Industrial waste-based adsorbents as a new trend for removal of water-borne emerging contaminants.

Emerging contaminants in wastewater are one of the growing concerns because of their adverse effects on human health and ecosystems. Adsorption technology offers superior performance due to its cost-effectiveness, stability, recyclability, and reliability in maintaining environmental and health standards for toxic pollutants. Despite extensive research on the use of traditional adsorbents to remove emerging contaminants, their expensiveness, lack of selectivity, and complexity of regeneration remain some of the challenges. Industrial wastes viz. blast furnace slag, red mud, and copper slag can be used to develop efficacious adsorbents for the treatment of emerging contaminants in water. Advantages of the use of such industrial wastes include resource utilization, availability, cost-effectiveness, and waste management. Nevertheless, little is known so far about their application, removal efficacy, adsorption mechanisms, and limitations in the treatment of emerging contaminants. A holistic understanding of the application of such unique industrial waste-derived adsorbents in removing emerging contaminants from water is need of the hour to transform this technology from bench-scale to pilot and large-scale applications. This review investigates different water treatment techniques associated with industrial waste-based adsorbents derived from blast furnace slag, red mud, and copper slag. Besides, this review provides important insights into the growing trends of utilizing such novel types of adsorbents to remove emerging contaminants from water with an emphasis on removal efficacy, controlling measures, adsorption mechanisms, advantages, and limitations. The present timely review brings the current state of knowledge into a single reference which could be a strong platform for future research in understanding the latest advancements, decision making, and financial management related to the treatment of wastewater using industrial waste-based adsorbents.

Biowaste-derived Ni/NiO decorated-2D biochar for adsorption of methyl orange.

Eco-friendly carbothermal techniques were used to synthesize nanocomposites of biowaste-derived Ni/NiO decorated-2D biochar. The use of chitosan and NiCl2 in the carbothermal reduction technique was a novelty to synthesize the Ni/NiO decorated-2D biochar composite. Potassium persulfate (PS) was found to be activated by Ni/NiO decorated-2D biochar, which is thought to oxidize organic pollutants through an electron pathway designed by the reactive complexes formed between PS and the Ni/NiO biochar surface. This activation led to the efficient oxidation of methyl orange and organic pollutants. Analyzing Ni/NiO decorated-2D biochar composite before and after the methyl orange adsorption and degradation procedure allowed us to report on the process of its elimination. The Ni/NiO biochar with PS activation showed higher efficiency than Ni/NiO decorated-2D biochar composite as this material was able to degrade over 99% of the methyl orange dye. The effects of initial methyl orange concentration, dosages effect, solution pH, equilibrium studies, kinetics, thermodynamic studies, and reusability were examined and evaluated on Ni/NiO biochar.