1.
Chem Commun (Camb)
; (22): 2800-1, 2003 Nov 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-14651111
RESUMO
The total synthesis of (-)-raumacline from L-tryptophan was achieved, featuring a cis-specific Pictet-Spengler reaction, a stereoselective Dieckmann cyclization, and an epimerization step that allowed complete stereocontrol of five chiral centres.