Thermodynamic evaluation of solar assisted ZnO/Zn thermochemical CO2 splitting cycle.

The solar thermochemical CO2 splitting (CDS) is scrutinized via a redox ZnO/Zn cycle. The second law efficiency analysis is carried out by acquiring the required thermodynamic data from HSC Chemistry software. The main focus of this study is to explore the influence of reduction temperature (Tred), molar flow rate of inert sweep gas (n˙inert), and energy required for the gas separation on the solar-to-fuel energy conversion efficiency (ηsolar-to-fuel) of the ZnO/Zn cycle. All the calculations are conducted at a constant gas-to-gas heat recovery effectiveness (εgg) equal to 0.5. n˙inert required is recorded to be too high (5050 mol/s) at Tred equal to 1500 K and moderately low (15 mol/s) for Tred equal to 2000 K. The amount of thermal energy required to heat the inert/O2 gas mixture (from CDS temperature to separator-1 temperature) and inert sweep gas (from separator-1 temperature to reduction temperature) has a significant impact on the total thermal energy requirement of the cycle (Q˙TC). The rise in Tred from 1500 K to 2000 K shows a considerable decline in Q˙TC from 77417.5 kW to 1161.8 kW, respectively. Consequently, the highest ηsolar-to-fuel (17.0%) is recorded for Tred equal to 2000 K.

Bio-sorption of toxic metals from industrial wastewater by algae strains Spirulina platensis and Chlorella vulgaris: Application of isotherm, kinetic models and process optimization.

The present study evaluates the effect of an acidic treatment on the improvement of the percentage removal of toxic metal (%TMrem) from wastewater by algae strains (Spirulina platensis (SP) and Chlorella vulgar (CV)) under different adsorbent dosages (0.2-2.5 g), a pH of (4-8) and contact time (5-100 min). The acidic treatment (Ac-T) altered the functional groups on the surface of algae promoting more electronegative groups and improved the %TMrem of Al, Ni and Cu. Treated SP removed up to 95.0 ± 0.3% (Std. Dev = 0.24), 87.0 ± 0.2% (Std. Dev = 0.34)%, and 63.0 ± 0.3% (Std. Dev = 0.14) of Al, Ni, and Cu at the optimum pH of 5.5, 6.0, and, 7.0 and an adsorbent dosage of = 2.5 ± 0.1 g/L (Std. Dev = 0.14) g/L, respectively. Lower %TMrem of 87.0% ± 0.2 (Std. Dev = 0.09), 79.1 ± 0.4% (Std. Dev = 0.08), and 80.0 ± 0.2% (Std. Dev = 0.04) were achieved with treated CV, respectively. The optimum operational conditions for maximum %TMrem were determined at (Calgae = 4.8 ± 0.2 gMNPs.L-1, Ct = 88 ± 1, and pH = 6) using the response surface methodology (RSM). The adsorption of TMs on algae is endothermic, spontaneous, and follows Langmuir and second-order kinetics. Zeta potential measurements indicated that the adsorption mechanism between the toxic metal (TM) and algal strains is controlled by electrostatic interaction. As such, bio-sorption is a sustainable and efficient technology for the removal of TM from wastewater.

Treatment of waste gas contaminated with dichloromethane using photocatalytic oxidation, biodegradation and their combinations.

The treatment of waste gas (WG) containing dichloromethane (DCM) using advanced oxidation processes (AOPs) [UV and UV-TiO2], biological treatment (BT), and their combination (AOPs-BT) was tested. AOP tests were performed in an annular photo-reactor (APHR), while BT was conducted in a continuous stirred tank bioreactor (CSTBR). The effects of gas flow rate (Qgas), inlet DCM concentration ([DCM]i), residence time (τ), photocatalyst loading (PH-CL) and % relative humidity (% RH) on the AOPs performance and the removal of DCM (%DCMr) were studied and optimized. The UV process exhibited %DCMr ≤ 12.5 % for tests conducted at a [DCM]i ≤ 0.45 g/m3, Qgas of 0.12 m3/h and τ of 27.6 s, respectively, and < 4 % when the [DCM]i ≥ 4.2 g/m3. The UV-TiO2 achieved a %DCMr ≥ 71 ±â€¯1.5 % at Qgas of 0.06 m3/h, [DCM]i of 0.45 g/m3, τ of 55.2 s, PH-CL of 10 g/m2, and %RH of 50, respectively. The BT process removed ∼97.6 % of DCM with an elimination capacity (EC) of 234.0 g/m3·h. Besides, the high %DCMr of ∼98.5 % in the UV-BT and 99.7 % in the UV-TiO2-BT processes confirms AOPs-BT as a promising technology for the treatment of recalcitrant compounds present in WG.

Various potential techniques to reduce the water footprint of microalgal biomass production for biofuel-A review.

Due to their rapid growth rates, high lipid productivity, and ability to synthesize value-added products, microalgae are considered as the potential biofuel feedstocks. However, among the several bottlenecks that are hindering the commercialization of microalgal biofuel synthesis, the issue of high water consumption is the least explored. This analysis, therefore, examines the factors that decide water use for the production of microalgae biofuel. Microalgae biodiesel water footprint varies from 3.5 to 3726 kg of water per kg of biodiesel. The study further investigates the cause for large variability in the estimation of the water footprint for microalgae fuel. Various strategies, including the reuse of harvested water, the use of high density cultivation that could be adopted for low water consumption in microalgal biofuel production are discussed. Specifically, the review identified a reciprocal relationship between biomass productivity and water footprint. On the basis of which the review emphasizes the significance of high density cultivation, which can be inexpensive and feasible relative to other water-saving techniques. With the setback of water scarcity due to the rapid industrialization in developing countries, the implementation of the cultivation system with a focus on minimizing the water consumption is inevitable for a successful large scale microalgal biofuel production.

Enhancing the production of biogas through anaerobic co-digestion of agricultural waste and chemical pre-treatments.

Large amounts of agricultural solid wastes (ASWs) and animal dung are produced annually causing serious environmental problem that requires proper treatment. The present study proposes a strategy for optimizing the anaerobic co-digestion of ASWs and cow dung (CD), identifies the key factors governing the co-digestion performance and evaluates the effect of NaHCO3 alkalinity treatment on improving the economy and performance of anaerobic digestion (AD). The results revealed that the highest cumulative methane production (CMP) of 297.99 NL/kgVS can be generated by co-digestion of ASWs and CD at a ratio of 60:40. Further improvement was achieved via alkalinity treatment with 1.0 g of NaHCO3/gVS leading to decrease in lignin, cellulose, and hemicellulose contents of feedstock by 3.5%, 10.5% and 15.9%, respectively, converting them to soluble fractions and improving the CMP by 11.2-29.7% based on substrate quality. The improved CMP in the chemically treated substrates reflects a 19% increase in the generated revenue. The kinetics of the AD process was successfully fitted to modified Gompertz model with very low standard deviation residuals (SDR) ≤ 5.21 and R2 ≥ 0.979. Results confirm that the proposed strategy is an effective method for producing biogas from co-digestion of ASWs and CD.

Review on sustainable production of biochar through hydrothermal liquefaction: Physico-chemical properties and applications.

This review examines in detail the production and characteristics of biochar resulting from hydrothermal liquefaction. Specifically, the impact of feedstocks and different process parameters on the properties and yield of biochar by hydrothermal liquefaction has been thoroughly studied. Hydrothermal liquefaction derived biochars, relative to biochars from high-temperature thermochemical processes retain critical functional groups during carbonization and are therefore promising for a wide range of applications. Most of the review's efforts are to study possible hydrothermal liquefaction biochar applications in various fields, including fuel, metal and dye adsorption, pollutant reduction, animal feed, and biogas catalyst. The feasibility of biochar through the hydrothermal liquefaction process has been analysed via life-cycle assessment and energy evaluation. The article concludes with a brief discussion on possible issues and strategies for the sustainable development of hydrothermal liquefaction-based biochar.

Cost effective biomethanation via surfactant coupled ultrasonic liquefaction of mixed microalgal biomass harvested from open raceway pond.

The present study aimed to enhance the biomethanation potential of mixed microalgae via cost effective surfactant coupled ultrasonic homogenization (SCUH). Mixed microalgae biomass was harvested using a coagulant (Alum) from a raceway pond. The harvested algal biomass was subjected to ultrasonic homogenization (UH) by varying the power from 100 to 180 W. A maximal soluble organic release of 2131 mg/L was achieved at an ultrasonic input energy (UIE) of 25200 kJ/kg TS. In order to enhance soluble organic release and to reduce energy spent, the optimized condition of ultrasonic pretreatment was coupled with varying sodium dodecyl sulphate (SDS) dosage. A higher solubilization of 30.5% was achieved at a UIE of 4200 kJ/kg SS with surfactant dosage of 0.02 g SDS/g SS for SCUH. SCUH showed higher methane production of 358 mL/g COD when compared to UH (185.9 mL/g COD), SCUH was economically feasible than UH.

Industrial wastewater to biohydrogen: Possibilities towards successful biorefinery route.

The aim of this review is to summarize the modern developments and enhancement strategies reported for improving the biorefinery route of industrial wastewater to biohydrogen. Recent developments towards biohydrogen production chiefly involves culture enrichment, pretreatment of biocatalysts, co culture fermentation, metabolic and genetic engineering, ecobiotechnological approaches and the coupling process of biohydrogen. In addition, an overview of dark fermentation, pathways involved, microbes involved in biohydrogen production, industrial wastewater as substrate have been focused. The utilization of organic residuals of dark fermentation for subsequent value added products are highlighted. More apparently, the two stage coupling process and its possibilities towards biorefinery has been reviewed comprehensively. Moreover, comparative energy and economic aspects of biohydrogen production from industrial wastewater and its prospects towards pilot scale applications are also spotlighted. Though all the enhancement strategies have both benefits and disadvantages, coupling process is considered as the most successful biorefinery route for biohydrogen production.

A review on the conversion of volatile fatty acids to polyhydroxyalkanoates using dark fermentative effluents from hydrogen production.

The production of bio/microbial-based polymers, polyhydroxyalkanoates (PHAs) from volatile fatty acids (VFAs) of dark fermentative effluents in the bio-H2 reactor is being paid attention, owing to their commercial demand, applications and as carbon as well as energy storage source. Since, they are the cheap precursors for such valuable renewable biopolymers which all possess the properties; those are analogous to the petro-derived plastics. Several studies were stated, related to the consumption of both individual and mixed VFAs for the potential PHAs production. Their biodegradability nature makes them extremely desirable alternative to fossil-derived synthetic polymers. In this regard, this review summarizes the use of bio-based PHAs production via both microbial and biochemical pathways using dark fermentative bio-H2 production from waste streams as feedstock. Furthermore, this review deals the characteristics, synthesis and production of the bio-based PHAs along with their co-polymers and applications to give an outlook on future research.

Impact of CO2 concentration and ambient conditions on microalgal growth and nutrient removal from wastewater by a photobioreactor.

The increase in atmospheric CO2 concentration and the release of nutrients from wastewater treatment plants (WWTPs) are environmental issues linked to several impacts on ecosystems. Numerous technologies have been employed to resolves these issues, nonetheless, the cost and sustainability are still a concern. Recently, the use of microalgae appears as a cost-effective and sustainable solution because they can effectively uptake CO2 and nutrients resulting in biomass production that can be processed into valuable products. In this study single (Spirulina platensis (SP.PL) and mixed indigenous microalgae (MIMA) strains were employed, over a 20-month period, for simultaneous removal of CO2 from flue gases and nutrient from wastewater under ambient conditions of solar irradiation and temperature. The study was performed at a pilot scale photo-bioreactor and the effect of feed CO2 gas concentration in the range (2.5-20%) on microalgae growth and biomass production, carbon dioxide bio-fixation rate, and the removal of nutrients and organic matters from wastewater was assessed. The MIMA culture performed significantly better than the monoculture, especially with respect to growth and CO2 bio-fixation, during the mild season; against this, the performance was comparable during the hot season. Optimum performance was observed at 10% CO2 feed gas concentration, though MIMA was more temperature and CO2 concentration sensitive. MIMA also provided greater removal of COD and nutrients (~83% and >99%) than SP.PL under all conditions studied. The high biomass productivities and carbon bio-fixation rates (0.796-0.950 gdw·L-1·d-1 and 0.542-1.075 gC·L-1·d-1 contribute to the economic sustainability of microalgae as CO2 removal process. Consideration of operational energy revealed that there is a significant energy benefit from cooling to sustain the highest productivities on the basis of operating energy alone, particularly if the indigenous culture is used.