RESUMO
The strong geometric frustration of the kagome antiferromagnets (KAFMs) can destabilise conventional magnetic order and lead to exotic electronic states, such as the quantum spin-liquid state observed in someS=12KAFM materials. However, the ground state ofS = 1 KAFM systems are less well understood. Spin nematic phases and valence bond solid ground states have been predicted to form but a paucity of experimental realisations restricts understanding. Here, theS = 1 KAFM NH4Ni2Mo2O10H3is presented, which has the 3-fold symmetry of the kagome lattice but significant site depletion, withâ¼64%site occupancy. Frustration and a competition between exchange interactions are evidenced through the suppression of order below the Weiss temperature|θW|and observation of ferromagnetic and antiferromagnetic characteristics in the magnetisation data. A semi spin glass ground state is predicted based on the ac-field frequency dependence of the magnetic transition and ferromagnetic signal.
RESUMO
Kagome antiferromagnets (KAFMs) have long been known to host exotic electronic states due to their strong geometric frustration, including the quantum spin liquid state in [Formula: see text] systems. Away from that limit, S = 1 KAFMs are also predicted to host unconventional ground states such as spin nematic phases, but a paucity of studies on known model materials has restricted progress. Here, we present the crystal structure and preliminary magnetization measurements on the newly synthesized S = 1 KAFM, NH4Ni2.5V2O7(OH)[Formula: see text]H2O, which has the three-fold symmetry of the kagome lattice but significant site depletion, with â¼[Formula: see text] site occupancy. Bulk magnetic data show clear evidence of frustration and competition between ferromagnetic and antiferromagnetic interactions. We propose that the magnetic Hamiltonian is frustrated and that anisotropic terms cause the formation of an unconventional ground state.