RESUMO
The aging phenomenon is commonly observed in quantum-dot light emitting diodes (QLEDs), involving complex chemical or physical processes. Resolving the underlying mechanism of these aging issues is crucial to deliver reliable electroluminescent devices in future display applications. Here, we report a reversible positive aging phenomenon that the device brightness and efficiency significantly improve after device operation, but recover to initial states after long-time storage or mild heat treatment, which can be termed as warming-up effects. Steady and transient equivalent circuit analysis suggest that the radiative recombination current dramatically increases but electron leakage from the quantum dots (QDs) to hole transport layer becomes more accessible during the warming-up process. Further analysis discloses that the notable enhancement of device efficiency can be ascribed to the filling of shell traps in gradient alloyed QDs. This work reveals a distinct positive aging phenomenon featured with reversibility, and further guidelines would be provided to achieve stable QLED devices in real display applications.
RESUMO
In this work, we report the quantitative determination of charge accumulation and recombination in an operated QLED using time-resolved electroluminescence (TREL) spectroscopy. As a supplement technique, time-resolved current (TRC) measurement was introduced and simulated using equivalent circuit model with a series resistance, a parallel resistance, and a capacitance. By modeling the key processes in a typical TREL spectra, the stages of delay, rising, and decay can be correlated to the charge accumulations, charge injection and recombination, and charge release and recombination, respectively. In particular, the rising stage can be described using a modified Langevin recombination model. The electroluminescence recombination rate can be derived by fitting the rising stage curves in the TREL spectra, providing an intrinsic parameter of the emissive materials. In all, this work provides a methodology to quantitatively determine the charge accumulation and recombination of an operational QLED device.
RESUMO
This paper proposes an electrostatic-piezoelectric-electromagnetic hybrid vibrational power generator with different frequency broadening schemes. Both the nonlinear frequency broadening mechanisms and the synergized effect of the electrostatic-piezoelectric-electromagnetic hybrid structures are investigated. The structure and performance of the composite generator are optimized to improve the response bandwidth and performance. We propose that the electrostatic power generation module and the electromagnetic power generation module be introduced into the cantilever beam to make the multifunctional cantilever beam, realizing small integrated output loss, high output voltage, and high current characteristics. When the external load of the electrostatic power generation module is 10 kΩ, its peak power can reach 3.6 mW; when the external load of the piezoelectric power generation module is 2 kΩ, its peak power is 2.2 mW; and when the external load of the electromagnetic power generation module is 170 Ω, its peak power is 0.735 mW. This means that under the same space utilization, the performance is improved by 90%. Moreover, an energy management circuit (ECM) at the rear end of the device is added, through the energy conditioning circuit, the device can directly export a 3.3 V DC voltage to supply power to most of the sensing equipment. In this paper, the hybrid generator's structure and performance are optimized, and the response bandwidth and performance are improved. In general, the primary advantages of the device in this paper are its larger bandwidth and enhanced performance.
