Chemical characterization of PM2.5 emissions and atmospheric metallic element concentrations in PM2.5 emitted from mobile source gasoline-fueled vehicles.

Fine particulate matter with an aerodynamic diameter of <2.5 µm (PM2.5), particularly from the in-use gasoline-fueled vehicles, is a leading air quality pollutant and the chemical composition of PM2.5 is vital to the practical issues of climate change, health effects, and pollution control policies, inter alia. These atmospheric fine particulate matters (PM2.5) emitted from the exhausts of mobile source gasoline-fueled vehicles constitute substantial risks to human health through inhalation, and most importantly, affect urban air quality. Therefore, in order to explicitly determine the inhalation risks of PM2.5 which could potentially contain a significant amount of chemicals and metallic elements (MEs) concentration, we investigated the chemical composition (comprising of carbonaceous species and metallic elements) of PM2.5 emissions from mobile source gasoline-fueled vehicles. To further examine the chemical composition and metallic elements concentration in PM2.5 from the exhausts of mobile source gasoline-fueled vehicles, we systematically investigated PM2.5 emission samples collected from the exhausts of fifteen (15) mobile source gasoline-fueled vehicles. Our study has equally also determined the chemical compositions based on carbonaceous species (organic carbon - OC and elemental carbon - EC). Furthermore, the concentrations of PM2.5 and metallic elements (Ca, Al, Zn, K, Ca, Fe, Mg and Cr) in PM2.5 were analyzed with the help of Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). The details of the tested gasoline-fueled vehicles cover the model years, consisting of the vehicles registered from 2000 to 2017 from several vehicle manufacturers (or brands) with various running mileages ranging from 123.4 to 575,844 km (average 123,105 km). Our results established that elemental carbon (EC) and organic carbon (OC) were the most significant concentrations of carbonaceous species. The concentration of metallic elements in PM2.5 and chemical characterization were studied by their relationship with atmospheric PM2.5 and the results showed that the metallic elements concentration in PM2.5 were in descending order as follows: Ca > Al > Zn > K > Fe > Mg > Cr. These results will help us to further understand how PM2.5 emissions from the exhausts of in-use gasoline-fueled vehicles contribute to both chemical and atmospheric metallic elements concentration in the ambient air.

Assessment of PM2.5 and PAH content in PM2.5 emitted from mobile source gasoline-fueled vehicles in concomitant with the vehicle model and mileages.

This study investigates the PM2.5 emission and analyses the PAHs content in PM2.5 emitted from gasoline-fueled vehicles. Outflow from the vehicles appear to be the ultimate source of PAHs in metro urban communities since the emission from gasoline vehicle increases the wellbeing hazard due to contiguity of exposure to gasoline exhaust. In this study, fifteen vehicles were randomly taken for sampling, where sixteen priority PAHs concentration were investigated. The study was performed on the vehicles with different Euro standard emission by taking into consideration the European legislative levels for vehicles on the toxic gaseous emission. Among all the PAHs outflow components of PM2.5 radiated in the exhaust of gasoline engines, the average concentration of total PAHs discharged was 0.377ng/L-fuel, while the total BaPeq concentration was 0.00993ng/L-fuel.

Effects of atmospheric-plasma system on energy efficiency improvement and emissions reduction from a diesel engine.

Efficient energy usage and energy saving is one of the nowadays necessity for all scientists of IC engine. This is because of the current environmental challenges that have tremendously increased concerning air pollution, particularly pollutant emissions from vehicles. Yet, industries and governments alike have disregarded this phenomenon which has been considerably contributing to climate change. It is against this background that, the research works carried out in this present study is predominantly focusing on improving energy efficiency and reducing emission levels from diesel engines. This can be achieved with the help of atmospheric-plasma system which can offer a noble solution to the above-mentioned challenges due to its potential to improve combustion efficiency which leads to energy efficiency, while reducing emission levels from diesel engines. In this study, the performance and emissions of a diesel generator supplemented with an atmospheric-plasma system was examined. The diesel engine was used to examine the effects of fuel composition, or brake specific fuel consumption, thermal efficiency and pollutant emissions at different plasma system voltages. To this end, we equally examined the effects of atmospheric-plasma system on energy efficiency improvement and emissions reduction from diesel engine as the main purpose of this study. We do so by testing the diesel-fueled engine generator under the atmospheric-plasma system. The tests were carried out at a constant state condition with the engine running at 2200 rpm with torque and power outputs of 10.4 Nm (75% of the max load) and 2.1 kW, separately, for the tested fuels and this was used to increase the output voltage of the plasma system during this study. The plasma system ionized the intake air and improved the formation of free radicals upon combustion. During this study, the output voltage of the plasma was set within the range of 0-7 kV. The experimental results have indicated that formaldehyde, acetaldehyde and acrolein account for more than 75% of total carbonyl compounds emissions. Simultaneously, it was also observed from the results that higher plasma system voltage reduces pollutants emissions levels. Hence, such reduction is predominantly evident for nitrogen oxides, particulate matters and carbon monoxide. However, the marginal improvements of engine performance and emissions reduction become insignificant when the plasma system voltage reaches 6 kV. On the other hand, increasing the amount of plasma system voltages in diesel engine continues to significantly reduce pollutant emissions.

Characterization and quantification of PM2.5 emissions and PAHs concentration in PM2.5 from the exhausts of diesel vehicles with various accumulated mileages.

Road traffic is one of the main sources of particulate matter in the atmospheric environment. Notwithstanding its significance, there are noteworthy challenges in quantitative assessment of its contribution to the concentrations of airborne. This study reports on the characterization and quantification of PM2.5 emissions and PAHs concentration in PM2.5 from the exhausts of on-road diesel vehicles with various accumulated mileages in Kaohsiung City, Taiwan. Urban areas could be a subject matter not just in connection to deprived air quality, but similarly to pollution of other significant environmental media by air contaminants. To that end, our study intends to estimate the PM2.5 emissions from diesel vehicles using diesel fuels and to analyze the PM2.5 emissions and PAHs concentration in PM2.5. In this study, particulate matters (PM2.5) were characterized and quantified from a place impacted by diesel vehicles fueled with diesel in Kaohsiung City, Taiwan. The tested diesel vehicles with various accumulated mileages overs the model year comprising of the vehicles registered from 1984 to 2012 from different manufacturers (or brands) ranging from 8733 to 965,026 km (average 445,433 km) accumulative mileages. Exhaust constituents include CO, NOx, PM2.5 and particle phase PAHs. The concentrations of twenty-one (21) priority polycyclic aromatic hydrocarbons (PAHs) were studied in the samples by their relationship with atmospheric PM2.5. However, in relations to cumulative mileages, lower cumulative mileage (mileage <20,000 km) has the lowest CO and NOx emission factors. The mileage ranged from 20,001 to 30,000 km had an increased CO and NOx emission factors, respectively. Interestingly, with the increased high number of mileages ranged from 30,001 to 50,000 km, CO and NOx emission factor was observed to be declining, respectively. This could be attributed to the technological changes on new diesel vehicle models. But nonetheless, the trend of CO emission factor was found to be higher with an increasing of cumulative mileages as compared to the mileage that reached lower than 30,000 km.

Effect of air pollutants and toxic emissions from various mileage of motorcycles and aerosol related carcinogenicity and mutagenicity assessment.

This research investigates the mileage and the health risk assessment of aerosol carcinogenicity and mutagenicity emitted by ten in-use motorcycles. The total p-PAHs emission factor of ten in-use motorcycles are 676.3 µg km-1 with average of 67.6 ± 13.6 µg km-1. Naphthalene (Nap) shows the largest emission factors, followed by phenanthrene (PA) and fluoranthen (FL). The mileage present high correlation coefficient (Rsp = 0.681) with CO. CO is associated with cumulative mileage leading to bad combustion efficiency, which caused low to high relationship for total p-PAHs (Rsp = 0.388), PM2.5 (Rsp = 0.680) and NOx (Rsp = 0.799). Both PM2.5 and total p-PAHs are generally generated via incomplete combustion and the results expressed the moderate to high correlation (Rsp = 0.578, 0.898) with NOx. Taking into consideration of high-mileage motorcycles (30,001-50,000 km), the toxic equivalent of carcinogenicity and mutagenicity exhaust are about 4.67, 1.99 and 3.89, 2.0 times higher than low (10,001-20,000 km) and middle (20,001-30,000 km) cumulative mileages, respectively. Therefore, in the conclusion of our study in compared with that of other research directed the fact that lower carcinogenicity and mutagenicity emission factor were found at lower cumulative mileages motorcycles however, the impact increases with the high cumulative mileage motorcycles.

Using tracer technique to study the flow behavior of surfactant foam.

Surfactant foam was used to remove absorbed hydrocarbons from soils. The nature and extent of the foam pathway decide the efficiency of this technology. The characteristics and behavior of foam flow are difficult to visually observe. In this study, laboratory sandbox experiments were performed to estimate the flow behavior of surfactant foam and thus elucidate the properties and flow behavior of surfactant foam. To quantitatively determine the distribution of foam and evaluate accurately the flow field of foam in the soil, this study designed a special technique, applying micro-scale iron powder as a tracer. The foam generated with 4% (w/v) mixed solution of Span 60 and sodium dodecyl sulfate (SDS) showed an excellent stability and quality, which made it particularly apt for this study. The results indicated that the foam flows through the zone above the clay planes and also flows through the zone between the clay planes. The heterogeneous sand does not inhibit the invasion of foam flow. Moreover, the results of tracer tests and photographs of the foam distributions in sandbox were identical in the behavior of foam flow. This knowledge is valuable for providing insight into the foam remediation of contaminated soil.

Coupled acidification and ultrasound with iron enhances nitrate reduction.

Contaminated soils, especially when pollutant concentrations are high, pose potentially serious threats to surface and groundwater quality, when there are spills, discharges, or leaking storage tanks. For in situ remediation of nitrate in groundwater, the use of zero-valent iron (Fe(0)) is suggested. The formation of passivating scales on Fe(0) over time may limit the long-term reduction potential of Fe(0). The aim of this study was to investigate the effect of ultrasound and pH on the destruction of passive oxide film. Batch tests were conducted in a specially designed protocol using ultrasound, and changing iron (commercial iron powder of micro-scale grain size) loading and pH. The results showed deactivation of the degradation process by Fe(0) with combined ultrasound/iron system and with ultrasound alone. However, the degradation rate increases with decrease in pH. The degradation rate was 45% for pH 2 and 20% for pH 4. The combination of iron, acidification, and ultrasound showed excellent degradation efficiency, and the degradation rate was 99%. Acidification could destroy passive oxide film and activate iron, thus, hastening the reaction between Fe(0) and nitrate. Ultrasound was helpful in destroying or preventing the formation of passive oxide film under acidification.

Association of pretreatment thrombocytosis with disease progression and survival in oral squamous cell carcinoma.

The objective of this study was to review the prevalence and prognostic impact of pretreatment thrombocytosis in patients with oral squamous cell carcinoma (OSCC). Medical records of 253 patients with OSCC were retrospectively reviewed. The relationship between the platelet count, TNM stage, histologic differentiation, recurrence rate, metastasis, and survival were analyzed. Pretreatment thrombocytosis was found in 61 (24.1%) of 253 patients and was associated with aggressive tumour growth (p=0.015), lymph node metastasis (p=0.009), and distant metastasis (p=0.001). Association with tumour recurrence fell just short of statistical significance (p=0.058). Patients with preoperative thrombocytosis had a poorer survival than those with normal platelet counts (p=0.004). Multivariate analysis using Cox's proportional hazards model indicated that thrombocytosis was an independent predictor of shorter survival (RR 2.48, 95% CI 1.30- 4.73, p=0.006).

Estimating the change of porosity in the saturated zone during air sparging.

Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the saturated zone change, which may alter the flow path of the air. To understand better the particle movement, this study performed a sandbox test to estimate the soil porosity change during air sparging. A clear fracture was formed and the phenomenon of particle movement was observed when the air injection was started. The moved sand filled the porous around the fracture and the reparked sand filled the fracture, reducing the porosity around the fracture. The results obtained from the photographs of the sandbox, the current measurements and the direct sand sample measurements were close to each other and are credible. Therefore, air injection during air sparging causes sand particle movement of sand, altering the characteristic of the sand matrix and the air distribution.