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1.
Chemosphere ; 337: 139417, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37419157

RESUMO

Overuse or mistimed application of nitrogen fertilizer can cause nitrate contamination in groundwater and surrounding surface waters. Previous greenhouse studies have explored the use of graphene nanomaterials, including graphite nano additive (GNA), to reduce nitrate leaching in an agricultural soil while growing lettuce crops. To investigate the mechanism of GNA addition in suppressing nitrate leaching, we conducted soil column experiments using native agricultural soils under saturated or unsaturated flow conditions to simulate varied irrigation. We investigated the effects of temperature (4 °C compared with 20 °C) on microbial activity and dose effect of GNA was also explored (165 mg/kg soil and 1650 mg/kg soil) for biotic soil column experiments whereas a single temperature condition (20 °C) and GNA dose (165 mg/kg soil) was employed for abiotic (autoclaved) soil column experiments. Results showed GNA addition had minimal effects on nitrate leaching in saturated flow soil columns due to short hydraulic residence times (∼3.5 h). In comparison, longer residence times (∼3 d) in unsaturated soil columns reduced nitrate leaching by 25-31% relative to control soil columns without GNA addition. Furthermore, nitrate retention in the soil column was found to be suppressed at 4 °C compared with 20 °C, suggesting a bio-mediated mechanism for GNA addition to reduce nitrate leaching. In addition, the soil dissolved organic matter was found to be associated with nitrate leaching, where less nitrate leaching occurring when higher dissolved organic carbon (DOC) was measured in leachate water. Following studies of adding soil-derived organic carbon (SOC) resulted in greater nitrogen retention in the unsaturated soil columns only when GNA was present. Overall, the results suggest that GNA-amended soil reduces nitrate loss through increased N immobilization in the microbial biomass or loss of N in gaseous phase through enhanced nitrification and denitrification process.


Assuntos
Grafite , Solo , Nitratos/análise , Fertilizantes , Agricultura/métodos , Nitrogênio/análise
2.
Sci Total Environ ; 631-632: 223-232, 2018 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-29525703

RESUMO

River water quality in rapidly urbanising Asian cities threatens to damage the resource base on which human health, economic growth and poverty reduction all depend. Dhaka reflects the challenges and opportunities for balancing these dynamic and complex trade-offs which goals can be achieved through effective policy interventions. There is a serious problem of water pollution in central Dhaka, in the Turag-Tongi-Balu River system in Bangladesh with the river system being one of the most polluted in the world at the moment. A baseline survey of water chemistry and total coliforms has been undertaken and shows dissolved oxygen close to zero in the dry season, high organic loading together with extreme levels of Ammonium-N and total coliform in the water. Models have been applied to assess hydrochemical processes in the river and evaluate alternative strategies for policy and the management of the pollution issues. In particular models of flow, Nitrate-N, Ammonium-N and indicator bacteria (total coliforms) are applied to simulate water quality in the river system. Various scenarios are explored to clean up the river system, including flow augmentation and improved effluent treatment. The model results indicate that improved effluent treatment is likely to have a more significant impact on reducing Ammonium-N and total coliforms than flow augmentation, but a combined strategy would greatly reduce the pollution problems in the Turag-Tongi-Balu River System.

3.
Int J Low Extrem Wounds ; 7(4): 204-9, 2008 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-19019846

RESUMO

The effects of spermatheca gland extract of snail (Telescopium telescopium) to promote wound healing were studied in an animal model. The spermatheca gland extract of the snail was used as a topical medicament to treat experimentally created full thickness wounds in 12 rabbits (Oryctologous cuniculus). Wound healing was assessed on the basis of physical, histomorphological, and histochemical changes on days 0, 3, 7, and 14. Statistically significant differences were observed between the groups in all measured parameters. These exciting findings suggest that the data should be further tested in animal models to better understand the potential for wound healing in the spermatheca gland extract of the marine snail.


Assuntos
Caramujos , Extratos de Tecidos/uso terapêutico , Cicatrização , Ferimentos e Lesões/terapia , Animais , Lectinas , Coelhos , Distribuição Aleatória
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