Widespread Pb contamination in urban backyard soils for >100 years identified in soil cores constrained by 210Pb and 137Cs.

Contaminated soil in urban residential areas is often overlooked as a source of childhood exposure to toxic levels of lead (Pb). We document mean Pb concentrations of 1200 ± 1000 mg/kg, three times the now outdated EPA soil hazard standard of 400 mg/kg, for 370 surface soils collected from 76 homes in the boroughs of Brooklyn and Manhattan of New York City. The mean Pb content of 250 ± 290 mg/kg Pb for 571 surface soils collected from tree pits and public parks was much lower. A subset of 22 surface samples analyzed by EPA Method 1340 extracted 86 ± 21 % (±1SD) of total soil Pb, indicating that it the Pb was highly bioavailable. To investigate the origin of backyard contamination, 49 cores were collected to an average depth of 30 cm from a subset of 27 homes. Twelve soil cores were analyzed for 210Pb and 137Cs to constrain processes that impact contaminant distribution and inventories (particle focusing, soil accumulation, loss, and mixing). Concentrations of Pb declined with depth in 60 % of the cores but usually did not reach background. Mean uncorrected Pb inventories of 340 ± 210 g/m2 Pb (mean ± 1SD, n = 12) were more than five times higher than the radionuclide corrected inventory of 57 g/m2 from Central Park soil cores. Average inventories of 210Pbxs (3.5 ± 0.9 kBq/m2) and 137Cs (0.9 ± 0.6 kBq/m2) corresponded to 71 ± 19 % and 50 ± 30 % of the predicted atmospheric inventories. Elevated Pb concentrations were found both in the fine (<1 mm) and coarse (>1 mm) fractions, the latter suggesting a local non-atmospheric source. This was confirmed by individual grains containing up to 6 % Pb and visible pieces of coal, bricks, and ash. Regardless of the source of contamination in backyard soils, systematic testing is needed to identify contaminated areas and reduce child exposure.

Provenance of Anthropogenic Pb and Atmospheric Dust to Northwestern North America.

Industrial activities release aerosols containing toxic metals into the atmosphere, where they are transported far from their sources, impacting ecosystems and human health. Concomitantly, long-range-transported mineral dust aerosols play a role in Earth's radiative balance and supply micronutrients to iron-limited ecosystems. To evaluate the sources of dust and pollutant aerosols to Alaska following the 2001 phase-out of leaded gasoline in China, we measured Pb-Sr-Nd isotopic compositions of particles collected in 2016 from snow pits across an elevational transect (2180-5240 m-a.s.l) in Denali National Park, USA. We also determined Pb flux and enrichment from 1991-2011 in the Denali ice core (3870 m-a.s.l). Chinese coal-burning and non-ferrous metal smelting account for up to 64% of Pb deposition at our sites, a value consistent across the western Arctic. Pb isotope ratios in the aerosols did not change between 2001 and 2016, despite the ban on lead additives. Emissions estimates demonstrate that industrial activities have more than compensated for the phase-out of leaded gasoline, with China emitting ∼37,000 metric tons year-1 of Pb during 2013-2015, approximately 78% of the Pb from East Asia. The Pb flux to Alaska now equals that measured in southern Greenland during peak pollution from North America.

Evidence for a Northern Hemispheric trigger of the 100,000-y glacial cyclicity.

The causes of the Mid-Pleistocene Transition, the shift from ∼41-ky to 100-ky interglacial-glacial cycles and more intense ice ages, remain intensely debated, as this fundamental change occurred between ∼1,250 and 650 ka without substantial changes in astronomical climate forcings. Recent studies disagree about the relative importance of events and processes in the Northern and Southern Hemispheres, as well as whether the shift occurred gradually over several interglacial-glacial cycles or abruptly at ∼900 ka. We address these issues using a north-to-south reconstruction of the Atlantic arm of the global meridional overturning ocean circulation, a primary means for distributing heat around the globe, using neodymium (Nd) isotopes. Results reveal a period of intense erosion affecting the cratonic shields surrounding the North Atlantic between Marine Isotope Stages (MIS) 27 and 25 (∼980 and 950 ka), reflected by unusually low Nd isotope ratios in deep North Atlantic seawater. This episode preceded a major ocean circulation weakening between MIS 25 and 21 (950 and 860 ka) that coincided with the first ∼100-ky-long interglacial-glacial onset of Northern Hemisphere glaciation at around 2.4 to 2.8 Ma. The data point to a Northern Hemisphere-sourced initiation for the transition, possibly induced through regolith loss and increased exposure of the crystalline bedrock, which would lead to increased friction, enabling larger ice sheets that are characteristic of the 100-ky interglacial-glacial cycles.

Geochemistry and magmatc evolution of explosive tephras et3 and et4 from Arenal Volcano, Costa Rica

An outcrop at El Cruce, 5.7 km from the vent of Arenal volcano, exposes thick sequences of two recent tephras, ET4 (silicic) and, immediately above, ET3 (mafic). The ET4 to ET3 transition is abrupt, with no soil between the layers. Therefore, they appear to be part of one eruptive phase. A petrological model is inferred from the detailed stratigraphic record of these eruptions. The ET4 sequence can be modeled by crystal fractionation via gravity settling. ET4 is most mafic at the top of the section. The silicic tephra at the bottom of this unit is aphyric. Compatible elements increase and incompatible elements decrease moving down through the magma chamber. The percentage of phenocrysts increases through the top. Models of crystal fractionation, using the most mafic and phenocryst enriched tephra as the parent magma, produce the most silicic tephra by removal of 37

phenocrysts. The ET3 sequence shows the opposite trend of that seen in the ET4 sequence, becoming less enriched in incompatible elements down through the section. Some crystal sorting, followed by the removal of a silicic melt from the top of the magma chamber, could generate the reversed trend for the ET3 sequence.(AU)