Effect of Cellulose-Based Bioplastics on Current LDPE Recycling.

The increased use of bioplastics in the market has led to their presence in municipal solid waste streams alongside traditional fossil-based polymers, particularly low-density polyethylene (LDPE), which bioplastics often end up mixed with. This study aimed to assess the impact of cellulose acetate plasticized with triacetin (CAT) on the mechanical recycling of LDPE. LDPE-CAT blends with varying CAT content (0%, 1%, 5%, 7.5%, and 10% by weight) were prepared by melt extrusion and analyzed using scanning electron microscopy, Fourier-transform infrared spectroscopy, thermal analysis (thermogravimetric and differential scanning calorimetry), dynamic rheological measurements, and tensile tests. The results indicate that the presence of CAT does not significantly affect the chemical, thermal, and rheological properties of LDPE, and the addition of CAT at different levels does not promote LDPE degradation under typical processing conditions. However, the addition of CAT negatively impacts the processability and mechanical behavior of LDPE, resulting in the reduced quality of the recycled material. Thus, the presence of cellulose-based bioplastics in LDPE recycling streams should be avoided, and a specific sorting stream for bioplastics should be established.

Does PET trays sorting affect the sustainability of plastic waste? An LCA and cost-revenue approach.

Currently, the management of polyethylene terephthalate (PET) trays waste is still challenging since this packaging affects the consolidate recycling of PET bottles. It is important to separate PET trays from the PET bottle waste stream to avoid its contamination during recycling process and to recover a higher amount of PET. Hence, the present study aims to evaluate the environmental (by means of Life Cycle Assessment, LCA) and economic sustainability of sorting PET trays from the plastic waste streams selected by a Material Recovery Facility (MRF). For this scope, the case of a MRF in Molfetta (Southern Italy) was chosen as reference, and different scenarios have been evaluated by assuming different schemes of manual and/or automated PET trays sorting. The alternative scenarios did not achieve very pronounced environmental benefits over the reference case. Upgraded scenarios resulted in overall environmental impacts approx. 10 % lower as compared to the current scenario, with the exception of the climate and ozone depletion categories where differences in impacts were much higher. From an economic point of view, the upgraded scenarios achieved slightly lower costs (<2 %) than the current one. Electricity or labour costs were necessary in upgraded scenarios, but in this way fines for PET trays contamination in PET streams for recycling were avoided. Implementing any of the technology upgrade scenarios is then environmentally and economically viable, when the PET sorting scheme is performed in appropriate output streams through optical sorting.

Environmental Sustainable Cement Mortars Based on Polyethylene Terephthalate from Recycling Operations.

The building and construction industry is a key sector behind the ecological transition in that it is one of the main responsible factors in the consumption of natural resources. Thus, in line with circular economy, the use of waste aggregates in mortars is a possible solution to increase the sustainability of cement materials. In the present paper, polyethylene terephthalate (PET) from bottle scraps (without chemical pretreatment) was used as aggregate in cement mortars to replace conventional sand aggregate (20%, 50% and 80% by weight). The fresh and hardened properties of the innovative mixtures proposed were evaluated through a multiscale physical-mechanical investigation. The main results of this study show the feasibility of the reuse of PET waste aggregates as substitutes for natural aggregates in mortars. The mixtures with bare PET resulted in less fluid than the specimens with sand; this was ascribed to the higher volume of the recycled aggregates with respect to sand. Moreover, PET mortars showed a high tensile strength and energy absorption capacity (with Rf = 1.9 ÷ 3.3 MPa, Rc = 6 ÷ 13 MPa); instead, sand samples were characterized by a brittle rupture. The lightweight specimens showed a thermal insulation increase ranging 65-84% with respect to the reference; the best results were obtained with 800 g of PET aggregate, characterized by a decrease in conductivity of approximately 86% concerning the control. The properties of these environmentally sustainable composite materials may be suitable for non-structural insulating artifacts.

Recycling of Contaminated Marine Sediment and Industrial By-Products through Combined Stabilization/Solidification and Granulation Treatment.

Stabilization/solidification (S/S) is becoming increasingly important, as it allows the remediation of contaminated sediments and their recovery into materials for civil engineering. This research proposes a cement-free cold granulation process for manufactured low-cost aggregates from marine sediments contaminated with organic compounds and metals. After the chemo-physical characterization of the study materials, two mix designs were prepared in a rotary plate granulator by adding two industrial by-products as geopolymer precursors, coal fly ash (CFA) and Blast Furnace Slag (BFS), but also alkaline activation solutions, water, and a fluidizer. The results indicated that sediments treated with mix 1 (i.e., with a higher percentage of water and fluidifier) represent the optimal solution in terms of metal leachability. The metal leachability was strictly influenced by aggregates' porosity, density, and microstructure. The technical performance (such as the aggregate impact value > 30%) suggested the use of granules as lightweight aggregates for pavement construction. The results indicated that cold granulation represents a sustainable solution to recycling contaminated marine sediments, CFA, and BFS into lightweight artificial aggregates.

Life cycle assessment of end-of-life options for cellulose-based bioplastics when introduced into a municipal solid waste management system.

The partial degradation of cellulose-based bioplastics in industrial treatment of organic fraction of Municipal Solid Waste (MSW) opened to the investigation of further disposal routes for bioplastics in the waste management system. For this purpose, the environmental footprint of three MSW management scenarios differing only for the bioplastics final destination (organic, plastic or mixed waste streams) was assessed through a Life Cycle Assessment (LCA) approach. Results revealed how the treatment of bioplastics with organic waste achieved the worst environmental performance (5.8 kg CO2 eq/FU) for most impact categories. On the other hand, treatment with plastics and mixed waste achieved negative impact values (that mean avoided GHG emissions) of -9.8 and -7.7 kg CO2 eq/FU respectively, showing comparable benefits from these scenarios. The key reason was the lower quality of compost obtained from the organic treatment route, which reduced the environmental credits achieved by the energy recovery during anaerobic digestion.

Co-digestion of food waste and cellulose-based bioplastic: From batch to semi-continuous scale investigation.

Only few studies on the behaviour of bioplastics in anaerobic co-digestion could be found in literature and most of them are conducted in batch mode. Despite the fact that continuous experiments confirm or add new insight to the findings acquired from batch ones, there is still lack of such studies. This work aims to cover this gap, carrying out a semi-continuous anaerobic co-digestion of food waste and cellulose acetate (which its behaviour under anaerobic environment is also quite unexplored). After a first evaluation of the potential methane production from each substrate at batch scale, the semi-continuous co-digestion of food waste and cellulose acetate was carried out in three configurations. During the semi-continuous process, a methane yield of 331 NmlCH4/gVS was generated from the co-digestion of food waste and cellulose acetate while bioplastics specimens achieved a weight loss of about 45 %. The results were both lower than the one obtained from batch co-digestion, although methane production rates were comparable regardless of being fed with or without bioplastics. An increase was registered after 65 days of semi-continuous process, due to the accumulation of CA specimens. This confirms the different degradation trends between bioplastics and food waste.

Effects of cellulose-based bio-plastics on the aerobic biological stabilization treatment of mixed municipal solid waste: A lab-scale assessment.

The aim of this work is to assess how the presence of cellulose-based bio-plastics influence the biological stabilization of mixed Municipal Solid Waste (MSW). For the scope, two cellulose acetate bio-plastics have been mixed with a synthetic mixed waste to create samples with and without bio-plastics. A self-induced biostabilization has been carried out for 7 and 14 days where temperature and off-gas have been monitored continuously. Results about temperature evolution, O2 consumption, CO2 production and respiratory quotient did not show a substantial difference regarding both the duration of the process and the presence of cellulose-based bio-plastics on the mixture. On the average, the temperature peak and the maximum daily O2 consumption and CO2 production were 52.2 °C, 35.81 g O2/kg DM *d and 48.95 g CO2/kg DM *d respectively. Disintegration of bio-plastics samples after 7 and 14 days were comparable (on the average 23.13%). The self-induced biostabilization gave its main contribution after 4 days and resulted almost finished at the end of the day 7 of the process. Results showed that cellulose-based bio-plastics did not give a negative effect on mixed MSW biological stabilization and suggest a possible management, aiming at energy recovery of the outputs.

The Improvement of Durability of Reinforced Concretes for Sustainable Structures: A Review on Different Approaches.

The topic of sustainability of reinforced concrete structures is strictly related with their durability in aggressive environments. In particular, at equal environmental impact, the higher the durability of construction materials, the higher the sustainability. The present review deals with the possible strategies aimed at producing sustainable and durable reinforced concrete structures in different environments. It focuses on the design methodologies as well as the use of unconventional corrosion-resistant reinforcements, alternative binders to Portland cement, and innovative or traditional solutions for reinforced concrete protection and prevention against rebars corrosion such as corrosion inhibitors, coatings, self-healing techniques, and waterproofing aggregates. Analysis of the scientific literature highlights that there is no preferential way for the production of "green" concrete but that the sustainability of the building materials can only be achieved by implementing simultaneous multiple strategies aimed at reducing environmental impact and improving both durability and performances.

The influence of bio-plastics for food packaging on combined anaerobic digestion and composting treatment of organic municipal waste.

The use of bio-plastic-based packaging as an alternative to conventional plastic packaging is increasing. Among the plethora of different bio-based plastics, the most relevant ones are those that, at the end of their life, can be treated with the organic fraction of municipal solid waste. Even in these cases, their impact on the waste processing and recycling is not always positive. This study aim to assess on a laboratory scale the influence on combined anaerobic digestion and composting industrial processes of a bio-based plastic film, namely cellulose acetate (CA), in pure and modified (additions of additive) forms. CA films were mixed with organic waste and subjected to: (i) anaerobic digestion; (ii) active composting and (iii) two stages of curing composting. Anaerobic digestion and composting were monitored through methane yield and oxygen uptake respectively; additionally, the bio-plastics degree of disintegration was assessed during all the processes. The final disintegration of pure and modified CA was 73.82% and 54.66%, respectively. Anaerobic digestion contributes to the disintegration of the material, while aerobic treatment appears to be nearly ineffective, especially for modified CA. The presence of cellulose acetate during anaerobic digestion of food waste increased the methane yield by about 4.5%. Bioassay confirmed the absence of possible toxic effects on the final compost from the bio-plastic treatment. Although bio-based materials are not the only solution to plastic pollution, the findings confirm the need to upgrade the organic waste treatment plants and the necessity to revise the requirements for the use of compost in agriculture.

The role of (bio)degradability on the management of petrochemical and bio-based plastic waste.

In order to mitigate the social and ecological impacts of post-consumer plastic made of conventional petrochemical polymers, the market of (bio)degradable plastics have recently become more widespread. Although (bio)degradable plastics could be an environmentally friendly substitute of petrochemical ones, the consequences of their presence in the waste management system and in the environment (if not correctly disposed) are not always positive and plastic pollution is not automatically solved. Consequently, this work aims to review how plastic (bio)degradability affects the municipal solid waste management cycle. To this end, the state-of-the-art of the intrinsic (bio)degradability of conventional and unconventional petrochemical and bio-based polymers has been discussed, focusing on the environment related to the waste management system. Then, the focus was on strategies to improve polymer (bio)degradability: different types of eco-design and pre-treatment approach for plastics has been investigated, differently from other works that focused only on specific topics. The information gathered was used to discuss three typical disposal/treatment routes for plastic waste. Despite many of the proposed materials in eco-design have increased the plastics (bio)degradability and pre-treatments have showed interesting results, these achievements are not always positive in the current MSW management system. The effect on mechanical recycling is negative in several cases but the enhanced (bio)degradability can help the treatment with organic waste. On the other hand, the current waste treatment facility is not capable to manage this waste, leading to the incineration the most promising options. In this way, the consumption of raw materials will persist even by using (bio)degradable plastics, which strength the doubt if the solution of plastic pollution leads really on these materials. The review also highlighted the need for further research on this topic that is currently limited by the still scarce amount of (bio)degradable plastics in input to full-scale waste treatment plants.

Experimental Investigation on Environmentally Sustainable Cement Composites Based on Wheat Straw and Perlite.

Environmentally sustainable cement mortars containing wheat straw (Southern Italy, Apulia region) of different length and dosage and perlite beads as aggregates were prepared and characterised by rheological, thermal, acoustic, mechanical, optical and microstructural tests. A complete replacement of the conventional sand was carried out. Composites with bare straw (S), perlite (P), and with a mixture of inorganic and organic aggregates (P/S), were characterised and compared with the properties of conventional sand mortar. It was observed that the straw fresh composites showed a decrease in workability with fibre length decrease and with increase in straw volume, while the conglomerates with bare perlite, and with the aggregate mixture, showed similar consistency to the control. The thermal insulation of the straw mortars was extremely high compared to the sand reference (85-90%), as was the acoustic absorption, especially in the 500-1000 Hz range. These results were attributed to the high porosity of these composites and showed enhancement of these properties with decrease in straw length and increase in straw volume. The bare perlite sample showed the lowest thermal insulation and acoustic absorption, being less porous than the former composites, while intermediate values were obtained with the P/S samples. The mechanical performance of the straw composites increased with length of the fibres and decreased with fibre dosage. The addition of expanded perlite to the mixture produced mortars with an improvement in mechanical strength and negligible modification of thermal properties. Straw mortars showed discrete cracks after failure, without separation of the two parts of the specimens, due to the aggregate tensile strength which influenced the impact compression tests. Preliminary observations of the stability of the mortars showed that, more than one year from preparation, the conglomerates did not show detectable signs of degradation.

A review of the in-situ capping amendments and modeling approaches for the remediation of contaminated marine sediments.

Contaminated sediments can pose long-term risks to human beings and ecosystems as they accumulate inorganic and organic contaminants becoming a sink and source of pollution. Compared to ex-situ technologies (i.e., dredging activities and off site treatments), in-situ capping (ISC) intends to minimize contaminated sediment mobilization and impact into the water column whilst treating contamination. Literature shows that numerous types of ISC amendments in presence of both organic and inorganic pollutants are investigated, although a few are contributions whose experiments have been designed and conducted with a view to future engineering. Against this background of shortcomings, this review paper intends to investigate ISC reliability, applicability and its long-term effectiveness, by also comparing reactive and physical ISCs. Additionally, an examination of the main numerical simulations applied to ISC technology was carried out. We found that activated carbon and organoclay resulted the most studied amendments for organically contaminated sediment, whereas biochar, clay minerals, and industrial-by products were more employed in presence of sediment contaminated by metal(loids). There is no better ISC system in absolute terms, since technological performance depends on many factors and only a few experimental investigations included a long-term modeling phase to predict ISC long-term efficiency. Most of numerical models included simplified transport equations based on diffusion and adsorption, and the goodness of fitting between experimental and modeled data was not always computed. The review finally discusses new research directions such as the need for long-term applications on field-scale and cap effectiveness in presence of site-specific tidal forces and currents.

Sustainable ex-situ remediation of contaminated sediment: A review.

Routine waterway dredging activities generate huge volumes of dredged sediment. The remediation of dredged contaminated sediment is a worldwide challenge. Novel and sustainable ex-situ remediation technologies for contaminated sediment have been developed and adopted in recent years. In this review paper, the state-of-art ex-situ treatment technologies and resource utilisation methods for contaminated sediment were critically reviewed. By applying different techniques, sediment could been successfully transformed into sustainable construction materials, such as ceramsite, supplementary cementitious materials, fill materials, paving blocks, partition blocks, ready-mixed concrete, and foamed concrete. We highlighted that proper remediation technologies should be cleverly selected and designed according to the physical and chemical characteristics of sediment, without neglecting important aspects, such as cost, safety, environmental impacts, readiness level of the technology and social acceptability. The combination of different assessment methods (e.g., environmental impact assessment, cost-benefit analysis, multi-criteria decision analysis and life cycle assessment) should be employed to comprehensively evaluate the feasibility of different sustainable remediation technologies. We call on the scientific community in a multidisciplinary fashion to evaluate the sustainability of various remediation technologies for contaminated sediment.

A holistic DPSIR-based approach to the remediation of heavily contaminated coastal areas.

This paper proposes a holistic approach to connect anthropogenic impacts to environmental remediation solutions. The eDPSIR (engineered-Drivers-Pressures-States-Impacts-Responses) framework aims at supporting the decision-maker in designing technological solutions for a contaminated coastal area, where the natural matrices need to be cleaned up. The eDPSIR is characterized by cause-effect relationships that are operationally implemented through three multidisciplinary toolboxes: (i) Toolbox 1, to connect driving forces with pressures, classifying the state of the system and allowing the identification of target contaminants and the extent of contamination; (ii) Toolbox 2, to quantify bioaccumulation also by identifying corresponding areas; (iii) Toolbox 3, to identify the most suitable remediation solutions for previously identified contaminated areas, named contamination scenarios. The eDPSIR was calibrated on the case study of the Mar Piccolo in Taranto (Southern Italy), one of the most complex and polluted areas in Europe. While the consolidated DPSIR allows for a strategic response by limiting the use of contaminated areas or reducing upstream pressures, the eDPSIR made it possible to structure with a semi-quantitative logic the problem of assisting the decision-makers in choosing the optimal technological remediation responses for each sediment scenario of contamination (heavy metal; organic compounds; mixed). Assisted natural attenuation was identified as the best remediation technology in terms of treatment effectiveness and smallest amount of impacts involved in the project actions. However, considering the scenario of mixed contamination, in-situ reactive capping reached a good rank with a value of the composite indicator equal to 99.5%; thermal desorption and stabilization/solidification recorded a value of 94.1% and 84.6%, respectively. The application of these toolboxes provides alternative means to interpret, manage, and solve different cases of global marine contaminated sites.

Feasibility Analysis on the Adoption of Decentralized Anaerobic Co-Digestion for the Treatment of Municipal Organic Waste with Energy Recovery in Urban Districts of Metropolitan Areas.

Anaerobic digestion (AD) of organic fraction of municipal solid waste (OFMSW) is considered an excellent solution for both waste management and energy generation, although the impacts of waste collection and transportation on the whole management system are not negligible. AD is often regarded as a centralized solution for an entire community, although recently, there has been some debate on the adoption of decentralized, smaller facilities. This study aims to evaluate the techno-economic feasibility of an AD plant at the local scale for the treatment of organic waste generated from urban districts. Depending on the type of feedstock, two scenarios were evaluated and compared with the reference scenario, based on composting treatment: (1) mono-AD of OFMSW and (2) co-AD of OFMSW and sewage sludge (SS). Furthermore, different district extensions of the metropolitan area were considered with the goal of determining the optimal size. Results showed the advantage of the two scenarios over the reference one. Scenario 1 proved to be the most suitable solution, because the introduction of SS in Scenario 2 increased costs and payback time, rather than generating a higher waste amount and lower biogas yield. The preferred district extension was the medium-sized one. Capital cost strongly affected the economic analysis, but revenue from the city for the management operation of the organic waste could significantly decrease costs. Further studies about the differences in the type of feedstock or the introduction of other criteria of analysis (such as environmental) are considered necessary.

Contaminated marine sediment stabilization/solidification treatment with cement/lime: leaching behaviour investigation.

Among ex situ remediation technologies, stabilization/solidification (S/S) provides for the addition of a binder to dredged materials in order to chemically immobilise the contaminants and improve mechanical behaviour of sediments. The simplest form of treatment is obtained by the addition of Portland cement or lime (calcium oxide), although other additives such as adsorbents may be added. Nevertheless, the success of the S/S treatment may be affected by the contaminants present or by the salt content in the water. In this study, experimental laboratory investigation was carried out on sediments carefully collected from the Mar Piccolo of Taranto in Southern Italy, contaminated by heavy metals, polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs); the goal was to explore the effectiveness of S/S treatment by using Portland cement/lime as binders, monitoring over time (28 days) the leaching of the different mixtures of treated sediment. It is noted that the Mar Piccolo of Taranto is one of the sites of national interest subject to remediation by the Italian government. Once taken within the first meter under the sea floor by a team of experienced divers, the samples were stored at a controlled temperature, characterised in terms of grain size and physical-chemical characteristics and treated by S/S laboratory tests. The results indicate that the addition of binders increased the pH of the mixtures with a consequent leachability of different metals. The mobility of the metals appeared to be governed also by the curing time. The performance of the mixtures in terms of immobilised metals was influenced by the presence of organic contaminants (e.g. organic matter, PAHs and PCBs). As a lesson, high organic matter and fine-grained particles can negatively affect the effectiveness of the S/S treatment in terms of metal immobilisation.

Sustainable design of large wastewater treatment plants considering multi-criteria decision analysis and stakeholders' involvement.

The typical treatment scheme of a large municipal wastewater treatment plant (LWWTP) is almost always the result of design based on technical and economic criteria. Once a threshold in terms of population equivalent (PE) is reached, it is possible that additional sludge thermal treatment might be required. Aspects such as greenhouse gas (GHG) emissions and land use for the construction of the WWTP or the service landfill are considered marginal in current design practice; in a world that requires increasingly attention to the environment, these criteria cannot be ignored when defining the treatment scheme of a LWWTP. With the intent of providing a sustainable approach to design, this study aims to identify the best treatment scheme for a LWWTP with a 720,000 PE size. Methodologically, the study involves the development of an approach based on multi-criteria decision analysis (MCDA). Six alternative treatment schemes were considered; two simplified schemes, without primary sedimentation, with extended aeration activated sludge processes and aerobic sludge stabilization; four full schemes, with primary sedimentation and anaerobic sludge digestion. Some schemes differ for the organic loading rate applied; others for the use of sludge incineration. Subsequently, six evaluation criteria (ECs) such as GHG emissions, electricity consumption, running costs, WWTP planimetric area, surface for the service landfill, as well as WWTP as biorefinery have been considered. The weighting of the ECs involved the participation of the main stakeholders in such a decision-making process, following a bottom-up approach. The resolution of the MCDA problem allowed the identification of the full scheme based on primary sedimentation, biological activated sludge at low organic load (0.210 kgBOD5/kgVSS/d) and anaerobic sludge digestion as the best solution. The sensitivity analysis, able to indirectly take into account the multitude of decision makers involved, allowed corroborating the results. The obtained treatment scheme was different from that generally adopted in current design practice for LWWTPs.

Environmentally Sustainable Cement Composites Based on End-of-Life Tyre Rubber and Recycled Waste Porous Glass.

In this paper, environmentally sustainable cement mortars were prepared with end-of-life tyre rubber (TR) and recycled waste porous glass (PG) as aggregates in order to obtain lightweight products characterized by renewable and not-pretreated materials specifically for indoor applications. The secondary raw materials were added as partial and/or total replacement of the conventional sand aggregate. The resulting lightweight specimens were characterized by rheological, mechanical, thermal, microstructural and wettability tests. Fine tyre rubber aggregates affected the cohesiveness of the composites, as opposite to coarse tyre rubber and porous glass. The flexural and the compressive strengths of the porous glass samples were higher than the tyre rubber samples because of the higher stiffness and good adhesion of the glass to the cement paste as observed by microstructural observations. On the contrary, an unfavorable adhesion of the tyre aggregates to the cement paste was observed, together with discrete cracks after failure without separation of the two parts of the specimens. The latter result can explain the best results obtained by tyre rubber mortars in the case of impact compression tests where the super-elastic properties of the elastomeric material were evidenced by a deep groove before complete failure. Moreover, the thermal conductivity decrease of the lightweight porous TR and PG composites was in the range of ~80-90% with respect to the sand-based samples, which suggests that they can be used as plasters and masonries, and, in the case of tyre rubber specimens, outside applications are not excluded as observed from the wettability tests.

Alternating pure oxygen and air cycles for the biostabilization of unsorted fraction of municipal solid waste.

Biostabilisation is a process of treating the unsorted fraction of municipal solid waste (UFMSW) mechanically pre-treated. Although concepts such as circular economy would seem to limit biostabilization, several authors have recently described the advantages of biostabilization in regions where recycling systems are inadequate. In this perspective, the development of new MBT technologies is of considerable importance. The objective of the study was to evaluate the effects of the use of alternating air and oxygen cycles on the treated waste stability as well as on the quality of leachate and process gaseous emissions. Two Herhof biocells were prepared for this purpose. One implemented the conventional process and the other the "Air + O2" process. The biostabilization of the inlet UFMSW (3965 ±â€¯1965 mgO2/kgVS/h) resulted in a final product with a dynamic respirometric index almost equal in both processes. The mass balance indicated that of the 400 tons representing the input waste, 37.57% were biostabilized waste, 0.29% leachate and 62.14% CO2 and odours. However, the biostabilized waste was lower than that of the conventional process (equal to 40.18%). The Air + O2 system resulted in a shorter duration, increased production of leachate (although characterized by higher quality) and process gaseous emissions quality. The energy balance (20.3 kJ/kg per input waste) and cost analysis (80.0 €/ton per input waste) showed values equal or better to those of the conventional system. By contrast, weakness was in the O2 diffusion system. Although a life cycle analysis is necessary, the results highlighted the feasibility of the proposal especially for emergency situations.

Binders alternative to Portland cement and waste management for sustainable construction-part 1.

This review presents "a state of the art" report on sustainability in construction materials. The authors propose different solutions to make the concrete industry more environmentally friendly in order to reduce greenhouse gases emissions and consumption of non-renewable resources. Part 1-the present paper-focuses on the use of binders alternative to Portland cement, including sulfoaluminate cements, alkali-activated materials, and geopolymers. Part 2 will be dedicated to traditional Portland-free binders and waste management and recycling in mortar and concrete production.