Stress Relaxation Behaviour Modeling in Rigid Polyurethane (PU) Elastomeric Materials.

Polyurethane (PU) has been used in a variety of industries during the past few years due to its exceptional qualities, including strong mechanical strength, good abrasion resistance, toughness, low-temperature flexibility, etc. More specifically, PU is easily "tailored" to satisfy particular requirements. There is a lot of potential for its use in broader applications due to this structure-property link. Ordinary polyurethane items cannot satisfy people's increased demands for comfort, quality, and novelty as living standards rise. The development of functional polyurethane has recently received tremendous commercial and academic attention as a result. In this study, the rheological behavior of a polyurethane elastomer of the PUR (rigid polyurethane) type was examined. The study's specific goal was to examine stress relaxation for various bands of specified strains. We also suggested the use of a modified Kelvin-Voigt model to describe the stress relaxation process from the perspective of the author. For the purpose of verification, materials with two different Shore hardness ratings-80 and 90 ShA, respectively-were chosen. The outcomes made it possible to positively validate the suggested description in a variety of deformations ranging from 50% to 100%.

Constitutive Law Identification and Fatigue Characterization of Rigid PUR Elastomers 80 ShA and 90 ShA.

This paper presents the results of a study of polyurethane rigid (PUR) elastomers in terms of the constitutive law identification, and analyses the effect of polyurethane elastomers' hardness on fatigue properties. The research objects were PUR materials based on 4,4'-diphenylmethane diisocyanate (MDI) with the hardness of 80 ShA and 90 ShA, typically used in various industrial applications. Based on the performed experimental campaign under static and cyclic loading, the constitutive model proposed by Ogden is most appropriate. In addition, a hybrid numerical-experimental analysis (using FEM-DIC) of diabolo specimens' behaviour is carried out in fatigue tests. Based on the performed fatigue test, it is worth noting that the energy approach describes the fatigue process synonymously compared to the displacement or strain approach. Finally, simple fatigue characteristics were analyzed and statistically validated for both PUR material configurations.

The Effect of Flame Retardant-Aluminum Trihydroxide on Mixed Mode I/II Fracture Toughness of Epoxy Resin.

Fire resistance is a major issue concerning composite materials for safe operation in many industrial sectors. The design process needs to meet safety requirements for buildings and vehicles, where the use of composites has increased. There are several solutions to increasing the flame resistance of polymeric materials, based on either chemical modification or physical additions to the material's composition. Generally, the used flame retardants affect mechanical properties either in a positive or negative way. The presented research shows the influence of the mixed-mode behavior of epoxy resin. Fracture toughness tests on epoxy resin samples were carried out, to investigate the changes resulting from different inorganic filler contents of aluminum trihydroxide (ATH). Three-point bending and asymmetric four-point bending tests, with different loading modes, were performed, to check the fracture behavior in a complex state of loading. The results showed that the fracture toughness of mode I and mode II was reduced by over 50%, compared to neat resin. The experimental outcomes were compared with theoretical predictions, demonstrating that the crack initiation angle for higher values of KI/KII factor had a reasonable correlation with the MTS prediction. On the other hand, for small values of the factor KI/KII, the results of the crack initiation angle had significant divergences. Additionally, based on scanning electron microscopy images, the fracturing of the samples was presented.

Rheological Relaxation of OSB Beams Reinforced with CFRP Composites.

An experimental and analytical approach to the relaxation problem of wood-based materials-OSB (Oriented Strand Boards-pressed wood-based composite panels) beams, including beams with CFRP (Carbon fiber reinforced polymer) tape composite reinforcement, is presented. It is a relevant engineering and scientific problem due to the fact that wood and wood-based materials, as well as composite reinforcements, are widely used in building constructions. Their rheological properties are very important and complicated to estimate. A 10 day long relaxation test of thick OSB beams without reinforcement and with CFRP tape was performed. A four-point bending test with five different bending levels was performed, during which the reduction of the loading force was measured. A five-parameter rheological model was used to describe the rheology of the beams. The equations of this model were calculated with the use of Laplace transform, whereas the values of the parameters were calculated based on the experimental relaxation curves. A high correlation between experimental and theoretical results was obtained. A beam reinforced with CFRP tape was treated as a system with a viscoelastic element (OSB) and an elastic element (CFRP), joined together without the possibility of slipping. The equations of the mathematical model were calculated based on the assumptions of the linear theory of viscoelasticity and the convolution integral. A good correlation between experimental and theoretical results was obtained. A significant redistribution of stresses was observed during the relaxation of the reinforced beam. The reinforced beams show a higher stiffness of approximately 63% and carry proportionally higher loads than unreinforced beams at the same deflection values.

Microwave Non-Destructive Testing for Delamination Detection in Layered Composite Pipelines.

Microwave imaging and defectoscopy are promising techniques for dielectric composite evaluation. Their most significant advantage is their relatively high penetration depth. Another feature worth noting is that traditional methods could not acquire an internal content with such a low impact on both the sample and surrounding environment, including the test operator, compared to other techniques. This paper presents microwave non-destructive and noninvasive methods for quality evaluation of layered composite materials using an open-ended waveguide probe. Pure |S11| parameters only exceptionally give a clear answer about the location of material cracks. Therefore, this makes it necessary to analyze these parameters simultaneously along with several other factors, such as stand-off distance, probe type or wave polarization. The purpose of the work was to find the dependency between the physical state of a layered composite powerplant pipeline and the S-matrix parameters response (reflection and transmission parameters) in a Ku frequency band that has not yet been extensively researched. Lower-frequency measurements broaden the application possibility for thicker composites, mainly because of a higher penetration depth and measurement setup availability. Different methods have been shown, including reflection and transmission/reflection methods, both in close proximity and in stand-off distance. The measurements are based on a low-complexity experimental setup.

The Mechanical Investigation of Filament-Wound CFRP Structures Subjected to Different Cooling Rates in Terms of Compressive Loading and Residual Stresses-An Experimental Approach.

Although cooling at ambient temperature is widely used and is said to be safe and convenient, faster cooling may have an influence not only on the time of the manufacturing process but also on the mechanical response, especially the residual stress. The study aimed to investigate the influence of the cooling rate after curing on the mechanical response of filament-wound thick-walled carbon fiber reinforced polymer (CFRP) rings. Three cooling rates were taking into consideration: cooling with the oven, at room temperature, and in the water at 20 °C. The splitting method was used to examine the residual strains. In the radial compression test, the mechanical response was investigated between the rings with different cooling regimes. The FEM analysis of the compression test in elastic range was also performed. Both the splitting method and the radial compression test showed no significant difference in the mechanical response of the CFRP rings. The presented results showed that the fast-cooling rate slightly decreases the mechanical performance of the filament-wound rings.