Mechanical recycling of CFRPs based on thermoplastic acrylic resin with the addition of carbon nanotubes.

Carbon fibre-reinforced polymers (CFRPs) are commonly used in aviation, automotive and renewable energy markets, which are constantly growing. Increasing the production of composite parts leads to increased waste production and a future increase in end-of-life components. To improve the recyclability of CFRPs, new materials that fit in with the idea of a circular economy should be used as a composite matrix. One such material is a commercially available thermoplastic liquid resin, Elium® (Arkema, France). In this work, the authors investigated how the mechanical recycling process affects the properties of thermoplastic-based carbon fibre composites. CFRPs with neat Elium® resin and resin modified with 0.02 wt.% single-walled carbon nanotubes or 0.02 wt.% multi-walled carbon nanotubes were manufactured using the resin infusion process. Afterwards, prepared laminates were mechanically ground, and a new set of composites was manufactured by thermopressing. The microstructure, mechanical, thermal and electrical properties were investigated for both sets of composites. The results showed that mechanical grinding and thermopressing processes lead to a significant increase in the electrical conductivity of composites. Additionally, a sharp decrease in all mechanical properties was observed.

Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes.

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon nanotubes (MWCNTs) was carried out by means of aryl groups grafting via the diazotization reaction with selected aniline derivatives, and then nanocomposites based on ELIUM® resin were fabricated. FT-IR analysis confirmed the effectiveness of the carried-out chemical surface modification of MWCNTs as new bands on FT-IR spectra appeared in the measurements. TEM observations showed that carbon nanotube fragmentation did not occur during the modifications. According to the results from Raman spectroscopy, the least defective carbon nanotube structure was obtained for aniline modification. Transmission light microscopy analysis showed that the neat MWCNTs agglomerate strongly, while the proposed modifications improved their dispersion significantly. Viscosity tests confirmed, that as the nanofiller concentration increases, the viscosity of the mixture increases. The mixture with the highest dispersion of nanoparticles exhibited the most viscous behaviour. Finally, an enhancement in impact resistance and electrical conductivity was obtained for nanocomposites containing modified MWCNTs.

Introduction of SWCNTs as a Method of Improvement of Electrical and Mechanical Properties of CFRPs Based on Thermoplastic Acrylic Resin.

The aim of this research was to improve the electrical and mechanical properties of carbon-fibre-reinforced polymers (CFRP) based on thermoplastic acrylic resin ELIUM®, by introducing single-walled carbon nanotubes (SWCNTs) into their structure. The laminates were fabricated using the infusion technique of infiltrating the carbon fabric with the mixture of acrylic resin and SWCNTs. The addition of SWCNTs improved the electrical conductivity through the thickness of the laminate by several times compared to the laminate without modification. No defects or voids were observed in the structure of the fabricated nanocomposites. The introduction of SWCNTs into the CFRP structure increased the Young's modulus, interlaminar shear strength and impact resistance. DMA analysis showed almost no change in the glass transition temperature of the fabricated SWCNT/CFRP nanocomposites compared to the reference laminate.

Effect of Processing Temperature and the Content of Carbon Nanotubes on the Properties of Nanocomposites Based on Polyphenylene Sulfide.

The study aimed to investigate the effect of processing temperature and the content of multi-wall carbon nanotubes (MWCNTs) on the rheological, thermal, and electrical properties of polyphenylene sulfide (PPS)/MWCNT nanocomposites. It was observed that the increase in MWCNT content influenced the increase of the complex viscosity, storage modulus, and loss modulus. The microscopic observations showed that with an increase in the amount of MWCNTs, the areal ratio of their agglomerates decreases. Thermogravimetric analysis showed no effect of processing temperature and MWCNT content on thermal stability; however, an increase in stability was observed as compared to neat PPS. The differential scanning calorimetry was used to assess the influence of MWCNT addition on the crystallization phenomenon of PPS. The calorimetry showed that with increasing MWCNT content, the degree of crystallinity and crystallization temperature rises. Thermal diffusivity tests proved that with an increase in the processing temperature and the content of MWCNTs, the diffusivity also increases and declines at higher testing temperatures. The resistivity measurements showed that the conductivity of the PPS/MWCNT nanocomposite increases with the increase in MWCNT content. The processing temperature did not affect resistivity.