1.
IUCrdata
; 6(Pt 11): x211142, 2021 Nov.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36337466
RESUMO
A new triazole-based N-heterocyclic cationic carbene iridium(I) complex with a tetra-fluorido-borate counter-anion, [Ir(C8H12)(C7H13N3)(C18H15P)]BF4, has been synthesized and structurally characterized. The IrI atom of the cationic complex has an expected square-planar coordination environment with unexceptional bond lengths. There are several close Fâ¯H contacts between the cations and the anions in the range 2.36-2.58â Å, stabilizing the orientation of the out-sphere [BF4 -] counter-anion. In the crystal, C-Hâ¯π(ring) inter-actions are observed that orient the phenyl rings of the tri-phenyl-phosphane ligands.