∼68% of COD and ∼62% TOC removal. Moreover, the intermediates of plausible degradation pathways were identified by the m/z values obtained from GC-MS analysis.

Post-fabrication structural changes and enhanced photodegradation activity of semiconductors@zeolite composites towards noxious contaminants.

This review article provides the recent progress in semiconductor-based zeolite photoactive materials for the application of noxious contaminants removal. The rapidly expanding industrialization and globalization cause serious threats to the environment or water bodies. The semiconductor@zeolite photocatalysts were implemented for water quality management/sustainment. The exclusive properties of zeolite material have been elaborated with their role in the photocatalysis process. The photoactive material's properties like single-atom catalysts (SACs), distribution of metal in the zeolite crystal were elaborated along with their role in catalytic reactions. Differently prepared semiconductor@zeolite composites such as TiO2@zeolite, binary and ternary composites, Fe/Ag/bismuth-modified/ZnO/ZnS/NiO/g-C3N4/core-shell/quantum dots modified zeolite composites, were systematically summarized. The research progress in morphologies, structural effect, degradation mechanism were recapitulated and tabulated form of % degradation with their optimal parameters such as catalyst dose, pollutant concentrations, pH, light source intensities were also provided. The significance of zeolite frameworks, the structural properties of semiconductor@zeolite photoactive materials to enhance the degradation efficiencies was explored. Analysis of the intermediate products of Norfloxacin, TCDD (2,3,7,8-tetrachlorodibenzo-p-dioxin), TCDF (2,3,7,8-tetrachlorodibenzofuran), diclofenac contaminants were systematically represented and structurally identified by GC-MS/HPLC-MS techniques.

Degradation of pharmaceutical drug paracetamol via UV irradiation using Fe-TiO2 composite photocatalyst: statistical analysis and parametric optimization.

In the present investigation, a novel Fe-TiO2 composite was fabricated by mixing fly ash (FA), foundry sand (FS), and bentonite clay for the degradation of paracetamol (PCM). This composite acts as a surface for immobilizing the TiO2 catalyst (using the dip-coating method) besides facilitating the leaching of iron (FA and FS) in acidic conditions. Leached iron (in the form of Fe(II), Fe(III), and total iron) promotes the photo-Fenton (with the addition of H2O2 in the system) while the surface-active TiO2 layer leads to photocatalysis, thus leading to in situ dual process combining photocatalysis and photo-Fenton in one system. This dual process led to a synergy of 75% in comparison to the photocatalysis and photo-Fenton process owing to the large production of •OH. Various parameters such as H2O2 dose (525 mg l-1), number of beads (80), degradation time (215 min), and volume (200 ml) were optimized, and 96.6% of reduction in PCM was observed. Durability study of catalyst showed a minor reduction in the activity of the catalyst after 30 cycles. The TiO2 catalyst was still intact as a film, and iron leaching was also occurring from the beads even after recycling, thus confirming their long-term durability in terms of dual effect. The stability and durability of the composite were confirmed by characteristic analysis such as SEM/EDS. Mineralization of PCM was concluded through the estimation of degradation by-products using GC-MS analysis followed by estimation of nitrate and nitrite ions.

Complete removal of endocrine disrupting compound and toxic dye by visible light active porous g-C3N4/H-ZSM-5 nanocomposite.

Photocatalytic degradation of toxic pollutants is an efficient technique to completely remove the toxic pollutants from water bodies. In the present investigation, photocatalytic degradation of pollutants was studied over porous g-C3N4/H-ZSM-5 nanocomposite under visible light irradiation. The composite g-C3N4/H-ZSM-5 was synthesized by mixing an aqueous solution of H-ZSM-5 zeolite (increases surface area and provides active sites for degradation) with melamine (precursor of g-C3N4) for 10-12 h followed by calcinations at 550 °C. The photocatalyst was characterized by XRD, BET, HRTEM, FESEM, EDS and elemental mapping analysis. These techniques confirmed that, g-C3N4/H-ZSM-5 composite have layered and porous structure with uniform distribution of g-C3N4 on H-ZSM-5 surface. The BET N2 adsorption-desorption analysis verified that the catalyst has high surface area (∼175 m2/g) having mesopores and micropores. The prepared catalyst was then used for the photodegradation of a model dye, Methylene Blue (MB) and an endocrine disrupting compound, Fipronil (FIP). Effects of various parameters such as pH, catalyst dose and scavengers were also studied. The % photocatalytic degradation of MB and FIP were around ∼92% and ∼84% with a high rate constants of 0.00997 and 0.00875 min-1, respectively. From the scavenger study, OH (hydroxyl radical) and radical was found to be the major reactive species for MB and FIP degradation. From these studies it is revealed that, the catalyst is visible active, easy to prepare and an efficient photocatalyst for toxic pollutant degradation.

Interlining Cr(VI) remediation mechanism by a novel bacterium Pseudomonas brenneri isolated from coalmine wastewater.

A bioremedial approach was investigated on the removal of Cr(VI) from aqueous solution using a novel chromium reducing bacteria isolated from coalmine wastewater. Cr(VI) removal efficacy of the bacterium was determined in a series of batch studies under the influence of various parameters viz., pH (1-7), temperature (20-40 °C), initial metal concentration (1-150 mg/L), agitation speed (80-150 rpm) and substrate concentration (1-5 mg/L). Oxygen involvement in the removal process was determined by different incubation conditions. Substrate consumption and its resultant biomass generation were considered for determining the viability of the microbe under varied metal concentration. The microbial isolate survived in Cr(VI) tainted solution with initial concentration of 1-140 mg/L, among which maximum remediation was found in 60 mg/L Cr(VI) loaded solution. The bacterial species also survived in other metal solution viz., Fe(II), As(V), Cu(II), Pb(II), Zn(II), Mg(II), Mn(II) apart from Cr(VI). Multiple approaches were tested to facilitate understanding of the bacterial Cr(VI) removal mechanism. The bacteria accumulated metal ions in the exponential growth phase both on and within the cell. Underlying latent factors which governed the bacterial growth and its removal activity was determined with the classical Monod equation. The isolated bacterium also survived in the bimetallic solutions with significant removal of Cr(VI). The microbial species isolated from mining area was identified as Pseudomonas brenneri by 16s rRNA molecular characterization. Hence, the isolated novel bacterium illustrated promising involvement towards bio-treatment of Cr(VI) laden wastewater.

Removal of emerging contaminants daidzein and coumestrol from water by nanozeolite beta modified with tetrasubstituted ammonium cation.

In present research, a simplistic hydrothermal method was adopted for one-step synthesis of nanozeolite beta (NZB) having an average particle size of 18nm with Si/Al ratio 46.67, surface area 328m2/g, pore volume 0.287cm3/g, and pore diameter 3.5nm. The surface of the synthesized NZB was modified with 0.5wt% hexadecyltrimethylammonium bromide (HDTMA-Br) and used as an adsorbent for the removal of two phytoestrogens daidzein and coumestrol from aqueous solutions. The surface properties and surface charge of NZB considerably changed after modification with HDTMA-Br, which resulted in enhanced removal of daidzein (92-98% from 7 to 27%) and coumestrol (93.5-99% from 5 to 9.2%). The surface modified zeolite beta (SMZB) has similar physical characteristics as of NZB with an average particle size of 20nm, surface area 299.8m2/g, pore volume 0.263cm3/g, and pore diameter 3.51nm. The influence of various parameters was examined by conducting a sequence of batch experiments. The adsorption equilibrium was achieved in less than 3h with saturation capacity of 40.74mg/g and 42.87mg/g for daidzein and coumestrol, respectively. The Freundlich isotherm and fractional order kinetic models represented the adsorption data very closely. The thermodynamic parameters indicated that sorption of both phytoestrogens onto SMZB is spontaneous and exothermic.

Removal of methyl orange and mythelene blue dyes from aqueous solution using low cost adsorbent zeolite synthesized from fly ash.

The zeolite ZX1 synthesized from fly ash was employed as effective adsorbent for removal of methylene blue and methyl orange, from its aqueous solution. In the present study, X-type and A-type zeolite were synthesized by alkali fusion, followed by hydrothermal treatment. The synthesized zeolite was then characterized using various techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM). Solution pH has an important role in the the adsorption behavior of ZX1. Higher solution pH results in higher adsorption capacity. The equilibrium results were well described by Freundlich isotherm model. Physical regeneration at high temperature showed that the adsorbent exhibits somehow lower adsorption capacity as compared to the fresh sample. The values of changes in enthalpy (deltaH(o)) and entropy (deltaS(o)) during the adsorption process were found to be -20.85 kJ/mol and -90.61 J/mol K(-1). Adsorption of methyl orange over Zeolite ZX1 is much higher than ZA1. Correlation coefficient was found to be 0.998.