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With advancements in research and the necessity of improving the performance of bioelectrochemical system (BES), coupling anaerobic digestion (AD) with BES is crucial for energy gain from wastewater and bioremediation. Hybridization of BES-AD concept opens new avenues for pollutant degradation, carbon capture and nutrient-resource recovery from wastewater. The strength of merging BES-AD lies in synergy, and this approach was employed to differentiate fads from strategies with the potential for full-scale implementation and making it an energy-positive system. The integration of BES and AD system increases the overall performance and complexity of combined system and the cost of operation. From a technical standpoint, the primary determinants of BES-AD feasibility for field applications are the scalability and economic viability. High potential market for such integrated system attract industrial partners for more industrial trials and investment before commercialization. However, BES-AD with high energy efficacy and negative economics demands performance boost.
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Ácidos Alcanossulfônicos , Fontes de Energia Bioelétrica , Purificação da Água , Águas Residuárias , Anaerobiose , Fenômenos FísicosRESUMO
The rapid global economic growth driven by industrialization and population expansion has resulted in significant issues, including reliance on fossil fuels, energy scarcity, water crises, and environmental emissions. To address these issues, bioelectrochemical systems (BES) have emerged as a dual-purpose solution, harnessing electrochemical processes and the capabilities of electrochemically active microorganisms (EAM) to simultaneously recover energy and treat wastewater. This review examines critical performance factors in BES, including inoculum selection, pretreatment methods, electrodes, and operational conditions. Further, authors explore innovative approaches to suppress methanogens and simultaneously enhance the EAM in mixed cultures. Additionally, advanced techniques for detecting EAM are discussed. The rapid detection of EAM facilitates the selection of suitable inoculum sources and optimization of enrichment strategies in BESs. This optimization is essential for facilitating the successful scaling up of BES applications, contributing substantially to the realization of clean energy and sustainable wastewater treatment. This analysis introduces a novel viewpoint by amalgamating contemporary research on the selective enrichment of EAM in mixed cultures. It encompasses identification and detection techniques, along with methodologies tailored for the selective enrichment of EAM, geared explicitly toward upscaling applications in BES.
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Ácidos Alcanossulfônicos , Fontes de Energia Bioelétrica , Transporte de Elétrons , EletrodosRESUMO
Ion exchange membranes, especially cation exchange membranes (CEMs), are an important component in membrane-based energy generation and storage because of their ability to transport cations via the electrochemical potential gradient while preventing electron transport. However, developing a CEM with low areal resistance, high permselectivity, and stability remains difficult. In this study, electrospun graphene oxide/polyethersulfone (GO/PES) composite nanofibers were prepared with varying concentrations of GO. To fabricate a CEM, the pores of the electrospun GO/PES nanofiber substrates were filled with a Nafion ionomer. The pore-filled PES nanofiber loaded with 1% GO revealed a noticeable improvement in hydrophilicity, structural morphology, and mechanical properties. The 1% GO/PES pore-filled CEM was compared to a Nafion membrane of a varying thickness and without a nanofiber substrate. The CEM with a nanofiber substrate showed permselectivity of 85.75%, toughness of 111 J/m3, and areal resistance of 3.7 Ω cm2, which were 12.8%, 4.3 times, and 4.0 times better, respectively, than those of the Nafion membrane at the same thickness. The development of a reinforced concrete-like GO/PES nanofiber structure containing stretchable ionomer-enhanced membrane surfaces exhibited suitable areal resistance and reduced the thickness of the composite membrane without compromising the mechanical strength, suggesting its potential application as a cation exchange membrane in electrochemical membrane-based systems.
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A direct contact bioassay of thiosulfate utilizing denitrifying bacteria (TUDB) based on inhibition of gas production was deployed to assess the toxicity of naturally contaminated field soils and soils artificially contaminated with heavy metals. Test procedure producing optimal conditions responsible for maximum gas production was 0.5 mL test culture, 1 g soil sample, 80 RPM, and 48 h reaction time. Similarly, the concentrations which generated a 50% reduction in gas production by TUDB for the tested heavy metals were 3.01 mg/kg Cr6+; 15.30 mg/kg Ni2+;15.50 mg/kg Cu2+;16.60 mg/kg Ag+; 20.60 mg/kg As3+; 32.80 mg/kg Hg2+; 54.70 mg/kg Cd2+; and 74.0 mg/kg Pb2+. Because soil toxicity is usually influenced by various physicochemical characteristics, ten reference soils were used to determine the toxicity threshold for evaluating the toxicity of naturally contaminated field soils. All eight contaminated soils were toxic to the TUDB bioassay because their levels of inhibition ranged between 72% and 100% and exceeded the determined toxicity threshold of 10%. Compared to other direct contact assays, the newly developed assay TUDB proved to be very robust, producing highly sensitive data while the different soil physicochemical properties exerted minimal influence on the gas production activity of TUDB. Additionally, the simplicity of the developed methodology coupled with the elimination of pretreatment procedures such as elutriation, and ability to perform generate sensitive data in turbid and highly colored samples makes it, cost-effective, and easily adaptable for the assessment of heavy metal and field contaminated soils when compared with other conventional assays which require sophisticated instrumentation and prolonged testing procedures and times.
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Metais Pesados , Poluentes do Solo , Tiossulfatos , Metais Pesados/química , Poluição Ambiental , Solo/química , Bactérias , Poluentes do Solo/toxicidade , Poluentes do Solo/análise , Monitoramento Ambiental/métodosRESUMO
Nanomaterials have gained huge attention with their wide range of applications. This is mainly driven by their unique properties. Nanomaterials include nanoparticles, nanotubes, nanofibers, and many other nanoscale structures have been widely assessed for improving the performance in different applications. However, with the wide implementation and utilization of nanomaterials, another challenge is being present when these materials end up in the environment, i.e. air, water, and soil. Environmental remediation of nanomaterials has recently gained attention and is concerned with removing nanomaterials from the environment. Membrane filtration processes have been widely considered a very efficient tool for the environmental remediation of different pollutants. Membranes with their different operating principles from size exclusions as in microfiltration, to ionic exclusion as in reverse osmosis, provide an effective tool for the removal of different types of nanomaterials. This work comprehends, summarizes, and critically discusses the different approaches for the environmental remediation of engineered nanomaterials using membrane filtration processes. Microfiltration (MF), ultrafiltration (UF), and nanofiltration (NF) have been shown to effectively remove nanomaterials from the air and aqueous environments. In MF, the adsorption of nanomaterials to membrane material was found to be the main removal mechanism. While in UF and NF, the main mechanism was size exclusion. Membrane fouling, hence requiring proper cleaning or replacement was found to be the major challenge for UF and NF processes. While limited adsorption capacity of nanomaterial along with desorption was found to be the main challenges for MF.
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The rapid growth in the consumption of fossil fuels resulted in climate change and severe health issues. Among the different proposed methods to control climate change, carbon capture technologies are the best choice in the current stage. In this study, the various membrane technologies used for carbon capture and their impact on achieving sustainable development goals (SDGs) are discussed. Membrane-based carbon capture processes in pre-combustion and post-combustion, which are known as membrane gas separation (MGS) and membrane contactor (MC), respectively, along with the process of fabrication and the different limitations that hinder their performances are discussed. Additionally, the 17 SDGs, where each representing a crucial topic in the current global task of a sustainable future, that are impacted by membrane-based carbon capture technologies are discussed. Membrane-based carbon capture technologies showed to have mixed impacts on different SDGs, varying in intensity and usefulness. It was found that the membrane-based carbon capture technologies had mostly influenced SDG 7 by enhancement in the zero-emission production, SDG 9 by providing 38-42% cost savings compared to liquid absorption, SDG 3 through reducing pollution and particulate matter emissions by 23%, and SDG 13, with SDG 13 being the most positively influenced by membrane-based carbon capture technologies, as they significantly reduce the CO2 emissions and have high CO2 capture yields (80-90%), thus supporting the objectives of SDG 13 in combatting climate change.
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Carbono , Desenvolvimento Sustentável , Dióxido de Carbono/análise , Saúde Global , Combustíveis FósseisRESUMO
Membrane-based technologies are recently being considered as effective methods for conventional water and wastewater remediation processes to achieve the increasing demands for clean water and minimize the negative environmental effects. Although there are numerous merits of such technologies, some major challenges like high capital and operating costs . This study first focuses on reporting the current membrane-based technologies, i.e., nanofiltration, ultrafiltration, microfiltration, and forward- and reverse-osmosis membranes. The second part of this study deeply discusses the contributions of membrane-based technologies in achieving the sustainable development goals (SDGs) stated by the United Nations (UNs) in 2015 followed by their role in the circular economy. In brief, the membrane based processes directly impact 15 out of 17 SDGs which are SDG1, 2, 3, 5, 6, 7, 8, 9, 11, 12, 13, 14, 15, 16 and 17. However, the merits, challenges, efficiencies, operating conditions, and applications are considered as the basis for evaluating such technologies in sustainable development, circular economy, and future development.
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Desenvolvimento Sustentável , Purificação da Água , Água , Osmose , Ultrafiltração , Purificação da Água/métodosRESUMO
Lignocellulosic and algal biomasses are known to be vital feedstocks to establish a green hydrogen supply chain toward achieving a carbon-neutral society. However, one of the most pressing issues to be addressed is the low digestibility of these biomasses in biorefinery processes, such as dark fermentation, to produce green hydrogen. To date, various pretreatment approaches, such as physical, chemical, and biological methods, have been examined to enhance feedstock digestibility. However, neither systematic reviews of pretreatment to promote biohydrogen production in dark fermentation nor economic feasibility analyses have been conducted. Thus, this study offers a comprehensive review of current biomass pretreatment methods to promote biohydrogen production in dark fermentation. In addition, this review has provided comparative analyses of the technological and economic feasibility of existing pretreatment techniques and discussed the prospects of the pretreatments from the standpoint of carbon neutrality and circular economy.
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Hidrogênio , Lignina , Biomassa , Fermentação , Plantas , BiocombustíveisRESUMO
Bioelectrochemical hydrogen production via microbial electrolysis cells (MECs) has attracted attention as the next generation of technology for the hydrogen economy. MECs work by electrochemically active bacteria reducing organic compounds at the anode. However, the hydrophobic nature of carbon-based anodes suppresses the release of the produced gas and water penetration, which significantly reduces the possibility of microbial attachment. Consequently, a limited surface area of the anode is used, which decreases hydrogen production efficiency. In this study, the bifunctional material poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) was applied to the surface of a three-dimensional carbon felt anode to enhance the hydrogen production efficiency of an MEC owing to the high conductivity of PEDOT and super-hydrophilicity of PSS. In experiments, the PEDOT:PSS-modified anode almost doubled the hydrogen production efficiency of the MEC compared with the control anode owing to the increased capacitance current (239.3 %) and biofilm formation (220.7 %). The modified anode reduced the time required for the MEC to reach a steady state of hydrogen production by 14 days compared to the control anode. Microbial community profiles demonstrated that the modified anode had a greater abundance of electrochemically active bacteria than the control anode. This simple method could be widely applied to various bioelectrochemical systems (e.g., microbial fuel cells and solar cells) and to scaling up MECs.
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Fontes de Energia Bioelétrica , Eletrólise , Eletrodos , Hidrogênio/química , Bactérias , Interações Hidrofóbicas e HidrofílicasRESUMO
Electrochemists and ecological engineers find environmental bioelectrochemistry appealing; however, there is a big gap between expectations and actual progress in bioelectrochemical system (BES). Implementing such technology opens new opportunities for novel electrochemical reactions for resource recovery and effective wastewater treatment. Loopholes of BES exist in its scaling-up applications, and numerous attempts toward practical applications (200, 1000, and 1500 L) are key successive indicators toward its commercialization. This review emphasized the critical rethinking of standardization of performance indices i.e. current generation (A/m2), net energy recovery (kWh/kg·COD), product/resource yield (mM), and economic feasibility ($/kWh) to make fair comparison with the existing treatment system. Therefore, directional perspectives, including modularity, energy-cost balance, energy and resource recovery, have been proposed for the sustainable market of BES. The current state of the art and up-gradation in resource recovery and contaminant removal warrants a systematic rethinking of functional worth and niches of BES for practical applications.
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Fontes de Energia Bioelétrica , Purificação da Água , Ácidos Alcanossulfônicos , Eletroquímica , Eletrodos , Águas ResiduáriasRESUMO
Laminar graphene oxide (GO) membranes have demonstrated great potential as next-generation water-treatment membranes because of their outstanding performance and physicochemical properties. However, solute rejection and stability deterioration in aqueous solutions, which are caused by enlarged nanochannels due to hydration and swelling, are regarded as serious issues in the use of GO membranes. In this study, we attempt to use the crosslinking of divalent cations to improve resistance against swelling in partially reduced GO membranes. The partially reduced GO membranes intercalated by divalent cations (i.e., Mg2+) exhibited improved dye-rejection efficiencies of up to 98.40%, 98.88%, and 86.41% for methyl orange, methylene blue, and rhodamine B, respectively. In addition, it was confirmed that divalent cation crosslinking and partial reduction could strengthen mechanical stability during testing under harsh aqueous conditions (i.e., strong sonication).
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Microbial electrolysis cells (MECs) have attracted significant interest as sustainable green hydrogen production devices because they utilize the environmentally friendly biocatalytic oxidation of organic wastes and electrochemical proton reduction with the support of relatively lower external power compared to that used by water electrolysis. However, the commercialization of MEC technology has stagnated owing to several critical technological challenges. Recently, many attempts have been made to utilize nanomaterials in MECs owing to the unique physicochemical properties of nanomaterials originating from their extremely small size (at least <100 nm in one dimension). The extraordinary properties of nanomaterials have provided great clues to overcome the technological hurdles in MECs. Nanomaterials are believed to play a crucial role in the commercialization of MECs. Thus, understanding the technological challenges of MECs, the characteristics of nanomaterials, and the employment of nanomaterials in MECs could be helpful in realizing commercial MEC technologies. Herein, the critical challenges that need to be addressed for MECs are highlighted, and then previous studies that used nanomaterials to overcome the technological difficulties of MECs are reviewed.
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During wastewater treatment, microbial electrochemical technologies (METs) are a promising means for in situ energy harvesting and resource recovery. The primary constraint for such systems is scaling them up from the laboratory to practical applications. Currently, most research (â¼90%) has been limited to benchtop models because of bioelectrochemical, economic, and engineering design limitations. Field trials, i.e., 1.5 m3 bioelectric toilet, 1000 L microbial electrolysis cell and industrial applications of METs have been conducted, and their results serve as positive indicators of their readiness for practical applications. Multiple startup companies have invested in the pilot-scale demonstrations of METs for industrial effluent treatment. Recently, advances in membrane/electrode modification, understanding of microbe-electrode interaction, and feasibility of electrochemical redox reactions have provided new directions for realizing the practical application. This study reviews the scaling-up challenges, success stories for onsite use, and readiness level of METs for commercialization that is inexpensive and sustainable.
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Fontes de Energia Bioelétrica , Purificação da Água , Eletrodos , Eletrólise , TecnologiaRESUMO
Transition metal selenides (TMS) have excellent research prospects and significant attention in supercapacitors (SCs) owing to their high electrical conductivity, superior electrochemical activity and excellent structural stability. However, the commercial utilization of TMS remains challenge due to their elaborate synthesis. Present study designed a hierarchical cobalt selenide (CoSe2) nanowire array on Ni-foam to serve as a positive electrode for asymmetric SCs (ASCs). The nanowires-like morphology of CoSe2 was highly advantageous for SCs, as it offered enhanced electrical conductivity, plenty of surface sites, and short ion diffusion. The as-obtained, CoSe2 nanowire electrode demonstrated outstanding electrochemical features, with an areal capacity of 1.08 mAh cm-2 at 3 mA cm-2, high-rate performance (69.5 % at 50 mA cm-2), as well as outstanding stability after 10,000 cycles. The iron titanium nitride@nitrogen-doped graphene (Fe-TiN@NG) was prepared as a negative electrode to construct the ASCs cell. The obtained ASCs cell illustrated an energy density of 91.8 W h kg-1 at a power density of 281.4 W kg-1 and capacity retention of 94.6% over 10,000 cycles. The overall results provide a more efficient strategy to develop redox-ambitious active materials with a high capacity for advanced energy-storage systems.
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The management and disposal of excess sludge are emerging issues owing to the high costs associated with treatment. In this study, the viability of a modified bentonite was investigated as a conditioning agent for the stabilisation of heavy metals (i.e., Cu, Zn, Cr, Pb, and Cd) and the retention of nutrient species (i.e., total nitrogen (TN), total phosphorus (TP), available nitrogen (available N), and Olsen-phosphorus (Olsen-P)) in sewage sludge for agricultural use. Five grams of modified bentonite resulted in the highest stabilisation rate of heavy metals and strongly contributed to the stabilisation of heavy metals. However, increased amounts of modified bentonite might increase the TN, available N, and TP losses in the conditioned sewage sludge. Through the analytic hierarchy process modelling, optimal concentrations of nutrient species and heavy metals remaining in the conditioned sewage sludge were achieved when the ratio of bentonite to sewage sludge was 1:12.5 (4 g bentonite : 50 g sludge). Moreover, the optimal mixing ratio of the conditioned sewage sludge to the soil (1:2) was suggested for agricultural use. Based on these observations, modified bentonite allowed the sewage sludge to be used as a fertiliser in agriculture by stabilising heavy metals and retaining nutrient species.
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Metais Pesados , Esgotos , Agricultura , Bentonita , NutrientesRESUMO
In-situ sludge reduction plays a significant role in reducing excess sludge production. This study investigated the role of beneficial microorganisms (BM) in the anoxic-oxic-settling-anoxic (A-OSA) process associated with the in-situ sludge reduction efficiency under synthetic landfill leachate treatment. The rates of excess sludge reduction with the inoculation of BM increased up to 53.6% (calculated as total suspended solids) and 38.3% (calculated as total volume), respectively. Side-stream reactors, as important components of the A-OSA process, were further studied to explore change of parameters related to in-situ sludge reduction. With the inoculation of BM, the release and conversion of extracellular polymeric substances and the dehydrogenase activity (increasing rate = 60.9%) were increased. Species richness and microbial diversity, as well as the microbial community composition (e.g., hydrolytic and fermentative bacteria), were improved via bioaugmentation. Moreover, potential gene functions of microorganisms were positively regulated and the abundance of gene expressions (e.g., nirK, norB) for in-situ sludge reduction could be improved.
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Esgotos , Poluentes Químicos da Água , Anaerobiose , Reatores Biológicos , Consórcios Microbianos , Eliminação de Resíduos LíquidosRESUMO
This study warns regarding the possibility of microplastics (MPs) release from wet wipes and further in the environment and examines the potential associated risks. The exposure of humans to MPs during cleaning, and their discharge into wastewater treatment processes through flushing in toilets/basins was simulated by rubbing wet wipes on hands and immersing them in water, respectively. Wet wipes can be stored in a waste bin and subsequently disposed of through waste treatment or directly disposed in aquatic environments. The released MPs were identified and quantified using Fourier transform infrared spectroscopy. The released MPs were in the fibre form, and their major component was polyester. A higher number of MP fibres (693-1066 p/sheet) was released when the wet wipe was exposed to the aquatic environment compared to rubbing the wet wipe on hands or solid materials (180-106 p/sheet) or both. In particular, wet wipes in the wet state released the highest number (1966 p/sheet) of MP fibres. Unexpectedly, the least number of MP fibres was released by rubbing them on the hands/solid (180-200 p/sheet). Most fibres (>90%) were more than 100 µm, and those above 300 µm accounted for more than 40%-60% of the total number of detected MP fibres. This implies that long MP fibres released into the environment could disrupt the health of the aquatic ecosystem owing to their bioaccumulation, retention time, intestinal toxicity, and the transfer of persistent organic matter to aquatic organisms.
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The annual growth of global energy demand and the associated environmental impacts (EIs) has an important role in the large sustainable and green global energy transition. Renewable energy systems have been attracting substantial economic, environmental, and technical attention throughout the last decade, while some have been in the market for almost a century. However, even renewable energy may negatively affect the environment, which is widely considered much less harsh than fossil energy resources. This, in return, requires more consideration and appropriate precautions to be taken. This work discusses the environmental impacts (EIs) of small and medium-sized wind, hydro, biomass, and geothermal power systems. The approach goes through all stages from planning and conception to construction and installation and throughout service life and decommissioning. For various circumstances and technically and ecologically viable guidelines for their effect on natural resources and wildlife, clear and comprehensive solutions have been given.
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In response to the ever-increasing need for monitoring-based process control of wastewater treatment plants, an online applicable respirometer shows great promise for real-time measurement of oxygen uptake rate (OUR) and biochemical oxygen demand (BOD) measurements as a surrogate of the biodegradability of wastewater. Here, we have developed a photosensor-assisted real-time respirometric system equipped with bubble counting sensors for accurate measurement of microbial oxygen consumption in a bottle. This system can measure OUR and BOD in a bottle equipped with a tube containing NaOH solution to absorb carbon dioxide and supplied with continuous atmospheric oxygen to the bottle, which reliably supplies non-limiting dissolved oxygen (DO) for aerobic biodegradation even at high organic loads. These technical improvements allow a sensitive and rapid analytical tool offering real-time profiles of oxygen uptake rate as well as BOD measurements with an extended measurable range (0-420 mg O2/L), enabling significant reduction or elimination of dilution steps. The respirometric system was used to elucidate the biodegradable kinetics of domestic and swine wastewaters as a function of the type and concentration of organic matters, depending on source characteristics including rapidly or slowly oxidizable organic substances by bacteria. Compared with conventional and manometric BOD methods, our method is reliable and accurate.