RESUMO
Recent regulatory actions aim to limit per- and polyfluoroalkyl substances (PFAS) concentrations in drinking water and wastewaters. Regenerable anion exchange resin (AER) is an effective separation process to remove PFAS from water but will require PFAS post-treatment of the regeneration wastestream. Electrocatalytic (EC) processes using chemically boron-doped diamond electrodes, stable in a wide range of chemical compositions show potential to defluorinate PFOA in drinking water and wastewater treatments. Chemical composition and concentration of mineral salts in supporting electrolytes affect AER regeneration efficiency, and play a crucial role in the EC processes. Their impact on PFAS degradation remains understudied. This study investigates the impact of 17 brine electrolytes with different compositions on perfluorooctanoic acid (PFOA) degradation in an alkaline medium and explores the correlation between the rate of PFOA degradation and the solution's conductivity. Results show that higher electrolyte concentrations and conductivity lead to faster PFOA degradation rates. The presence of chloride anions have negligible impact on the degradation rate. However, the presence of nitrate salts reduce PFOA degradation efficiency. Additionally, the use of mixed electrolytes may be a promising approach for reducing the cost of EC operations. PFOA degradation was not influenced by the pH of the bulk solution.
Assuntos
Caprilatos , Eletrólitos , Fluorocarbonos , Poluentes Químicos da Água , Purificação da Água , Caprilatos/química , Fluorocarbonos/química , Concentração de Íons de Hidrogênio , Poluentes Químicos da Água/química , Eletrólitos/química , Purificação da Água/métodos , Catálise , Águas Residuárias/química , Água Potável/química , EletrodosRESUMO
Long-term electrolyses of glucose in a potassium carbonate (K2CO3) aqueous electrolyte have been performed on graphite felt electrodes with TEMPO as a homogeneous catalyst. The influences of the operating conditions (initial concentrations of glucose, TEMPO, and K2CO3 along with applied anode potential) on the conversion, selectivity toward gluconate/glucarate, and faradaic efficiency were assessed first. Then, optimizations of the conversion, selectivity, and faradaic efficiency were performed using design of experiments based on the L9 (34) Taguchi table, which resulted in 84% selectivity toward gluconate with 71% faradaic efficiency for up to 79% glucose conversion. Side products such as glucaric acid were also obtained when the applied potential exceeded 1.5 V vs. reversible hydrogen electrode.