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1.
J Acoust Soc Am ; 155(1): 742-756, 2024 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-38284824

RESUMO

The waveguide acoustic black hole (WAB) effect is a promising approach for controlling wave propagation in various applications, especially for attenuating sound waves. While the wave-focusing effect of structural acoustic black holes has found widespread applications, the classical ribbed design of waveguide acoustic black holes (WABs) acts more as a resonance absorber than a true wave-focusing device. In this study, we employ a computational design optimization approach to achieve a conceptual design of a WAB with enhanced wave-focusing properties. We investigate the influence of viscothermal boundary losses on the optimization process by formulating two distinct cases: one neglecting viscothermal losses and the other incorporating these losses using a recently developed material distribution topology optimization technique. We compare the performance of optimized designs in these two cases with that of the classical ribbed design. Simulations using linearized compressible Navier-Stokes equations are conducted to evaluate the wave-focusing performance of these different designs. The results reveal that considering viscothermal losses in the design optimization process leads to superior wave-focusing capabilities, highlighting the significance of incorporating these losses in the design approach. This study contributes to the advancement of WAB design and opens up new possibilities for its applications in various fields.

2.
Sci Rep ; 13(1): 21248, 2023 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-38040802

RESUMO

Using material distribution-based topology optimization, we optimize the bandpass design of a loudspeaker cabinet targeting low frequencies. The objective is to maximize the loudspeaker's output power for a single frequency as well as a range of frequencies. To model the loudspeaker's performance, we combine a linear electromechanical transducer model with a computationally efficient hybrid 2D-3D model for sound propagation. The adjoint variable approach computes the gradients of the objective function with respect to the design variables, and the Method of Moving Asymptotes (MMA) solves the topology optimization problem. To manage intermediate values of the material indicator function, a quadratic penalty is added to the objective function, and a non-linear filter is used to obtain a mesh independent design. By carefully selecting the target frequency range, we can guide the optimization algorithm to successfully generate a loudspeaker design with the required bandpass character. To the best of our knowledge, this study constitutes the first successful attempt to design the interior structure of a loudspeaker cabinet using topology optimization.

3.
J Acoust Soc Am ; 151(6): 4279, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35778217

RESUMO

The acoustic black hole (ABH) effect in waveguides is studied using frequency-domain finite element simulations of a cylindrical waveguide with an embedded ABH termination composed of retarding rings. This design is adopted from an experimental study in the literature, which surprisingly showed, contrary to the structural counterpart, that the addition of damping material to the end of the waveguide does not significantly reduce the reflection coefficient any further. To investigate this unexpected behavior, we model different damping mechanisms involved in the attenuation of sound waves in this setup. A sequence of computed pressure distributions indicates occurrences of frequency-dependent resonances in the device. The axial position of the cavity where the resonance occurs can be predicted by a more elaborate wall admittance model than the one that was initially used to study and design ABHs. The results of our simulations show that at higher frequencies, the visco-thermal losses and the damping material added to the end of the setup do not contribute significantly to the performance of the device. Our results suggest that the primary source of damping, responsible for the low reflection coefficients at higher frequencies, is local absorption effects at the outer surface of the cylinder.

4.
Ecology ; 103(9): e3763, 2022 09.
Artigo em Inglês | MEDLINE | ID: mdl-35612376

RESUMO

Despite our growing understanding of the global carbon cycle, scientific consensus on the drivers and mechanisms that control dissolved organic carbon (DOC) turnover in aquatic systems is lacking, hampered by the mismatch between research that approaches DOC reactivity from either intrinsic (inherent chemical properties) or extrinsic (environmental context) perspectives. Here we propose a conceptual view of DOC reactivity in which the combination of intrinsic and extrinsic factors controls turnover rates and determines which reactions will occur. We review three major types of reactions (biological, photochemical, and flocculation) from an intrinsic chemical perspective and further define the environmental features that modulate the expression of chemically inherent reactivity potential. Finally, we propose hypotheses of how extrinsic and intrinsic factors together shape patterns in DOC turnover across the land-to-ocean continuum, underscoring that there is no intrinsic DOC reactivity without environmental context. By acknowledging the intrinsic-extrinsic control duality, our framework intends to foster improved modeling of DOC reactivity and its impact on ecosystem services.


Assuntos
Matéria Orgânica Dissolvida , Ecossistema , Carbono/metabolismo , Ciclo do Carbono
5.
Glob Chang Biol ; 27(20): 5154-5168, 2021 10.
Artigo em Inglês | MEDLINE | ID: mdl-34157201

RESUMO

Stress factors such as climate change and drought may switch the role of temperate peatlands from carbon dioxide (CO2 ) sinks to sources, leading to positive feedback to global climate change. Water level management has been regarded as an important climate change mitigation strategy as it can sustain the natural net CO2 sink function of a peatland. Little is known about how resilient peatlands are in the face of future climate change scenarios, as well as how effectively water level management can sustain the CO2 sink function to mitigate global warming. The authors assess the effect of climate change on CO2 exchange of south Swedish temperate peatlands, which were either unmanaged or subject to water level regulation. Climate chamber simulations were conducted using experimental peatland mesocosms exposed to current and future representative concentration pathway (RCP) climate scenarios (RCP 2.6, 4.5 and 8.5). The results showed that all managed and unmanaged systems under future climate scenarios could serve as CO2 sinks throughout the experimental period. However, the 2018 extreme drought caused the unmanaged mesocosms under the RCP 4.5 and RCP 8.5 switch from a net CO2 sink to a source during summer. Surprisingly, the unmanaged mesocosms under RCP 2.6 benefited from the warmer climate, and served as the best sink among the other unmanaged systems. Water level management had the greatest effect on the CO2 sink function under RCP 8.5 and RCP 4.5, which improved their CO2 sink capability up to six and two times, respectively. Under the current climate scenario, water level management had a negative effect on the CO2 sink function, and it had almost no effect under RCP 2.6. Therefore, the researchers conclude that water level management is necessary for RCP 8.5, beneficial for RCP 4.5 and unimportant for RCP 2.6 and the current climate.


Assuntos
Dióxido de Carbono , Mudança Climática , Sequestro de Carbono , Ecossistema , Água
6.
Sci Rep ; 11(1): 6202, 2021 03 18.
Artigo em Inglês | MEDLINE | ID: mdl-33737556

RESUMO

The boreal forest is among the largest terrestrial biomes on earth, storing more carbon (C) than the atmosphere. Due to rapid climatic warming and enhanced human development, the boreal region may have begun transitioning from a net C sink to a net source. This raises serious concern that old biogenic soil C can be re-introduced into the modern C cycle in near future. Combining bio-decay experiments, mixing models and the Keeling plot method, we discovered a distinct old pre-bomb organic carbon fraction with high biodegradation rate. In total, 34 ± 12% of water-extractable organic carbon (WEOC) in podzols, one of the dominating boreal soil types, consisted of aged (~ 1000 year) labile C. The omission of this aged (i.e., Δ14C depleted) WEOC fraction in earlier studies is due to the co-occurrence with Δ14C enriched modern C formed following 1950s nuclear bomb testing masking its existence. High lability of aged soil WEOC and masking effects of modern Δ14C enriched C suggests that the risk for mobilization and re-introduction of this ancient C pool into the modern C cycle has gone undetected. Our findings have important implications for earth systems models in terms of climate-carbon feedbacks and the future C balance of the boreal forest.

7.
Sci Rep ; 11(1): 255, 2021 01 08.
Artigo em Inglês | MEDLINE | ID: mdl-33420220

RESUMO

A subwoofer generates the lowest frequency range in loudspeaker systems. Subwoofers are used in audio systems for live concerts, movie theatres, home theatres, gaming consoles, cars, etc. During the last decades, numerical simulations have emerged as a cost- and time-efficient complement to traditional experiments in the design process of different products. The aim of this study is to reduce the computational time of simulating the average response for a given subwoofer design. To this end, we propose a hybrid 2D-3D model that reduces the computational time significantly compared to a full 3D model. The hybrid model describes the interaction between different subwoofer components as interacting modules whose acoustic properties can partly be pre-computed. This allows us to efficiently compute the performance of different subwoofer design layouts. The results of the hybrid model are validated against both a lumped element model and a full 3D model over a frequency band of interest. The hybrid model is found to be both accurate and computationally efficient.

8.
J Acoust Soc Am ; 148(3): 1624, 2020 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-33003855

RESUMO

A method for estimating acoustic absorption in porous materials is presented in which the thermal and viscous boundary layers are modeled through boundary conditions to the Helmholtz equation for the acoustic pressure. The method is proposed for rigid-framed porous materials in which vibration of the frame is negligible compared to pressure fluctuations in air. The method reduces computation times by 2 orders of magnitude compared to a full thermoviscous acoustic solver. Furthermore, the method is shown to be highly accurate over geometrical features and frequencies of interest as long as thermal and viscous boundary layers do not overlap and the effects of the sharp changes in curvature are negligible. The method is demonstrated for a periodic sound absorber from the literature as well as a sound absorber with a randomly graded microstructure.

9.
Sci Rep ; 9(1): 14897, 2019 10 17.
Artigo em Inglês | MEDLINE | ID: mdl-31624278

RESUMO

Inland waters transport, transform and retain significant amounts of dissolved organic carbon (DOC) that may be biologically reactive (bioreactive) and thus potentially degraded into atmospheric CO2. Despite its global importance, relatively little is known about environmental controls on bioreactivity of DOC as it moves through river systems with varying water residence time (WRT). Here we determined the influence of WRT and landscape properties on DOC bioreactivity in 15 Swedish catchments spanning a large geographical and environmental gradient. We found that the short-term bioreactive pools (0-6 d of decay experiments) were linked to high aquatic primary productivity that, in turn, was stimulated by phosphorus loading from forested, agricultural and urban areas. Unexpectedly, the percentage of long-term bioreactive DOC (determined in 1-year experiments) increased with WRT, possibly due to photo-transformation of recalcitrant DOC from terrestrial sources into long-term bioreactive DOC with relatively lower aromaticity. Thus, despite overall decreases in DOC during water transit through the inland water continuum, DOC becomes relatively more bioreactive on a long time-scale. This increase in DOC bioreactivity with increasing WRT along the freshwater continuum has previously been overlooked. Further studies are needed to explain the processes and mechanisms behind this pattern on a molecular level.

10.
Mar Environ Res ; 148: 39-45, 2019 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-31078961

RESUMO

Increasing loading of terrestrially derived dissolved organic matter tends to enhance bacterioplankton respiration (BR) in boreal estuaries, but knowledge on the mechanisms behind this effect is not complete. We determined the stable isotopic signature of the reactive estuarine dissolved organic carbon (DOC) in the Öre estuary (Baltic Sea) by using the Keeling plot method. The δ13C ratio of the estuarine labile DOC varied from -26.0‰ to -18.7‰ with most values resembling those typical for DOC of coastal phytoplanktonic origin (-18 to -24‰), while being distinctly higher than those of DOC from ter-res-trial sources (-28‰ to -27‰). Furthermore, the δ13C of the respired carbon was positively correlated to DOC concentrations, indicating that carbon of marine origin increasingly dominated the reactive substrates when input of organic matter into the estuary became higher. This suggests that riverine organic matter mainly affects BR indirectly, by providing nutrients that stimulate the production of phytoplankton-derived reactive DOC in the estuary. Thus, riverine derived DOC per se may not be as important for coastal CO2 emissions as previously thought.


Assuntos
Organismos Aquáticos/química , Carbono , Estuários , Bactérias Aeróbias/metabolismo , Países Bálticos , Ciclo do Carbono , Isótopos de Carbono , Monitoramento Ambiental , Rios/química , Alga Marinha/química
11.
Environ Microbiol ; 21(4): 1425-1435, 2019 04.
Artigo em Inglês | MEDLINE | ID: mdl-30816622

RESUMO

Planktonic community respiration is an important carbon cycling process, typically quantified by converting measured values of dissolved O2 consumption rates into CO2 production rates assuming a respiratory quotient of 1 (RQ = CO2 per O2 by moles). However, the true variability in planktonic RQs between different aquatic ecosystems is poorly understood. We conducted in situ RQ measurements in a eutrophic lake dominated by algal-derived substances and found that RQs were significantly below 1. In fact, many RQ values were extremely low (0.2-0.6), below theoretical RQs for oxidation of algal organic matter substrates (0.7-0.8), suggesting that other factors than substrate control need to be considered to understand the RQ. This view was further supported by lack of correlations between RQ and microbial variables known to be strongly substrate dependent, including bacterial growth efficiency and the functional capacity of the bacterioplankton community to degrade different compounds. Based on the measured dynamics in methane and nutrient pools, we discuss that methane oxidation and nitrification likely occurred in the lake, contributing to the unusually low RQs. Our findings demonstrate that planktonic RQs in productive lakes can systematically be below 1, suggesting that CO2 emissions from these lakes may currently be overestimated.


Assuntos
Organismos Aquáticos/metabolismo , Eutrofização , Plâncton/metabolismo , Plâncton/microbiologia , Respiração Celular/fisiologia , Ecossistema , Lagos/microbiologia , Metano/metabolismo
12.
Sensors (Basel) ; 18(9)2018 Aug 21.
Artigo em Inglês | MEDLINE | ID: mdl-30134629

RESUMO

In this paper, we investigate the use of fat tissue as a communication channel between in-body, implanted devices at R-band frequencies (1.7⁻2.6 GHz). The proposed fat channel is based on an anatomical model of the human body. We propose a novel probe that is optimized to efficiently radiate the R-band frequencies into the fat tissue. We use our probe to evaluate the path loss of the fat channel by studying the channel transmission coefficient over the R-band frequencies. We conduct extensive simulation studies and validate our results by experimentation on phantom and ex-vivo porcine tissue, with good agreement between simulations and experiments. We demonstrate a performance comparison between the fat channel and similar waveguide structures. Our characterization of the fat channel reveals propagation path loss of ∼0.7 dB and ∼1.9 dB per cm for phantom and ex-vivo porcine tissue, respectively. These results demonstrate that fat tissue can be used as a communication channel for high data rate intra-body networks.


Assuntos
Tecido Adiposo , Eletrônica/métodos , Próteses e Implantes , Animais , Corpo Humano , Humanos , Modelos Anatômicos , Imagens de Fantasmas , Suínos
13.
PLoS One ; 13(7): e0199608, 2018.
Artigo em Inglês | MEDLINE | ID: mdl-29979688

RESUMO

Climate change projections show that temperature and precipitation increases can alter the exchange of greenhouse gases between the atmosphere and high latitude landscapes, including their freshwaters. Dissolved organic carbon (DOC) plays an important role in greenhouse gas emissions, but the impact of catchment productivity on DOC release to subarctic waters remains poorly known, especially at regional scales. We test the hypothesis that increased terrestrial productivity, as indicated by the normalized difference vegetation index (NDVI), generates higher stream DOC concentrations in the Stordalen catchment in subarctic Sweden. Furthermore, we aimed to determine the degree to which other generic catchment properties (elevation, slope) explain DOC concentration, and whether or not land cover variables representing the local vegetation type (e.g., mire, forest) need to be included to obtain adequate predictive models for DOC delivered into rivers. We show that the land cover type, especially the proportion of mire, played a dominant role in the catchment's release of DOC, while NDVI, slope, and elevation were supporting predictor variables. The NDVI as a single predictor showed weak and inconsistent relationships to DOC concentrations in recipient waters, yet NDVI was a significant positive regulator of DOC in multiple regression models that included land cover variables. Our study illustrates that vegetation type exerts primary control in DOC regulation in Stordalen, while productivity (NDVI) is of secondary importance. Thus, predictive multiple linear regression models for DOC can be utilized combining these different types of explanatory variables.


Assuntos
Carbono/análise , Sistemas de Informação Geográfica , Compostos Orgânicos/análise , Tecnologia de Sensoriamento Remoto , Rios/química , Mudança Climática , Monitoramento Ambiental , Água Doce/análise , Água Doce/química , Geografia , Modelos Teóricos , Análise Espacial , Suécia
14.
Nat Ecol Evol ; 2(9): 1443-1448, 2018 09.
Artigo em Inglês | MEDLINE | ID: mdl-30013133

RESUMO

Effective societal responses to rapid climate change in the Arctic rely on an accurate representation of region-specific ecosystem properties and processes. However, this is limited by the scarcity and patchy distribution of field measurements. Here, we use a comprehensive, geo-referenced database of primary field measurements in 1,840 published studies across the Arctic to identify statistically significant spatial biases in field sampling and study citation across this globally important region. We find that 31% of all study citations are derived from sites located within 50 km of just two research sites: Toolik Lake in the USA and Abisko in Sweden. Furthermore, relatively colder, more rapidly warming and sparsely vegetated sites are under-sampled and under-recognized in terms of citations, particularly among microbiology-related studies. The poorly sampled and cited areas, mainly in the Canadian high-Arctic archipelago and the Arctic coastline of Russia, constitute a large fraction of the Arctic ice-free land area. Our results suggest that the current pattern of sampling and citation may bias the scientific consensuses that underpin attempts to accurately predict and effectively mitigate climate change in the region. Further work is required to increase both the quality and quantity of sampling, and incorporate existing literature from poorly cited areas to generate a more representative picture of Arctic climate change and its environmental impacts.


Assuntos
Mudança Climática , Regiões Árticas , Ecossistema , Viés de Seleção , Análise Espacial
15.
Glob Chang Biol ; 24(8): 3692-3714, 2018 08.
Artigo em Inglês | MEDLINE | ID: mdl-29543363

RESUMO

Northern ecosystems are experiencing some of the most dramatic impacts of global change on Earth. Rising temperatures, hydrological intensification, changes in atmospheric acid deposition and associated acidification recovery, and changes in vegetative cover are resulting in fundamental changes in terrestrial-aquatic biogeochemical linkages. The effects of global change are readily observed in alterations in the supply of dissolved organic matter (DOM)-the messenger between terrestrial and lake ecosystems-with potentially profound effects on the structure and function of lakes. Northern terrestrial ecosystems contain substantial stores of organic matter and filter or funnel DOM, affecting the timing and magnitude of DOM delivery to surface waters. This terrestrial DOM is processed in streams, rivers, and lakes, ultimately shifting its composition, stoichiometry, and bioavailability. Here, we explore the potential consequences of these global change-driven effects for lake food webs at northern latitudes. Notably, we provide evidence that increased allochthonous DOM supply to lakes is overwhelming increased autochthonous DOM supply that potentially results from earlier ice-out and a longer growing season. Furthermore, we assess the potential implications of this shift for the nutritional quality of autotrophs in terms of their stoichiometry, fatty acid composition, toxin production, and methylmercury concentration, and therefore, contaminant transfer through the food web. We conclude that global change in northern regions leads not only to reduced primary productivity but also to nutritionally poorer lake food webs, with discernible consequences for the trophic web to fish and humans.


Assuntos
Mudança Climática , Cadeia Alimentar , Animais , Peixes , Lagos/química , Rios/química , Estações do Ano
16.
Microb Ecol ; 76(1): 144-155, 2018 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-29255936

RESUMO

Increases in the terrestrial export of dissolved organic carbon (C) to rivers may be associated with additional loading of organic nitrogen (N) and phosphorus (P) to the coastal zone. However, little is known about how these resources interact in the regulation of heterotrophic bacterioplankton metabolism in boreal coastal ecosystems. Here, we measured changes in bacterioplankton production (BP) and respiration (BR) in response to full-factorial (C, N, and P) enrichment experiments at two sites within the Öre estuary, northern Sweden. The BR was stimulated by single C additions and further enhanced by combined additions of C and other nutrients. Single addition of N or P had no effect on BR rates. In contrast, BP was primarily limited by P at the site close to the river mouth and did not respond to C or N additions. However, at the site further away from the near the river mouth, BP was slightly stimulated by single additions of C. Possibly, the natural inflow of riverine bioavailable dissolved organic carbon induced local P limitation of BP near the river mouth, which was then exhausted and resulted in C-limited BP further away from the river mouth. We observed positive interactions between all elements on all responses except for BP at the site close to the river mouth, where P showed an independent effect. In light of predicted increases in terrestrial P and C deliveries, we expect future increases in BP and increases of BR of terrestrially delivered C substrates at the Öre estuary and similar areas.


Assuntos
Bactérias/crescimento & desenvolvimento , Bactérias/metabolismo , Carbono/metabolismo , Estuários , Nutrientes/metabolismo , Água do Mar/microbiologia , Carbono/química , Ecossistema , Monitoramento Ambiental , Água Doce/química , Processos Heterotróficos , Nutrientes/química , Fósforo/metabolismo , Plâncton/crescimento & desenvolvimento , Plâncton/metabolismo , Rios/química , Salinidade , Estações do Ano , Suécia
17.
Sci Rep ; 7: 45811, 2017 04 05.
Artigo em Inglês | MEDLINE | ID: mdl-28378792

RESUMO

Global warming can substantially affect the export of dissolved organic carbon (DOC) from peat-permafrost to aquatic systems. The direct degradability of such peat-derived DOC, however, is poorly constrained because previous permafrost thaw studies have mainly addressed mineral soil catchments or DOC pools that have already been processed in surface waters. We incubated peat cores from a palsa mire to compare an active layer and an experimentally thawed permafrost layer with regard to DOC composition and degradation potentials of pore water DOC. Our results show that DOC from the thawed permafrost layer had high initial degradation potentials compared with DOC from the active layer. In fact, the DOC that showed the highest bio- and photo-degradability, respectively, originated in the thawed permafrost layer. Our study sheds new light on the DOC composition of peat-permafrost directly upon thaw and suggests that past estimates of carbon-dioxide emissions from thawed peat permafrost may be biased as they have overlooked the initial mineralization potential of the exported DOC.

18.
Sci Adv ; 3(3): e1601765, 2017 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-28345035

RESUMO

Widespread evidence that organic matter exported from terrestrial into aquatic ecosystems supports recipient food webs remains controversial. A pressing question is not only whether high terrestrial support is possible but also what the general conditions are under which it arises. We assemble the largest data set, to date, of the isotopic composition (δ2H, δ13C, and δ15N) of lake zooplankton and the resources at the base of their associated food webs. In total, our data set spans 559 observations across 147 lakes from the boreal to subtropics. By predicting terrestrial resource support from within-lake and catchment-level characteristics, we found that half of all consumer observations that is, the median were composed of at least 42% terrestrially derived material. In general, terrestrial support of zooplankton was greatest in lakes with large physical and hydrological connections to catchments that were rich in aboveground and belowground organic matter. However, some consumers responded less strongly to terrestrial resources where within-lake production was elevated. Our study shows that multiple mechanisms drive widespread cross-ecosystem support of aquatic consumers across Northern Hemisphere lakes and suggests that changes in terrestrial landscapes will influence ecosystem processes well beyond their boundaries.


Assuntos
Cadeia Alimentar , Lagos , Modelos Biológicos
19.
Sci Rep ; 7: 45110, 2017 03 23.
Artigo em Inglês | MEDLINE | ID: mdl-28332585

RESUMO

To maximize the matching between a coaxial cable and rectangular waveguides, we present a computational topology optimisation approach that decides for each point in a given domain whether to hold a good conductor or a good dielectric. The conductivity is determined by a gradient-based optimisation method that relies on finite-difference time-domain solutions to the 3D Maxwell's equations. Unlike previously reported results in the literature for this kind of problems, our design algorithm can efficiently handle tens of thousands of design variables that can allow novel conceptual waveguide designs. We demonstrate the effectiveness of the approach by presenting optimised transitions with reflection coefficients lower than -15 dB over more than a 60% bandwidth, both for right-angle and end-launcher configurations. The performance of the proposed transitions is cross-verified with a commercial software, and one design case is validated experimentally.

20.
J Plankton Res ; 37(3): 489-499, 2015 May.
Artigo em Inglês | MEDLINE | ID: mdl-26251558

RESUMO

Research on nutrient controls of planktonic productivity tends to focus on a few standard fractions of inorganic or total nitrogen (N) and phosphorus (P). However, there is a wide range in the degree to which land-derived dissolved organic nutrients can be assimilated by biota. Thus, in systems where such fractions form a majority of the macronutrient resource pool, including many boreal inland waters and estuaries, our understanding of bacterio- and phytoplankton production dynamics remains limited. To adequately predict aquatic productivity in a changing environment, improved standard methods are needed for determining the sizes of active (bioavailable) pools of N, P and organic carbon (C). A synthesis of current knowledge suggests that variation in the C:N:P stoichiometry of bioavailable resources is associated with diverse processes that differentially influence the individual elements across space and time. Due to a generally increasing organic nutrient bioavailability from C to N to P, we hypothesize that the C:N and N:P of bulk resources often vastly overestimates the corresponding ratios of bioavailable resources. It is further proposed that basal planktonic production is regulated by variation in the source, magnitude and timing of terrestrial runoff, through processes that have so far been poorly described.

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