Melt stretching and quenching produce low-crystalline biodegradable poly(lactic acid) filled with ß-form shish for highly improved mechanical toughness.

High-toughness biodegradable poly(lactic acid) (PLA) has always been intensively pursued on the way of replacing traditional petroleum-based plastics. Regulating microstructures to achieve self-toughening holds great promise due to avoidance of incorporating other heterogeneous components. Herein, we propose a straightforward and effective way to tailor microstructures and properties of PLA through melt-stretching and quenching of slightly crosslinked samples. The melt stretching drives chains orientation and crystallization at high temperature, while the quenching followed can freeze the crystallization process to any stage. For the first time, we prepare a type of transparent and low-crystalline PLA filled with rod-like ß-form shish, which displays an outstanding tensile toughness, almost 17 times that of the conventional technique-processed one. This mechanical superiority is enabled by an integration of high ductility due to oriented chain network, and high tensile stress endowed by nanofibrous filler's role of ß-form shish. Furthermore, the mechanically toughened PLA is demonstrated to generate the richest micro-cracks and shear bands under loading, which can effectively dissipate the deformational energy and underlie the high toughness. This work opens a new prospect for the bottom-up design of high-performance bio-based PLA materials that are tough, ductile and transparent by precise microstructural regulation through scalable melt processing route.

A combined melt-stretching and quenching setup for experimental studies of polymer crystallization under complex flow-temperature environments.

A combined melt-stretching and quenching setup is designed and developed to allow experimental investigations of polymer crystallization under the complex flow-temperature environments comparable to those encountered in the actual industrial processing. The melt-stretching proceeds by two drums rotating in the opposite directions with simultaneous recording of a stress-strain curve, where the Hencky strain and strain rate (≤233 s-1) are adjustable over a large range. After stretching, liquid N2 is used as a cooling medium to quench the free-standing melt, which is sprayed directly to the deformed melt driven by an electric pump. To ensure a high cooling efficiency, a three-way solenoid valve is employed to execute a sequential control of the liquid N2 flow direction to reduce the boil-off of liquid N2 before entering the sample chamber. The melt cooling rate depends on the liquid N2 flow rate controlled by a flow valve, which is up to 221 °C/s when quenching the isotactic polypropylene (iPP) melt with a thickness of 0.28 mm at 150 °C. Two independent temperature control modules are designed to meet the requirements of different stages of melt-stretching and quenching. To verify the capability of the setup, we have performed the melt-stretching and quenching experiments on iPP samples. The setup is demonstrated to be a valuable new tool to study polymer crystallization under coupled flow-cooling fields.